• Wind and Structures
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• v.17 no.1
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• pp.1-19
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• 2013

A multiscale finite element method is applied to the Spalart-Allmaras turbulence model based detached-eddy simulation (DES). The multiscale arises from a decomposition of the scalar field into coarse (resolved) and fine (unresolved) scales. It corrects the lack of stability of the standard Galerkin formulation by modeling the scales that cannot be resolved by a given spatial discretization. The stabilization terms appear naturally and the resulting formulation provides effective stabilization in turbulent computations, where reaction-dominated effects strongly influence near-wall predictions. The multiscale DES is applied in the context of high-Reynolds flow over the Commonwealth Advisory Aeronautical Council (CAARC) standard tall building model, for both uniform and turbulent inflows. Time-averaged pressure coefficients on the exterior walls are compared with experiments and it is demonstrated that DES is able to resolve the turbulent features of the flow and accurately predict the surface pressure distributions under atmospheric boundary layer flows.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.150-155
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• 2010

Liquid rocket injectors play crucial roles on propulsive performance, combustion stability, and heat transfer characteristics. Nevertheless, their developments have mainly relied on empirical methods and expensive hot-firing tests due to lack of fundamental understanding of high pressure combustion phenomena in the near-injector regions. The present study was motivated by recent efforts to develop reliable modeling of liquid rocket combustion. The turbulent combustion model based on the flamelet concept has been extended to take into account real-fluid behaviors occurred at supercritical pressures, and validated against measurements for a cryogenic nitrogen injection, a non-premixed turbulent jet flame at atmospheric pressure, and a LOx/$GH_2$ coaxial shear injector at a supercritical pressure.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.493-502
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• 2012

Syngas laminar burning velocity measurements were carried out at atmospheric pressure and ambient temperature using the Bunsen flame configuration with nozzle burner as a fundamental study on flame stability of syngas fuel. Representative syngas mixture compositions ($H_2$:CO) such as 25:75%, 50:50% and 75:25% and equivalence ratios from 0.5 to 1.4 have been conducted. Average laminar burning velocities have been determined by the stabilized nozzle burner flames using the angle method, radical surface area method and compared with the data obtained from the other literatures. And the results of each experimental methodologies in the various composition ratios and equivalence ratios were coincided with the result of numerical simulation. Especially, it was confirmed that there was necessary to choice a more accurate measurement methodology even the same static flame method for the various composition ratios of syngas fuel including hydrogen. Also, it was reconfirmed that the laminar burning velocities gradually increased with the increasing of hydrogen content in a fuel mixture.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.5
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• pp.412-418
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• 2010

Steam reforming of n-hexadecane, a major component of diesel over Ni-based hydrotalcite-like catalyst was carried out at $900^{\circ}C$ at atmospheric pressure with space velocity of $10,000h^{-1}$ and feed molar ratio of steam/carbon=3.0. Ni-based hydrotalcite catalyst was prepared by a solid phase crystallization (spc) method and characterized by $N_2$-physisorption, CO chemisorption, TPR., XRD, and TEM techniques. It was found that spc Ni/MgAl catalyst showed higher catalytic stability and inhibition of carbon formation than Ni/$\gamma-Al_2O_3$ catalyst under the tested conditions. The results suggest that the modified spc-Ni/MgAl catalyst after optimization may be applied for the SR reaction of diesel.

• Journal of the Korean Institute of Gas
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• v.8 no.1 s.22
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• pp.13-17
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• 2004

To evaluate suitability of the Gaussian plume model for the small scale release of a dense toxic gas, experimental concentrations of the small scale release of chlorine were compared with theoretical concentrations calculated by the Gaussian plume model using various dispersion coefficients. As a result, Ive found that the dispersion of chlorine gas was fairly varied with dispersion coefficient and atmospheric stability and that chlorine concentrations were well estimated by the Gaussian plume model using Briggs' dispersion coefficient and the effective release hight.

• Environmental Engineering Research
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• v.10 no.3
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• pp.131-137
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• 2005

The catalytic activity of precious metals(Rh, Pd, Pt) and nickel catalysts supported on ${\gamma}-Al_2O_3\;and\;CeO_2$ in the partial combustion of methane(PCM) to syngas was investigated based on the product distribution in a fixed bed now reactor under atmospheric condition and also on analysis results by SEM, XPS, TPD, BET, and XRD. The activity of the catalysts based on the syngas yield increased in the sequence $Rh(5)/CeO_2{\geq}Ni(5)/CeO_2>>Rh(5)/Al_2O_3>Pd(5)/Al_2O_3>Ni(5)/Al_2O_3$. Compared to the precious catalysts, the syngas yield and stability of the $Ni(5)/CeO_2$ catalyst were almost similar to $(5)/CeO_2$ catalyst, and superior to these of any other catalysts. The syngas yield of $Ni(5)/CeO_2$ catalyst was 90.66% at 1023 K. It could be suggested to be the redox cycle of the successive reaction and formation of active site, $Ni^{2-}$ and the lattice oxygen, $O^{2-}$ produced due to reduction of $Ce^{4-}$ to $Ce^{3-}$.

• Applied Science and Convergence Technology
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• v.26 no.4
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• pp.62-65
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• 2017

Passivation of surface defects by the formation of chemically inert structure at the surface of $TiO_2$ nanocrystals can be potentially useful in enhancing their photocatalytic activity. In this regard, we have studied the surface chemical states of $TiO_2$ surfaces prepared by a treatment in the afterglow of $N_2$ microwave plasma using X-ray photoemission spectroscopy (XPS). We find that nitrogen is incorporated into the surface after the treatment up to a few atomic percent. Interestingly, the surface oxynitride layer is found to be chemically stable when it's in contact with water at room temperature (RT). The surface nitrogen species were also found to be thermally stable upon annealing up to $150^{\circ}C$ in the atmospheric pressure. Thus, we conclude that the treatment of oxide materials such as $TiO_2$ in the afterglow of $N_2$ plasma can be effective way to passivate the surface with nitrogen species.

• Journal of the Korean Institute of Gas
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• v.8 no.2 s.23
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• pp.8-14
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• 2004

This study analyzed dispersion characteristics and toxic effect in the small-scale continuous release of chlorine gas. We found that the Gaussian model using the Briggs' dispersion coefficient and the effective release height was better predicting experiments than the BM model. From chlorine concentrations calculated by Gaussian model, simulation results showed that the dispersion of chlorine was more affected by atmospheric stability and wind speed than release rate and that the toxic effect of chlorine gas was similar to the effect of parameters on chlorine dispersion. From effected areas with toxic criteria, damaged areas could be estimated to protect human.

• Nuclear Engineering and Technology
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• v.16 no.3
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• pp.136-140
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• 1984

A new medal is presented in order to evaluate the risk from a nuclear facility following accidents directly combining the on-site meteorological data using the Monte Carlo Method. To estimate the radiological detriment to the surrounding population-at-large (collective dose equivalent), in this study the probability distribution of each meteorological element based upon on-site data is analyzed to generate atmospheric dispersion conditions. The random sampling is used to select the dispersion conditions at any given time of effluent releases. In this study it is considered that the meteorological conditions such as wind direction, speed and stability are mutually independent and each condition satisfies the Markov condition. As a sample study, the risk of KNU-1 following the large LOCA was calculated, The calculated collective dose equivalent in the 50 mile region population from the large LOCA with 50 percent confidence level is 2.0$\times$10$^2$ man-sievert.

• Asia-Pacific Journal of Atmospheric Sciences
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• v.54 no.4
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• pp.563-573
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• 2018

An Expert Seasonal Prediction System for operational Seasonal Outlook (ESPreSSO) is developed based on the APEC Climate Center (APCC) Multi-Model Ensemble (MME) dynamical prediction and expert-guided statistical downscaling techniques. Dynamical models have improved to provide meaningful seasonal prediction, and their prediction skills are further improved by various ensemble and downscaling techniques. However, experienced scientists and forecasters make subjective correction for the operational seasonal outlook due to limited prediction skills and biases of dynamical models. Here, a hybrid seasonal prediction system that grafts experts' knowledge and understanding onto dynamical MME prediction is developed to guide operational seasonal outlook in Korea. The basis dynamical prediction is based on the APCC MME, which are statistically mapped onto the station-based observations by experienced experts. Their subjective selection undergoes objective screening and quality control to generate final seasonal outlook products after physical ensemble averaging. The prediction system is constructed based on 23-year training period of 1983-2005, and its performance and stability are assessed for the independent 11-year prediction period of 2006-2016. The results show that the ESPreSSO has reliable and stable prediction skill suitable for operational use.