• 제목/요약/키워드: atmospheric storage

검색결과 177건 처리시간 0.024초

발생원 유형에 따른 공기 중 휘발성 유기화합물의 비산배출 특성 평가 (Evaluation of Fugitive Emission Characteristics of Airborne Volatile Organic Compounds from Different Source Categories)

  • 백성옥;김미현;서영교
    • 한국대기환경학회지
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    • 제19권4호
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    • pp.363-376
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    • 2003
  • In this study, the fugitive emission characteristics of airborne volatile organic compounds from different source categories were evaluated with respect to the concentrations measured in the vicinity of the sources. A total of 22 different sources were investigated, including gasoline storage and filling stations, painting spray booth, laundry, printing officer, textile industries, and a number of environmental sanitary facilities such as landfill, wastewater treatment and incineration plants. The target VOCs included 83 individual compounds, which were determined by adsorption sampling and thermal desorption coupled with GC/MS analysis. Overall, the aliphatic compounds appeared to be the most abundant class of compounds in terms of their concentrations, followed by aromatic, and halogenated hydrocarbons. As a single compound, however, toluene was the most abundant one, explaining 11% of the total VOC concentrations as an average of all the dataset. Among source categories, petroleum associated sources such as gasoline storage/filling stations, and laundry factory were identified as the most significant sources of aliphatic hydrocarbons, while aromatic VOCs were dominantly emitted from the sources handling organic solvents, such as painting booth, printing offices, and textile dyeing processes. However. there was no apparent pattern in terms of the contributions of eath group to the total VOCs concentrations in environmental sanitary facilities. It was also found that the activated carbon adsorption tower installed for the VOC emission control in some facilities do not show any effective performances, which may result in the increased VOC levels in the ambient atmosphere.

형광물질을 이용한 대기 중 오존 Passive Sampler의 개발 (Development of a Passive Sampler using a Fluorescence Material for the Ambient Ozone)

  • 임봉빈;정의석;김선태
    • 한국대기환경학회지
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    • 제20권4호
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    • pp.483-491
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    • 2004
  • The purpose of this study is to develop an ozone passive sampler and to evaluate its performance p-Acetamidophenol using as the reagent for ozone reacts specifically with the ambient ozone to produce a fluorescence material (p-acetamidopheonl dimer). The volume of absorbent solution and the extraction time determined at suitable conditions for measuring ozone were 100$\mu$L and 60 min, respectively. The changes of fluorescence were observed with incresing the storage period of passive samplers in ambient air. but the cool storage in a refrigerator did not remarkably influence the increase of fluorescence. The measurement for the precision oi the passive sampling was carried out with duplicate measurement of passive samplers. The intra-class correlation coefficients of passive samplers using dry and wet filters were 0.992 and 0.962, respectively The results from field validation tests indicated practical agreement (dry filter: r=0.963, wet filter: r=0.995) between the passive sampler and an UV photometric $O_3$ analyzer. The limit of quantification of ozone passive samplers with sampling time of 8 hr (wet filter) and 24 hr (dry filter) were 8.0 ppb and 2.7 ppb, respectively.

산화철의 환원-산화 반응을 이용한 수소저장에 미치는 Rh/Ce/Zr의 효과 (The effect of Rh/Ce/Zr additives on the redox cycling of iron oxide for hydrogen storage)

  • 이동희;차광서;박주식;강경수;김영호
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.49-52
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    • 2007
  • We investigated hydrogen storage and production properties using redox system of iron oxide($Fe_{3}O_{4}$ + $4H_{2}$ ${\leftrightarrows}$ 3Fe + $4H_{2}O$) modified with rhodium, ceria and zirconia under atmospheric pressure. Reduction of iron oxide with hydrogen(hydrogen storage) and re-oxidation of reduced iron oxide with steam(hydrogen evolution) was carried out using a temperature programmed reaction(TPR) technique. On the temperature programmed studies, the effects of amounts of cerium and zirconium on the re-oxidation rate of partial reduced iron oxides were increased with increasing metal additives amount, but the rhodium amount showed little effect on the re-oxidation rate. On the thermal studies, the re-oxidation rates were enhanced with increasing temperature(300 $^{\circ}C$ < 350 $^{\circ}C$).

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저온용 저장탱크의 보온계산을 위한 Sol-Air 온도에 관한 연구 (A Study of the Sol-Air Temperature for the Calculation of Insulation in Cryogenic Storage Tank)

  • 손병진;맹주성;홍성민
    • 대한설비공학회지:설비저널
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    • 제14권2호
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    • pp.98-107
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    • 1985
  • In this thesis, the Sol-Air temperature distribution for the side-wall of a cylindrical cryogenic storage tank made of nonhomogenious composite layer was studied, in order to calculate the thermal load by Newton's cooling law, when the solar radiation was applied upon the side wall. In the analysis, the atmospheric slab was assumed to be horizontal and infinitely large, and the Sol -Air temperature, which was found by the Net- Radiation method considering the longwave radiation wi th surroundings, was used for boundary condition. Energy equation and boundary conditions were normalized by the defined reference- temperature, and solved. The solutions were developed by the Fourier cosine series. Then, the Sol-Air temperature distribution for the side-wall of LNG storage tank was calculated.

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감압저장 중 토마토과실의 향기성분의 변화 (Changes of Flavor Component in Tomato Fruits during Subatmospheric Pressure Storage)

  • 손태화;천성호;최상원;문광덕
    • Applied Biological Chemistry
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    • 제31권3호
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    • pp.298-307
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    • 1988
  • 토마토 과실의 저장 중 향기물질은 호흡 Climaceteric peak 시기와 함께 그 종류가 증가하였고 SAP-L이 NAP-N보다 향기성분 함량의 증가폭이 완만하였다. 향기성분 중 함량이 많은, 2-hexanone, n-propanol, n-pentanol 및 ethanol은 저장초기에 감소한 후 증가하였고, n-octanol과 furfural은 저장 전반에 걸쳐 증가한 반면 n-butanol, cyclohexanone 및 phenylacetaldehyde 등은 감소하였으며 trans, trans-2,4-decadienal, bensyl alcohol 및 2-heptanone 등은 거의 변화가 없었다.

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Richness of Forest Stands and Atmospheric Carbon Dioxide Storage in Urban Institutional Lands of Bukavu, D.R. Congo

  • KADIATA, Bakach D.;NDAMIYEHE, J.B. Ncutirakiza
    • Journal of Forest and Environmental Science
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    • 제33권2호
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    • pp.79-90
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    • 2017
  • Improving the urban environmental quality relies mainly on the increasing of urban forests capacity to store carbon dioxide. This study assesses the floristic diversity of urban institutional lands in Bukavu and their potential to reduce atmospheric $CO_2$. An exhaustive inventory over three sites ($Coll{\grave{e}}ge$ Alfajiri, $Cath{\acute{e}}drale$ Notre-Dame de la Paix and Institut $Sup{\acute{e}}rieur$ $P{\acute{e}}dagogique$) of Bukavu led to the identification of 1,113 trees of which the diameter at breast height (1.30 m) ranged from 4.9 to 161 cm. Results reveal a floristic diversity made up of 4 families of conifers with 4 species and 14 of broadleaves with 21 species. Average densities were of $54trees\;ha^{-1}$ and $5.21m^2\;ha^{-1}$ of basal area. Urban-based allometric equations used yielded up to 312.8 tons of carbon stored in trees aboveground biomass equivalent to 1,147.9 tons of $CO_2$ reduced from the atmosphere over the three sites. The rate of carbon storage reaches $15.1tons\;ha^{-1}$. Thus, trees of the three institutional sites in Bukavu play an important role in reducing atmospheric $CO_2$ and contribute, thereby, to mitigate global climate change effects. Given the current environmental challenge associated with high population growth rate in cities, the urban forest ecosystem in DRC requires to be extended and further investigation.

청과물 저장에 관한 연구(제 2보) -사과 저장에 있어서 환경압력 및 기체조성이 사과조직내 기체조성과 Ethylene 생성에 미치는 영향- (A Study on the storage of Fresh Fruits and Vegetables (Part II) Effects of Intercellular atmosphere and Ethylene evolution by control of external pressure and gas composition in Apple Fruits.)

  • 손태화;최종욱;서온수
    • 한국미생물·생명공학회지
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    • 제1권1호
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    • pp.25-30
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    • 1973
  • 본 연구는 1971년과 1972년 9월 25일에 수확한 흥옥과 동년 10월 25일에 수확한 국광을 시료로하여 이들 사과의 저장에 있어서 환경압력 및 환경기체조성이 사과조직내 기체조성과 호흡 및 ethylene 생성에 미치는 영향을 규명하기 위하여 실험하였던 바 그 결과는 다음과 같다. 1. 과실조직내 기체량은 환경압력에 비례적으로 변화하며, 환경압력이 사과의 조직내 기체조성 및 기체량에 현저하게 영향을 미쳤다. 2. 조직내 $CO_2$발생량의 증가는 조직내 $O_2$ 소비량에 관련되며, 그러므로 내부 $O_2$ 소비의 감소되는 시기와 호흡에 있어서 climacteric rise의 시기와 일치하였다. 3. $CO_2$ 발생량의 증가는 ethylene 생성 후에 나타나며 그리고 상압구의 이와 같은 현상은 감압구에 잇달아 일어난다. 4. 감압저장에 있어서도 저산소농도와 고탄산가스농도의 조절로써 CA효과를 얻을 수 있다.

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생강 저장굴에서 발생한 건강 피해의 원인 조사 (Investigation of Health Hazards in the Underground Storage Facilities of Ginger Roots)

  • 배근량;임현술
    • Journal of Preventive Medicine and Public Health
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    • 제35권1호
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    • pp.72-75
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    • 2002
  • Objectives : To evaluate the health hazards in the underground storage facilities of ginger roots. Methods : The authors reviewed the emergency rescue records from the Seosan fire department over the period Jan 1, 1996 to Aug 31, 1999. The atmospheres in 3 different underground storage locations were analyzed for $O_2,\;CO_2,\;CO,\;H_2S\;and\;NH_4$. Results : From the emergency records, we were able to identify 20 individuals that had been exposed to occupational hazards in the underground storage facilities. Among these 20 cases, 13 were due to asphyxiation (resulting in f deaths) and 7 were due to falls. In the first atmospheric tests, peformed on Feb 25, 1998, the O2 level inside the underground storage facility, located about $5{\sim}6$ meters below the surface, was 20.6% and the $CO_2$ level was about 1,000 ppm. CO, $H_2S\;and\;NH_4$ were not detected. In the second tests on Jul 6, 1999, measurements of the $O_2$ level at 3 meters below the surface in two different storage locations were 15.3 and 15.1%. And the $O_2$ levels inside the storage facilities were 12.2 and 12.1%. The $CO_2$ level was above 5,000 ppm (beyond upper limits of measurement). CO, $H_2S\;and\;NH_4$ were not detected. Conclusions : We conclude that asphyxiation in the underground storage facilities for ginger roots was not due to the presence of toxic gases such as CO, $H_2S\;and\;NH_4$, but rather the exclusion of oxygen by carbon dioxide was responsible for causing casualties. For the development of a hazard free working environment, safety education as well as improvements in storage methods are needed.

수소저항합금을 이용한 150ℓ급 수소저장용기의 제작과 특성에 관한 연구 (Fabrication and Characteristics of 150ℓ Class Hydrogen Tank Using Hydrogen Storage Alloy)

  • 강길구;강세선;권호영;이임렬
    • 한국수소및신에너지학회논문집
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    • 제13권2호
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    • pp.110-118
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    • 2002
  • The hydrogen storage vessel having a good heat conductivity along with a simple structure and a low cost for these alloys was designed and manufactured, and then its characteristic properties were studied in this study. The various parts in hydrogen storage vessel consisted of copper pipes and stainless steel of 250 mesh reached the setting temperature after 4~5 minutes, which indicated that storage vessel had a good heat conductivity that was required in application. And also the storage vessel had a good property of hydrogen transport considering that the reaction time between hydrogen and rare-earth metal alloys in storage vessel was found to be within 10 min at $18^{\circ}C$ under 10 atmospheric pressure. It showed that the average capacity of discharged hydrogen volume was found to be $120{\ell}$ for $MmNi_{4.5}Mn_{0.5}$ under discharging conditions of $40^{\circ}C{\sim}80^{\circ}C$ at a constant flow rate of $5{\ell}$/min. It was found that the optimum discharging temperature for obtaining an appropriate pressure of 3atm was determined to be $60^{\circ}C$ for $MmNi_{4.5}Mn_{0.5}$ hydrogen storage alloy.