• Journal of Korean Society for Atmospheric Environment
• /
• v.12 no.2
• /
• pp.189-198
• /
• 1996

Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

• Atmosphere
• /
• v.25 no.1
• /
• pp.31-49
• /
• 2015

From the hourly data of 75 Korean weather stations over a 12-year period (2001~2012), this study has chosen three cases (January 12, 2006; January 11, 2008; and February 22, 2009) of multiple freezing rains and investigated the atmospheric circulations that seemed to cause the events. As a result, the receding high pressure type (2006), prevailing high pressure type (2008), and warm front type (2009) are confirmed as synoptic patterns. In all three cases, freezing rain was found in regions with a strong ascending current near the end point of a low-level jet that carried the warm humid air from low latitudes. The strong ascending current resulted from lower-level convergence and upper-level divergence. In 2006 and 2009, the melting process was confirmed. In 2008, the supercooled warm rain process (SWRP) was confirmed. In contrast to existing SWRP theory, it was found that the cool air produced at the middle atmosphere and near the earth's surface led to the formation of freezing rain. The sources of this cool air were supposed to be the evaporative latent heat and the cold advection coming from the northeast. On the other hand, a special case was detected, in which the freezing rain occurred when both the soil surface temperature and surface air temperature were above $0^{\circ}C$. The thickness distributions related to freezing rain in Korea were found to be similar to those in North America. A P-type nomogram was considered for freezing rain forecasting; however, it was not relevant enough to Korea, and few modifications were needed.

• Journal of the Korean Chemical Society
• /
• v.51 no.6
• /
• pp.577-584
• /
• 2007

The purpose of this study is to suggest how to use the phase diagram for water to explain the evaporation and sublimation in the atmospheric condition. In principle, the phase diagram for water represents a one component system so it cannot be applied to the water contact with the air. When the liquid or solid phase of water exists in the air, always water vapor also exists in the air. In this case, we cannot present this state as a single point on the phase diagram because the pressure of the liquid or solid is different from that of the vapor in the air. However, since the saturation vapor pressure of liquid or solid is altered by negligible amount due to the presence of air, the evaporation and sublimation in the atmospheric condition can be explained using the vapor pressure line and sublimation line on the phase diagram.

• Journal of The Korean Association For Science Education
• /
• v.22 no.3
• /
• pp.560-570
• /
• 2002

This study was focused on whether secondary science teachers have consistent, integrative scheme on the definition of atmospheric pressure and phenomena caused by air pressure. We had made questionnaire and let 94 science teachers answer. We sorted the responses according to their major, school and compared them with the description in textbooks. The result can be summarized into three findings. First of all, teachers whose major is chemistry have strong tendency to understand that atmospheric pressure is caused by molecular motion though it, in textbooks, is defined as the pressure by weight of air mass. The half of respondents believed that decreasing of atmospheric pressure in high altitude is due to molecular motions, while most textbook says decrease in the weight of air mass. Secondly, many science textbooks show that air mass expands, rises, becomes less dense and the pressure of atmosphere becomes low when it receives heat. So, most of respondents explained low pressure is formed by lower density. Thirdly, they answered that they just teach the phenomena of air pressure by using the textbooks which mainly deal with the present state rather than a principle. In conclusion, the science textbooks should present the exact description and consolidated structures of those concepts to prevent students from having misconceptions on air pressure. In addition, training program for science teachers would be necessary to reconsider and explore the natural phenomena in various viewpoints.

• Journal of Advanced Marine Engineering and Technology
• /
• v.32 no.8
• /
• pp.1141-1148
• /
• 2008

One of the methods to increase the efficiency of an engine is to expand pressures obtained from combustions equal to the pressure of atmosphere as much as possible and then convert thermal energy into mechanical energy also as much as possible. In this research, the Diesel cycle was thermodynamically interpreted to evaluate the possibility of high efficiency by converting Diesel engines to the Atkinson cycle, and general cycle features were analyzed after comparing these two cycles. In the case of fuel air the Diesel-Atkinson cycle considering intake and exhaust similar to real cycles, the value of thermal efficiency and average effective pressure increased, though their values were smaller than those of standard air amount cycle, when expansion compression ratio increased. When normal Diesel engines of which compression stroke and expansion stroke are all the same, was converted to the Atkinson cycle by changing the time of intake value close, combustion pressure reduced due to reduced expansion compression ratio and intake air amount due to decreased effective cycle volume.

• Nuclear Engineering and Technology
• /
• v.54 no.6
• /
• pp.2311-2320
• /
• 2022

The main outcomes of the experiments H2P6 performed in the thermal-hydraulics large-scale PANDA facility at PSI in the frame of the OECD/NEA HYMERES-2 project are presented in this article. The experiments of the H2P6 series consists of two PANDA tests characterized by the activation of three (H2P6_1) or one (H2P6_2) cooler(s) in an initially stratified and pressurized containment atmosphere. The initial stratification is defined by a helium-rich region located in the upper part of the vessel and a steam/air atmosphere in the lower part. The activation of the cooler(s) results i) in the condensation of the steam in the vicinity of the cooler(s), ii) the corresponding activation of large scale natural circulation currents in the vessel atmosphere, with the result of iii) the re-distribution and mixing of the Helium stratification initially located in the upper half of the vessel and iv) the continuous pressure decay. The initial helium layer represents hydrogen generated in a postulated severe accident. The main question to be answered by the experiments is whether or not the interaction of the different, localized cooler units would be important for the application of numerical methods. The paper describes the initial and boundary conditions and the experimental results of the H2P6 series with the suggestion of simple scaling laws for both experiments in terms of i) the temperature difference(s) across the cooler(s), ii) the transient steam and helium content and iii) the pressure decay in the vessel. The outcomes of this scaling indicate that the interaction between separate, closely localized units does not play a prominent role for the present experiments. It is therefore reasonable to model several units as one large component with equivalent heat transfer area and total water flow rate.

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.4
• /
• pp.457-465
• /
• 2007

This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

• Journal of Korean Society for Atmospheric Environment
• /
• v.18 no.4
• /
• pp.275-284
• /
• 2002

Atmospheric concentrations of organochlorine pesticides (OCPs) in Seoul, South Korea between July 1999 and May 2000 were determined to investigate concentration distribution in air, relationship between concentrations and meteorological conditions, and apportionment of sources e.g. local sources (air- surface exchange) and long range transport. Endosulfan and $\alpha$-HCH were the highest concentrations in atmosphere with values typcally ranging from 10s to l00s of pg/㎥. These high concentrations may be attributed to their usage, period and chemical property (Koa). All OCPs also showed elevated levels during the summer and were positively correlated with temperature. This would suggest that a seasonal enhancement was due to (re)volatilization from secondary sources and application during the warmer months. The temperature dependence of atmospheric concentrations of OCPs were investigated using plots of the natural logarithm of partial pressure (In P) vs reciprocal mean temperatures (1/T), and environmental phase-transition energies were calculated for each of the pesticides. For OCPs, temperature dependence was statistically significant (at the 99.99% confidence level) and temperature accounted for 35~95% of the variability in concentrations. The relatively higher slopes and phase-transition energies for $\alpha$-, ${\gamma}$-chlordane, endosulfan and endosulfan sulfate suggested that volatilization from local sources influenced their concentrations. The relatively lower those for $\alpha$-, ${\gamma}$-HCH, p, p'-DDE and heptachlor epoxide also suggested that volatilization from local sources and long range transport influenced their concentrations.

• Journal of the Korean Society of Safety
• /
• v.14 no.4
• /
• pp.100-107
• /
• 1999

The purpose of the study is to investigate the effect of H$_2$ pressure on partial discharge (PD) activity and aging rate in turbine generator winding insulations. A series of field tests and laboratory tests were peformed to investigate the effect of $H_2$ pressure on PD activity. Field tests were conducted at two unit turbine generators in two conditions, in $H_2$ pressure and in air atmosphere. Obtained results are as follows ; 1) ${\Delta}tan{\delta}$ and maximum partial discharge are reduced with increase of $H_2$ pressure and partial discharge inception voltage. 2) The reduction ratio of ${\Delta}tan{\delta}$ due to $H_2$ pressure is higher than one of PD magnitude. 3) Partial discharge pulses suffer from attenuation and distortion when transmitted along windings, because of the complex L-C network between windings. From the result, partial discharge pulses are subjected to resonance phenomena in a generator winding.

• Atmosphere
• /
• v.26 no.2
• /
• pp.227-241
• /
• 2016

This study investigated the cause of the heavy snowfall that occurred in the East Coast of Korea from 6 February to 14 February 2014. The synoptic conditions were analyzed using blocking index, equivalent potential temperature, potential vorticity, maritime temperature difference, temperature advection, and ground convergence. During the case period, a large blocking pattern developed over the Western Pacific causing the flow to be stagnant, and there was a North-South oriented High-to-Low pressure system over the Korean Peninsula because of this arrangement. The case period was divided into three parts based on the synoptic forcing that was responsible for the heavy snowfall; detailed analyses were conducted for the first and last period. In the first period, a heavy snowfall occurred over the entire Korean Peninsula due to strong updrafts from baroclinic instability and a low pressure caused by potential vorticity located at the mid-troposphere. In the lower atmosphere, a North-South oriented High-to-Low pressure system over the Eastern Korea intensified the easterly airflow and created a convergence zone near the ground which strengthened the upslope effect of the Taebaek Mountain range with a cumulative fresh snowfall amount of 41 cm in the East Coast region. In the last period, the cold air nestled in the Maritime Province of Siberia and Manchuria strengthened much more than that in the first half and extended to the East Sea. The temperature difference between the 850 hPa air and the SST was large and convective clouds developed over the sea. The highest cumulative fresh snow amount of 39.7 cm was recorded in the coastal area during this period. During the entire period, vertically oriented equivalent potential temperature showed neutral stability layer that helped the cloud formation and development in the East Coast. The 2014 heavy snowfall case over the East Coast provinces of Korea were due to: 1) stagnation of the system by blocking pattern, 2) the dynamic effect of mid-level potential vorticity of 1.6 PVU, 3) the easterly air flow from North-South oriented High-to-Low pressure system, 4) the existence of vertically oriented neutral stable layer, and 5) the expansion of strong cold air into the East Sea which created a large temperature difference between the air and the ocean.