• 제목/요약/키워드: asymmetric mesogen

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Synthesis and Mesomorphic Properties of Banana-Shaped Mesogens with All-Ester Linking Group

  • Choi, E-Joon;Cui, Xin;Zin, Wang-Choel;Ohk, Chang-Woo;Lim, Tong-Kun;Lee, Ji-Hoon;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.197-199
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    • 2007
  • Four banana-shaped compounds have beene synthesized introducing ester linking group into mesogenic unit, varying the central core with 1,6-, 1,7-, 2,3-, and 2,7-naphthylene units, and introducing the dodecyloxy group as the terminal flexible unit. All obtained compounds except one with 1,7-naphthylene unit were reversibly thermotropically liquid crystalline. The compound with 1,7-naphthylene unit could not form the mesophase due to its asymmetrical and sharp substitution angle. The compounds with 1,6- and 2,3-naphthylene units showed an antiferroelectric switchable smectic phase, which has been designated B2 phase. Interestingly, the compound with the 2,3-naphthylene unit showed the two mesophases of B2 and nematic phase.

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