• Title/Summary/Keyword: atomic block

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Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation (방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구)

  • Lee, Sun-Young;Song, Ju-Myung;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.6 no.2
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Control of Block Copolymer Microdomain: In-Situ and Real-Time SANS Studies of Polymerization-Induced Self-assembly of Block Copolymer Microdomain Structure

  • Koizumi, Satoshi;Yamauchi, Kazuhiro;Hasegawa, Hirokazu;Tanaka, Hirokazu;Motokawa, Ryuhei;Hashimoto, Takeji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.71-72
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    • 2006
  • We investigated a simultaneous living anionic polymerization process of isoprene (I) and 4styrene-d_8$ (S) in $benzene-d_6$ as a solvent with sec-buthyllithium as an initiator into polyisoprene(PI)-block-poly($styrene-d_8$)(PS) and the polymerization-induced molecular self-assembling process. This process was observed in-situ by time-resolved small-angle neutron scattering (SANS) experiment. The SANS profiles measured exhibited three time regions, where (i) the selective growth of PI chains occurs; (ii) the living chain ends switch from isoprenyllithium to styryllithium, and (iii) the SANS exhibited the polymerization induced disorder-to-order transition and order-to-order transition.

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Structural integrity assessment procedure of PCSG unit block using homogenization method

  • Gyogeun Youn;Wanjae Jang;Youngjae Jeon;Kang-Heon Lee;Gyu Mahn Lee;Jae-Seon Lee;Seongmin Chang
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1365-1381
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    • 2023
  • In this paper, a procedure for evaluating the structural integrity of the PCSG (Printed Circuit Steam Generator) unit block is presented with a simplified FE (finite element) analysis technique by applying the homogenization method. The homogenization method converts an inhomogeneous elastic body into a homogeneous elastic body with same mechanical behaviour. This method is effective when the inhomogeneous elastic body has repetitive microstructures, and thus the method was applied to the sheet assembly among the PCSG unit block components. From the method, the homogenized equivalent elastic constants of the sheet assembly were derived. The validity of the determined material properties was verified by comparing the mechanical behaviour with the reference model. Thermo-mechanical analysis was then performed to evaluate the structural integrity of the PCSG unit block, and it was found that the contact region between the steam header and the sheet assembly is a critical point where large bending stress occurs due to the temperature difference.

A Very Fast 2${\times}$2 Fractal Coding By Spatial Prediction (공간예측에 의한 고속 2${\times}$2 프랙탈 영상압축)

  • Wee Young Cheul
    • Journal of KIISE:Computer Systems and Theory
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    • v.31 no.11
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    • pp.611-616
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    • 2004
  • In this paper, we introduce a very fast and efficient fractal coding scheme by using the spatial prediction on ultra-small atomic range blocks. This new approach drastically speeds up the encoding while improving the fidelity and the compression ratio. The affine transformation coefficients between adjacent range blocks induced by this method often have good correlations thereby the compression ratios can further be improved. The proposed method leads to improved rate-distortion performance compared to previously reported pure fractals, and it is faster than other state-of-the-art fractal coding methods.

Lifetime Evaluation of Digital Engineered Safety Features Actuation System Using Reliability Block Diagram

  • Park, Joo-Hyun;Lee, Dong-Young;Park, Jong-Gyun;Han, Jae-Bok;Jun Lyou
    • Proceedings of the Korean Reliability Society Conference
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    • 2002.06a
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    • pp.387-401
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    • 2002
  • The Digital Engineered Safety Feature Actuation System (DESFAS) of nuclear power plants actuates safety systems to mitigate severe accidents occurred in nuclear power plants. The reliability of the system should be evaluated in order to meet the reliability criteria of nuclear power plants. In this work, we have calculated and evaluated the lifetime of DESFAS by using Reliability Block Diagram (RBD) and failure rates of digital control components. Surveillance test is assumed in the evaluation. The result shows that the digital control component can be used in DESFAS system.

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