• Title/Summary/Keyword: atmospheric gas

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Understanding of Non-Thermal Atmospheric Pressure Plasma Characteristics Produced in Parallel Plate Type Geometry

  • Choe, Wonho;Moon, Se Youn;Kim, Dan Bee;Jung, Heesoo;Rhee, Jun Kyu;Gweon, Bomi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.144-144
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    • 2013
  • Non-thermal atmospheric pressure plasmas have recently garnered much attention due to their unique physical and chemical properties that are sometimes significantly different from those of low pressure plasmas. It can offer many possible application areas including nano and bio/medical areas. Many different types of plasma sources have been developed for specific needs, which can be one of the important merits of the atmospheric pressure plasmas since characteristics of the produced plasma depend significantly on operating parameters such as driving frequency, supply gas type, driving voltage waveform, gas flow rate, gas composition, geometrical factor etc. Among many source configurations, parallel plate type geometry is one of the simplest configurations so that it can offer many insights for understanding basic underlying physics. Traditionally, the parallel plate type set up has been studied actively for understanding low pressure plasma physics along with extensive employment in industries for the same reason. By considering that understanding basic physics, in conjunction with plasma-surface interactions especially for nano & bio materials, should be pursued in parallel with applications, we investigated atmospheric pressure discharge characteristics in a parallel plate type capacitive discharge source with two parallel copper electrodes of 60 mm in diameter and several millimeters in gap distance. In this presentation, some plasma characteristics by varying many operating variables such as inter-electrode distance, gas pressure, gas composition, driving frequency etc will be discussed. The results may be utilized for plasma control for widening application flexibility.

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Day and Night Distribution of Gas and Particle Phases Polycyclic Aromatic Hydrocarbons (PAHs) Concentrations in the Atmosphere of Seoul (서울 대기 중 기체 및 입자상 다환방향족탄화수소 (PAHs)의 낮·밤 분포 특성)

  • Lim, Hyung Bae;Kim, Yong Pyo;Lee, Ji Yi
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.4
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    • pp.408-421
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    • 2016
  • Day and night sampling for gas and particle phases PAHs were carried out in Seoul to characterize gas and particle phases PAHs concentrations in day and night times. There was no significant difference between day and night time for particle phase PAHs concentrations and phase distribution of PAHs, while, gas phase PAHs concentrations in daytime were about 1/2 of nighttime concentrations in both summer and winter due to photochemical reaction of gas phase PAHs during daytime. A high fraction of cancer risk for PAHs was attributed to particle phase PAHs and the excess cancer risk in winter was higher than in summer. The excess cancer risk level of total(gas+particle) PAHs in summer was partially observed when both gas and particle phase PAHs concentrations were considered as risk assessment. Based on the diagnostic ratios and factor analysis of PAHs concentrations, combustion(coal and natural gas) and vehicular emission might be the most significant contributors of PAHs and major factors for determining of PAHs concentration were different between day and night times.

Gas-particle Partitioning of Organochlorine Pesticides in Atmosphere (대기 중 유기염소계 살충제의 가스-입자 분배)

  • Choi, Min-Kyu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.457-465
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    • 2007
  • This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

Removal Characteristics of Gaseous Contaminants by a Wet Scrubber with Different Packing Materials (충진제의 종류에 따른 습식 스크러버의 가스상 물질 제거특성)

  • Han, Bang-Woo;Kim, Hak-Joon;Kim, Yong-Jin;Han, Kyeong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.744-751
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    • 2007
  • Wet scrubber is widely used to remove toxic gaseous contaminants in various industries such as semi-conductor industry, display manufacturing industry and so on. In this study, to optimize a packed bed scrubber as one of typical wet scrubber size while keeping its performance, four different packing materials were investigated at different air flow rates, liquid-gas ratios and pH values. Ammonia, hydrochloric acid and hydrofluoric acid were used as test gases to characterize the scrubber performance. Gas removal efficiency increased as the packing size decreased, which resulted in the increase of specific surface area. The increase of air flow rate led to the decrease of gas removal efficiency, while the increase of liquid-gas ratio led to the increase of gas removal efficiency. For the case of $NH_3$ gas, lower pH, and for the cases of HCl and HF, higher pH contributed to higher gas removal efficiency. Gas removal efficiency of a wet scrubber increased in the order of HCl < $NH_3$ < HF according to its water solubility.

Effects of the Convector Plate Shape and the Atmospheric Gas on Characteristics of Heat Transfer in a Batch Annealing Furnace (BAF에서 분위기 가스와 대류판 형태가 열전달 특성에 미치는 영향)

  • Yoon, Soon Hyun;Kim, Moon Kyung;Kim, Dae Seong
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.8
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    • pp.72-79
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    • 1996
  • In a BAF(Batch Annealing Furnace), various studies have been pursued in order to reduce energy consumption rate to improve productivity and to stabilize the properties of products. The purpose of this study was to investigate the effects of both the atmospheric gas and convector plate shapes on the augmentation of heat transfer. The use of hydrogen instead of nitrogen as an atmospheric gas, combined with high convection in the BAF, has shown that considerable increases in furnace out put and significantly improved material quality are attainable. Because convector plate shapes make the atmosheric gas easily flow density, high diffusivity and reducing character of hydrogen, a better heat transfer rates resulting in uniform material temperature distribution and improved coil surface quality can be achieved. Also, it was found that the closed convector plate took more time for the annealing cycle time than the other plate type(open-type)by about ten hours.

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Development of primary reference gas mixtures of 18 volatile organic compounds in hazardous air pollutants (5 nmol/mol level) and their analytical methods

  • Kang, Ji Hwan;Kim, Yong Doo;Lee, Jinhong;Lee, Sangil
    • Analytical Science and Technology
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    • v.34 no.5
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    • pp.202-211
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    • 2021
  • Volatile organic compounds (VOCs) in hazardous air pollutants (HAPs) have been regulated by the Air Pollution Control Act (1978) and their atmospheric concentrations have been monitored in 39 monitor sites in Korea. However, measurement standards of volatile organic compounds (VOCs) in HAPs at ambient levels have not been established in Korea. Primary reference gas mixtures (measurement standards) at ambient levels are required for accurately monitoring atmospheric VOCs in HAPs and managing their emissions. In this study, primary reference gas mixtures (PRMs) at 5 nmol/mol were developed in order to establish primary national standards of VOCs in HAPs at ambient levels. Primary reference gas mixtures (PRMs) were prepared in pressurized aluminum cylinders with special internal surface treatment using gravimetric method. Analytical methods using gas chromatography-flame ionization detector (GC-FID) coupled with a cryogenic preconcentrator were also developed to verify the consistency of gravimetrically prepared HAP VOCs PRMs. Three different columns installed in the GC-FID were evaluated and compared for the retention times and separation of eighteen target components in a chromatogram. Results show that the HAP VOCs PRMs at 5 nmol/mol were consistent within a relative expanded uncertainty (k=2) of less than 3 % except acrylonitrile (less than 6 %) and the 18 VOCs were stable for 1 year within their associated uncertainties.

An experimental Study on Exhaust Emissions of CNG Dedicated Engine (CNG 전소기관의 배출가스에 관한 실험적 연구)

  • 오용석
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.2
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    • pp.159-164
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    • 2000
  • A CNG dedicated engine one of the types in natural gas engine is assessed as the most effective mechanism for the reduction of exhaust emissions. This work described the measuring results of a CNG dedicated engine by the experiment, In this study the characteristics of the CNG engine was investigated and then measured exhaust gas by engine performance mode at maximum load condition with increasing the engine speed in the range of 1,000-2,200rpm. The exhaust emission was also measured at D-13 mode as well as AVL-8 mode.

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Numerical Simulation of Flow Field and Air Pollutatnts Concentration in Kwangyang Bay (광양만권의 유동장 및 대기오염농도예측)

  • 정용현
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.397-402
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    • 2000
  • Numerical simulation model using nesting method and considering topographic features was developed to predict atmospheric environments atmospheric flow temperature and diffusion of air pollutants in Kwangyang bay where having complex areas of point sources Korea. In addition developed simulation model was used tracing of spreading range of pollutants when a gas leaks suddenly from Yeo-cheon industrial complex. by comparing the measured and calculated data on atmospheric flow temperature and diffusion of air pollutants the results showed that this model can be well applied and complicated topography affected the diffusion of air pollutants.

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Investigation of Elemental Mercury Oxidation on Commercial SCR Catalysts in Flue Gas of Fossil Fired Power Plant (상용 SCR 촉매상에서 화력발전소 배기가스 중 원소수은의 산화반응연구)

  • Lee, Seung-Min;Lee, Jung-Bin
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.3
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    • pp.245-252
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    • 2010
  • For the purpose of evaluating to remove elemental mercury using SCR (Selective Catalytic Reduction) catalysts, the result of the concentration variation of elemental mercury in lab experiment and field measurement was compared. The effect of the elemental mercury oxidation on commercial catalysts was studied in simulated gas. Three species of SCR catalyst, $V_2O_5-TiO_2$ type, were selected. The elemental mercury reduced 30% without HCl gas in SCR operating condition. But the width of reduction increased 60% at 20 ppm HCl gas. According to the result of field measurement, reduction rate of elemental mercury at SCR outlet showed 60%. The total mercury concentration decreased about 20%. The results were similar to the lab test. The results of chemical analysis of test sample showed increase of mercury concentration but surface change was not observed.