• Title/Summary/Keyword: auxiliary agent

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Introduction of a New Chiral Oxazolidin-2-one Derived from D-Mannitol and Its Applications as a Chiral Auxiliary

  • Kim, Si-Min;Jin, Hyun-Yong;Jun, Jong-Gab
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.749-757
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    • 2002
  • Chiral oxazolidin-2-one is easily prepared from D-mannitol and demonstrated to undergo highly diastereoselective alkylation reactions via lithium imide Z-enolates of its N-acyl derivatives to afford ${\alpha}-branched$ products. Evans syn and non-Evans sy n aldol products were also selectively obtained using this new auxiliary in high diastereomeric purity by simply changing the stoichiometry of TiCl4 and the nature of the amine base. Also, this new auxiliary is employed in diastereoselective Staudinger-type ${\beta}-lactam$ syntheses. Using 2-chloro-1-methylpyridinium iodide as the dehydrating agent, the reaction of auxiliary tethered acetic acid with trans imines gave the desired ${\beta}-lactams$ with cis-selectivity.

Design Agent-Based Sensor Structure (Agent 기반의 센서 구조 설계)

  • 임선종;송준엽;김동훈;이승우;이안성;박경택;김선호
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.572-575
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    • 2004
  • Since the 1990s, the advancement of semiconductor technology has resulted in the development of microprocessor technology, auxiliary computer technology, and application technology such as intelligent algorithms (neural network, fuzzy, etc.). These based the development of intelligent machines. An agent is autonomous software that recognizes environment, exchanges knowledge with other agents and makes decisions. We designed agent-based sensor structure. For the purpose, first, it modeled the function of an intelligent machine. Second, it designed sensory function on the agent level.

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Implementation of the Agent using Universal On-line Q-learning by Balancing Exploration and Exploitation in Reinforcement Learning (강화 학습에서의 탐색과 이용의 균형을 통한 범용적 온라인 Q-학습이 적용된 에이전트의 구현)

  • 박찬건;양성봉
    • Journal of KIISE:Software and Applications
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    • v.30 no.7_8
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    • pp.672-680
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    • 2003
  • A shopbot is a software agent whose goal is to maximize buyer´s satisfaction through automatically gathering the price and quality information of goods as well as the services from on-line sellers. In the response to shopbots´ activities, sellers on the Internet need the agents called pricebots that can help them maximize their own profits. In this paper we adopts Q-learning, one of the model-free reinforcement learning methods as a price-setting algorithm of pricebots. A Q-learned agent increases profitability and eliminates the cyclic price wars when compared with the agents using the myoptimal (myopically optimal) pricing strategy Q-teaming needs to select a sequence of state-action fairs for the convergence of Q-teaming. When the uniform random method in selecting state-action pairs is used, the number of accesses to the Q-tables to obtain the optimal Q-values is quite large. Therefore, it is not appropriate for universal on-line learning in a real world environment. This phenomenon occurs because the uniform random selection reflects the uncertainty of exploitation for the optimal policy. In this paper, we propose a Mixed Nonstationary Policy (MNP), which consists of both the auxiliary Markov process and the original Markov process. MNP tries to keep balance of exploration and exploitation in reinforcement learning. Our experiment results show that the Q-learning agent using MNP converges to the optimal Q-values about 2.6 time faster than the uniform random selection on the average.

기술사마당 - 도시 쓰레기 소각에서 발생하는 다이옥신으로부터 국민건강을 지키자

  • Choi, Hae-Wuk
    • Journal of the Korean Professional Engineers Association
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    • v.46 no.2
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    • pp.44-50
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    • 2013
  • The treatment of city life wastes is headache problem. Now, only small portion of burnable wastes is burnt at modern process incinerators, the other large portion is buried in the soil by landfill method. The burnable wastes will be increased year by year. The dioxin, the cancer-causing agent, produced by incineration of wastes influences harmful effect to national human health. The new idea of burnable wastes treatment is using the city life wastes as auxiliary fuel of fluidizing bed combustion boiler of large scale coal-fired power plant. The dioxin-free treatment of burnable wastes is sucessfully achieved by burning the wastes, in flyash storm at fluidizing bed combustion boiler.

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Polycaprolactone Nanofiber Mats Fabricated Using an Electrospinning Process Supplemented with a Chemical Blowing Agent (전기방사공정과 발포제를 이용한 Polycaprolactone 나노섬유 지지체 제작)

  • Kim, Geun-Hyung;Yoon, Hyeon;Lee, Haeng-Nam;Park, Gil-Moon
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.458-464
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    • 2008
  • A successful scaffold should have a highly porous structure and good mechanical stability. High porosity and appropriate pore size provide structural matrix for initial cell attachment and proliferation enabling the exchange of nutrients between the scaffold and environment. In this paper the highly porous scaffold of poly(${\varepsilon}$-caprolactone) electrospun nanofibers could be manufactured with an auxiliary electrode and chemical blowing agent (BA) under several processing conditions, such as the concentration of PCL solution, weight percent of a chemical blowing agent, and decomposition time of a chemical blowing agent. To attain stable electrospinnability and blown nanofiber mats having high microporosity and large pore, a processing condition, 8wt% of PCL solution and 0.5wt% of a chemical blowing agent under $100^{\circ}C$ and decomposition time of $2{\sim}3\;s$, was used. The growth characteristic of human dermal fibroblasts cells cultured in the mats showed the good adhesion and proliferation on the blown mat compared to a normal electrospun mat.

The use of auxiliary devices during irrigation to increase the cleaning ability of a chelating agent

  • Prado, Marina Carvalho;Leal, Fernanda;Simao, Renata Antoun;Gusman, Heloisa;do Prado, Maira
    • Restorative Dentistry and Endodontics
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    • v.42 no.2
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    • pp.105-110
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    • 2017
  • Objectives: This study investigated the cleaning ability of ultrasonically activated irrigation (UAI) and a novel activation system with reciprocating motion (EC, EasyClean, Easy Equipamentos $Odontol\acute{o}gicos$) when used with a relatively new chelating agent (QMix, Dentsply). In addition, the effect of QMix solution when used for a shorter (1 minute) and a longer application time (3 minutes) was investigated. Materials and Methods: Fifty permanent human teeth were prepared with K3 rotary system and 6% sodium hypochlorite. Samples were randomly assigned to five groups (n = 10) according to the final irrigation protocol: G1, negative control (distilled water); G2, positive control (QMix 1 minute); G3, QMix 1 minute/UAI; G4, QMix 1 minute/EC; G5, QMix 3 minutes. Subsequently the teeth were prepared and three photomicrographs were obtained in each root third of root walls, by scanning electron microscopy. Two blinded and pre-calibrated examiners evaluated the images using a four-category scoring system. Data were statistically analyzed using Kruskal-Wallis and Dunn tests (p < 0.05). Results: There were differences among groups (p < 0.05). UAI showed better cleaning ability than EC (p < 0.05). There were improvements when QMix was used with auxiliary devices in comparison with conventional irrigation (p < 0.05). Conventional irrigation for 3 minutes presented significantly better results than its use for 1 minute (p < 0.05). Conclusions: QMix should be used for 1 minute when it is used with UAI, since this final irrigation protocol showed the best performance and also allowed clinical optimization of this procedure.

Catalytic Conversion of Cellulose to Cellulose Acetate Propionate (CAP) Over SO42-/ZrO2 Solid Acid Catalyst

  • Leng, Yixin;Zhang, Yun;Huang, Chunxiang;Liu, Xiaocheng;Wu, Yuzhen
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1160-1164
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    • 2013
  • The solid super acid catalyst $SO{_4}^{2-}$/$ZrO_2$ was prepared by impregnation method using $ZrO_2$ as the catalyst support. Catalyst forming was taken into consideration in order to separate catalyst from the mixture of cellulose acetate propionate (CAP). $Al_2O_3$ and sesbania gum powder were selected as binding agent and auxiliary agent respectively. The catalytic properties were evaluated through esterification of cellulose with acetic anhydride, propionic anhydride and characterized by XRD, FTIR and $NH_3$-TPD. In this paper, the effects of concentration of $H_2SO_4$ impregnated, calcination temperature, esterification temperature and esterification time on the yield, acyl content and viscosity of CAP were investigated. The results showed that $SO{_4}^{2-}/ZrO_2$ successfully catalyzed CAP synthesis over catalysts impregnated in 0.75 mol/L $H_2SO_4$ and calcined at $500^{\circ}C$. The yield, acetyl content and propionyl content of CAP reached the maximum value of 105.3%, 29.9% and 25.8% reacted at $50^{\circ}C$ for 8 h.

Washing Efficiency of Blood-Soiled Fabrics in Various Conditions of Washing - Focus on Washing Temperature, Fiber Type and Blood Aging - (혈액오구의 세척성에 관한 연구 - 세탁온도, 섬유종류 및 혈액의 노화를 중심으로 -)

  • Byeon, Hye Jin;Kim, Hye Jin;Myeong, Jeong Eun;Jo, Hee Ryeong;Yun, Changsang
    • Fashion & Textile Research Journal
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    • v.22 no.4
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    • pp.534-539
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    • 2020
  • Experimental research is needed to provide information on the removal of bloodstains since washing clothes contaminated with blood is necessary for medical related fields (such as ambulance workers and doctors) as well as for women of childbearing age. This study investigated efficient washing conditions for the removal of bloodstains with a focus on washing temperature, fiber type and blood ageing time. Polyester/cotton fabric showed the highest detergency from among three fabrics that were influenced by the composition of the fiber and the structure of the yarn and fabric. When examining the effect of detergent, it was concluded that the alkalinity over pH 10 was essential to remove bloodstains and that auxiliary agents such as soil antiredeposition agents and bleach had a significant effect on the removal of bloodstains. Washing temperature showed the highest detergency at 20℃ due to the activity of the enzyme without the denaturalization of blood. Blood-ageing influenced detergency by inducing changes in the adsorption area and chemical bond. A combination of methods such as quick removal after contamination, use of alkaline detergents including soil antiredeposition agents and bleach, and low-temperature washing could help remove bloodstains.

L-DOPA Synthesis Using Tyrosinase-immobilized on Electrode Surfaces

  • Rahman, Siti Fauziyah;Gobikhrisnan, Siramulu;Gozan, Misri;Jong, Gwi Taek;Park, Don-Hee
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.817-821
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    • 2016
  • Levodopa or L-3,4-dihydroxyphenylalanine (L-DOPA) is the direct precursor of the neurotransmitter dopamine. L-DOPA is a well-known neuroprotective agent for the treatment of Parkinson's disease symptoms. L-DOPA was synthesized using the enzyme, tyrosinase, as a biocatalyst for the conversion of L-tyrosine to L-DOPA and an electrochemical method for reducing L-DOPAquinone, the product resulting from enzymatic synthesis, to L-DOPA. In this study, three electrode systems were used: A glassy carbon electrode (GCE) as working electrode, a platinum, and a Ag/AgCl electrode as auxiliary and reference electrodes, respectively. GCE has been modified using electropolymerization of pyrrole to facilitate the electron transfer process and immobilize tyrosinase. Optimum conditions for the electropolymerization modified electrode were a temperature of $30^{\circ}C$ and a pH of 7 producing L-DOPA concentration 0.315 mM. After 40 days, the relative activity of an enzyme for electropolymerization remained 38.6%, respectively.

Surface Finishing Technique for Micro 3-Dimensional Structures Using ER Fluid

  • Kim, Wook-Bae;Lee, Sang-Jo;Kim, Yong-Jun;Lee, Eung-Sug
    • International Journal of Precision Engineering and Manufacturing
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    • v.5 no.1
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    • pp.47-54
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    • 2004
  • In this study, the electrorheological (ER) fluid was used as finishing agent. Since the apparent viscosity can be controlled by an electric field, the ER fluid can be one of efficient materials in finishing processes. To finish small 3-dimensional structures such as the aspherical surface in optical elements, the possible arrangement of a tool, part and auxiliary electrode was described. We examined the influence of the addition of a few abrasive particles on the performance of the ER fluid by measuring yield stress and observed the behavior of abrasive particles in the ER fluid by a CCD camera, which had been also theoretically predicted from the electromechanical principles of particles. On the basis of the above results, the steady flow analysis around the rotating micro tool was performed considering the non-uniform electric field. Finally, borosilicate glass was finished using the mixture of the ER fluid and abrasive particles and material removal with field strength and surface roughness were investigated.