• Current Optics and Photonics
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• v.5 no.5
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• pp.514-523
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• 2021

Methods for absolute depth estimation have received lots of interest, and most algorithms are concerned about how to minimize the difference between an input defocused image and an estimated defocused image. These approaches may increase the complexity of the algorithms to calculate the defocused image from the estimation of the focused image. In this paper, we present a new method to recover depth of scene based on a sharpness-assessment algorithm. The proposed algorithm estimates the depth of scene by calculating the sharpness of deconvolved images with a specific point-spread function (PSF). While most depth estimation studies evaluate depth of the scene only behind a focal plane, the proposed method evaluates a broad depth range both nearer and farther than the focal plane. This is accomplished using an asymmetric aperture, so the PSF at a position nearer than the focal plane is different from that at a position farther than the focal plane. From the image taken with a focal plane of 160 cm, the depth of object over the broad range from 60 to 350 cm is estimated at 10 cm resolution. With an asymmetric aperture, we demonstrate the feasibility of the sharpness-assessment algorithm to recover absolute depth of scene from a single defocused image.

• Electronic Materials Letters
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• v.14 no.6
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• pp.784-792
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• 2018

In this letter, a standard deviation based optimization technique has been applied on High Resolution X-ray Diffraction symmetric and asymmetric scan results to accurately determine the Aluminum molar fraction and lattice relaxation of Molecular Beam Epitaxy grown compositionally graded Aluminum Gallium Nitride (AlGaN)/Aluminum Nitride/Gallium Nitride (GaN) heterostructures. Mathews-Blakeslee critical thickness model has been applied in an alternative way to determine the partially relaxed AlGaN epilayer thicknesses. The coupling coefficient determination has been presented in a different perspective involving sample tilt method by off set between the asymmetric planes of GaN and AlGaN. Sample tilt is further increased to determine mosaic tilt ranging between $0.01^{\circ}$ and $0.1^{\circ}$.

• Proceedings of the PSK Conference
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• 2002.10a
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• pp.364.2-364.2
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• 2002

(S) and (R) 12-HETE. endogenous eicosanoids. have recently been discovered to be implicated in a number of important biological activities. In particular. it has recently been reported by us that both the capsaicin-activated channel of sensory neurons and the cloned capsaicin receptor (VR1) are activated by the eicosanoids including these metabolites. We report herein a novel and efficient asymmetric synthesis of highly enantiomerically enriched 12(S)-HETE via enzymatic kinetic resolution of the key allylic alcohol synthon. (omitted)

• Korean Chemical Engineering Research
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• v.43 no.6
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• pp.647-661
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• 2005

The stereoselective synthesis of chiral terminal epoxide is of immense academic and industrial interest due to their utility as versatile starting materials as well as chiral intermediates. In this review, we investigate the research and development trend in the asymmetric ring opening reactions using cobalt salen catalysts. Hydrolytic kinetic resolution (HKR) technology is the very prominent way to prepare optically pure terminal epoxides among available methods. We have synthesized homogeneous and heterogeneous chiral dinuclear salen complexes and demonstrated their catalytic activity and selectivity for the asymmetric ring opening of terminal epoxides with variety of nucleophiles and for asymmetric cyclization to prepare optically pure terminal epoxides in one step. The resolved ring opened product combined with ring closing in the presence of base and catalyst afforded the enantioriched terminal epoxides in quantitaive yield. Potentially, these catalysts are using on an industrial scale to produce chiral intermediates. The experimental results of HKR technology applied to the synthesis of various chiral compounds are presented in this paper.

• Journal of the Society of Naval Architects of Korea
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• v.53 no.1
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• pp.37-44
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• 2016

Recently researchers are conducting a lot of research related to EEDI in order to satisfy IMO resolution MEPC. Especially they are interested in design of energy saving device. This paper is to design the asymmetric pre-swirl stator for 160K LNG carrier in order to reduce energy. Two types of the asymmetric pre-swirl stator are taken into account; constant and variable pitch angle stators. “constant” and “variable” mean state that the pitch of stators change by radius. The dimensions of the stators are initially determined using potential-flow code. The propulsion performances of the stators are predicted using viscous-flow code. The model test is carried out in towing tank in PNU. Prediction of ship performance generally follow ITTC recommended. Ship wake prediction was done by two method, ITTC 1978 and ITTC 1999. Therefore propulsion performances were compared ITTC 1978 with ITTC 1999 methods. Comparison components are delivered power and thrust deduction coefficient of the model. Final pre-swirl stator is selected by comparing experiment and CFD.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.562-567
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• 2007

The stereoselective synthesis of chiral terminal epoxide is of immense academic and industrial interest due to their use as versatile starting materials as well as chiral intermediates. In this study, new polymeric chiral Co(salen) complexes bearing tallium (III)chloride and iron (III)chloride (ferric chloride) have been synthesized and characterized. Their catalytic activity and selectivity have been demonstrated for the asymmetric ring opening of various terminal epoxides using water and phenol derivatives as nucleophiles. The easily prepared polymeric complexes exhibited very high enantioselectivity for the asymmetric ring opening of epoxides with $H_2O$ and phenol nucleophiles, providing enantiomerically enriched terminal epoxides (> 98% ee). The system described in this work is very efficient for the synthesis of chiral epoxide, 1,2-diol and ${\alpha}$-aryloxy alcohol intermediates.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.313-318
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• 2008

An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.439-443
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• 1995

Both enantiomers of (S)-(-)-2-(diphenylphosphino)-2'-mercapto-1,1'-binaphthyl and their derivatives were obtained by synthesis from racemic 2,2'-dihydroxy-1,1'-binaphthyl and subsequent resolution. The utilities of these ligands were investigated briefly. And among these, S-methyl derivative 15 has proved to be an effective ligand for Pd-catalyzed allylic alkylation.

• Proceedings of the Korean Society of Life Science Conference
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• 2001.11a
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• pp.21-28
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• 2001

A newly isolated Aspergillus niger possessing the novel epoxide hydrolase(EHase) activity was investigated for the enantioselective hydrolysis of racemic aromatic epoxides. The gene encoding EHase was cloned by RT-PCR, and molecular characteristics of the EHase gene were compared with other microbial EHases. The cloned gene encodes 398 amino acids with a deduced molecular mass of 44.5 kDa and pI of 4.83, and sequence homology with other microbial EHase was low. Functional recombinant EHase could be obtained by heterologous expressions in E. coli. Enantioselectivity of recombinant EHase was tested for valuable aromatic epoxide intermediates. Reaction conditions of EHase-catalyzed asymmetric resolution were optimized for the production of chiral styrene oxide.

• Bulletin of the Korean Chemical Society
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• v.9 no.5
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• pp.275-280
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• 1988

The high resolution IR spectra of freon-12($CF_2Cl_2$) for the bands of 671cm$^{-1},\;922cm^{-1},\;1102cm^{-1},\;and\;1160cm^{-1}$ were taken and the rotational vibrational analysis has been carried out. The band types of $671cm^{-1}\;and\;1102cm^{-1}$ were confirmed to be A and those of $922cm^{-1}\;and\;1160cm^{-1}$ were confirmed to be B. The theoretically synthesized spectra were matched with the experimentally obtained spectra to get some informations of the molecular rotational behavior as well as the overall band shape of the spectra.