• Bulletin of the Korean Chemical Society
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• v.35 no.7
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• pp.2086-2092
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• 2014

Two novel coordination compounds $[Cu_2(pypya)_3(H_2O)_2]{\cdot}Cl{\cdot}(H_2O)_5$ (1) and $\{[Cd(pypya)(ta)_{1/2}]{\cdot}H_2O\}_n$ (2) (Hpypya=2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)acetic acid, $H_2ta$=terephthalic acid) were synthesized and characterized by single X-ray diffraction. Structure determination reveals that complex 1 and complex 2 crystallize in the triclinic system, with the P-1 space group. The asymmetric unit of 1 contains two Cu(II) ions, and their coordination modes are different. These units of complex 1 are linked together via hydrogen bonds and ${\pi}-{\pi}$ interactions, and the 3D structure of complex 1 was formed. Complex 2, a mononuclear Cd(II) coordination compound, has a 2D structure which was constructed via coordination bonds. TGA and fluorescence spectra analysis of complex 1 and complex 2 have also been studied. In addition, the geometry parameters of complex 1 have been optimized with the B3LYP method of density functional theory (DFT) to explain its coordination behavior. The electronic properties of the complex 1 and ligand Hpypya have been investigated based on the nature bond orbital (NBO) analysis at the B3LYP level of theory. The result verifies that the synergistic effect have occurred in the compound.

• Economic and Environmental Geology
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• v.29 no.5
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• pp.639-660
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• 1996

The lowest formation of the Cretaceous Gyeongsang Supergroup, the Nakdong Formation, unconformably overlies the gneiss complex basement in Hadong, Gyeongsangnam-do and Gwangyang, Chullanam-do. The Nakdong Formation of the study area is 500-600 m thick and occurs as a belt shape. Based upon lithology, sedimentary structure, and bedding geometry the formation consists of three conglomerate facies (Gd, Gn, Gic), five sandstone facies (Sh-n, Sh-i, Sp, Sr, Sm), and four mudstone facies (Mf, Mfn, Mc, Mv). Sandstone facies are the most prominent in the study area. The twelve facies can be grouped into five facies associations. The depositional settings are elucidated from analyses of 12 facies and five facies associations of the formation. The lower part of the Nakdong Formation was deposited in alluvial plain, and the middle and upper parts were in a riverine system. The lithologies of the Nakdong Formation of the Gyeongsang Basin have been considered to consist of generally conglomerates and pebbly sandstones that were accumulated in alluvial fans. But the common lithology of the study area is sandstone which was formed in lower part of alluvial fan or fluvial setting. It is supposed that the coarser sedimentary sequence distributed west to the study area should be eroded out after deposition and early uplift, and the finer sandstone sequence in the east remains behind. The mineral composition of sandstones and the clast composition of conglomerates indicate that the Nakdong Formation was derived mainly from the metamorphic source rocks. Some reworked intraclasts were also supplied from the intrabasinal sedimentary layers. Paleocurrent data collected from cross-beddings, ripple marks, asymmetric sand dune suggest that most sediments were transported from north to south during the Nakdong Formation time.

• Wind and Structures
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• v.13 no.5
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• pp.413-431
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• 2010

The focus of this article is on the assessment of vertical wind vector components and their aerodynamic impact on lattice framework, specifically two distinct sections of a guyed transmission tower. Thunderstorm winds, notably very localized events such as convective downdrafts (including downbursts) and tornadoes, result in a different load on a tower's structural system in terms of magnitude and spatial distribution when compared to horizontal synoptic winds. Findings of previous model-scale experiments are outlined and their results considered for the development of a testing rig that allows for rotation about multiple body axes through a series of wind tunnel tests. Experimental results for the wind loads on two unique experimental models are presented and the difference in behaviour discussed. For a model cross arm with a solidity ratio of approximately 30%, the drag load was increased by 14% when at a pitch angle of $20^{\circ}$. Although the effects of rotation about the vertical body axis, or the traditional 'angle of attack', are recognized by design codes as being significant, provisions for vertical winds are absent from each set of wind loading specifications examined. The inclusion of a factor to relate winds with a vertical component to the horizontal speed is evaluated as a vertical wind factor applicable to load calculations. Member complexity and asymmetric geometry often complicate the use of lattice wind loading provisions, which is a challenge that extends to future studies and codification. Nevertheless, the present work is intended to establish a basis for such studies.

• Transactions of Materials Processing
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• v.25 no.6
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• pp.379-389
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• 2016

As a stator for steam turbine diaphragm, hollow-type nozzle stator to substitute for conventional solid one is introduced in this study. This hollowed stator can be separated into two parts such as upper and lower plates with large and curved surface area. This study focuses on thick plate forming process for the upper plate of the hollow-partitioned nozzle stator. First, to reduce forming defects such as under-cut and localized thinning of the deformed plate, and to avoid tool interruption between forming punch and lower die, tool design including the position determination of forming surfaces is performed. Uni-axial tensile tests are carried out using SUS409L steel plate with initial thickness of 5.00mm, and plastic strain ratio (r-value) is also obtained. Due to the asymmetric curved configuration of the upper plate, it is hard to adopt a series of blank holder or draw-bead, so the initial plate during this thick plate forming experiences unstable and non-uniform contact. To easy this forming difficulty and find suitable tool geometry without sliding behavior of the workpiece in the die cavity, two geometric parameters with respect to each shoulder angle of the lower die and the upper punch are adopted. FE models with consideration of 21 combinations for the geometric parameters are built-up, and numerical simulations are performed. From the simulated and predicted results, it is shown that the geometric parameter combinations with ($30^{\circ}$, $90^{\circ}$) and ($45^{\circ}$, $90^{\circ}$) for the shoulder angle of the lower die and the upper punch are suitably applied to this upper plate forming of the hollow-partitioned nozzle stator used for the turbine diaphragm.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.9
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• pp.688-693
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• 2016

This paper describes the parachute dynamics modeling and simulation results for the development of training simulator of a HALO (High Altitude Low Opening) parachute, which is currently in use for military purposes. The target parachute is a rectangular shaped parafoil and its dynamic model is derived based on the real geometry data as the 9-DOF nonlinear equations of dynamics. The simulation was conducted through the moment of inertia and its aerodynamic derivatives to reflect the real characteristics based on the MATLAB/Simulink. In particular, its modeling includes the typical characteristics of the added mass and moment of inertia, which is shown in the strong effects in Lighter-Than-Air(LTA) flight vehicle. The proposed dynamic modeling was evaluated through the simulation under the spiral turning flight conditions of the asymmetric control inputs and compared with the performance index in the target parachute manual.

• Journal of Korean Society of Steel Construction
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• v.25 no.1
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• pp.35-45
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• 2013

The concrete-filled tube column has the excellent structural performance. But it is difficult to connect with column and beam because of closed section. It suggests that pipe should be produced by welding two sides together where two shapes are joined after a channel is pre-welded onto the three sides in order to form an internal diaphragm. The upper diaphragm of the connection used the horizontal plate and the lower diaphragm used the Vertical plate. This research performed 6 monotonic tension experiments describing the connection upside and downside in order to evaluate the structural capability of the offered connection. And the cyclic loading experiment was performed about 2 T-Type column to beam connections. As to the experimental result edge cutting geometry, there was no big effect. An increase in the number of holes of the plate ultimate strength was increased by 5% and The thickness of the plate increases, the maximum strength was increased by 4%. T-Type connections until it reaches the plastic moment showed a stable behavior.

• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.1946-1952
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• 2005

New group 15 organometallic compounds, M$(phenanthrenyl)_3$ (M = P (1), Sb (2), Bi (3)) have been prepared from the reactions of 9-phenanthrenyllithium with $MCl_3$. A reaction of 9-(diphenylphosphino)phenanthrene with 2,6-diisopropylphenyl azide led to the formation of (phenanthrenyl)${(Ph)}_2P$=N-(2,6-$^iPr_2C_6H_3$) (4). The crystal structures of 2 and 4 have been determined by single-crystal X-ray diffractions, both of which crystallize with two independent molecules in the asymmetric unit. Compound 2 shows a trigonal pyramidal geometry around the Sb atom with three phenanthrenyl groups being located in a screw-like fashion with an approximately $C_3$ symmetry. A significant amount of CH- -$\pi$ interaction exists between two independent molecules of 4. The phosphorus center possesses a distorted tetrahedral environment with P-N bond lengths of 1.557(3)$\AA$ (P(1) N) and 1.532(3)$\AA$ (P(2)-N), respectively, which are short enough to support a double bond character. One of the most intriguing structural features of 4 is an unusually diminished bond angle of C-N-P, attributable to the hydrogen bonding of N(1)-H(5A) [ca. 2.49$\AA$ between two adjacent molecules in crystal packing. The compounds 1-3 show purple emission both in solution and as films at room temperature with emission maxima ($\lambda_{max}$) at 349, 366, and 386 nm, respectively, attributable to the ligand centered $\pi$ $\rightarrow$ $\pi^\ast$ transition in phenanthrene contributed by the lone pair electrons of the Gp 15 elements. Yet the nature of luminescence observed with 4 differs in that it originates from $\pi$ (diisopropylbenzene)-$\pi^\ast$ (phenanthrene) transitions with the $\rho\pi$contribution from the nitrogen atom. The emission maximum of 4 is red-shifted ranging 350-450 nm due to the internal charge transfer from the phenanthrenyl ring to the N-arylamine group as deduced from the ab initio calculations.

• 한국해양학회지
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• v.30 no.4
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• pp.355-364
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• 1995

A heavy fluid is injected to a rotating cylindrical container of flat or inclined bottom filled with homogeneous lighter fluid. Continuous flow-in and spreading patterns over the bottom of the container are observed and at the same time upper-layer motions induced by the movement of the heavy fluid are traced by thymol blue solution. Regardless of bottom geometry, the injected denser fluid is deflected toward "western wall" and continuous its path along the boundary with radial spreading which occurs in the bottom boundary layer to make a quite asymmetric flow. When the bottom contains a slope(${\beta}$-plane), increased pressure gradient causes the fluid move faster to produce a stronger Coriolis force. This makes the width of the flow narrower than that of f-plane. But, when the denser flow reaches the southern part of the container, a local-depth of denser fluid increases (much greater than the Ekman-layer depth) such that the spreading velocity along the wall is reduced and the interfacial slope increases to make the upper-layer adjust geographically to have oppositely directed upper-layer motion along the interfacial boundary. The role of the denser fluid in terms of vorticity generation in the upper-layer is such that it produces local topographic effect over the western half of the container and also induces vortex-tube stretching which is especially dominant in the f-plane.

• The Journal of the Petrological Society of Korea
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• v.22 no.1
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• pp.19-34
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• 2013

The Ipcheon Subbasin is an isolated Miocene basin in SE Korea, which has the geometry of an asymmetric graben elongated in the NE-SW direction. It is in contact with basement rocks by faults and separated from adjacent Waup and Eoil basins by the basement. The strata of the basin fills have an overall homoclinal structure, dipping toward NW or WNW. The basin fills consist of Early Miocene sediments rich in dacitic volcanic and volcaniclastic deposits and Middle Miocene non-volcanic and nonmarine conglomerates intercalated with sand layers, which are distributed in the northeastern and southwestern parts of the basin, respectively. Kinematic analysis of syndepositional conjugate faults in the basin fills indicates WNW-ESE extension of the basin. These features are very similar to those of the adjacent Waup and Eoil basins, indicating that the basin extension was governed by the NE-trending northwestern border faults and that the basin experienced a propagating rifting from NE to SW. Basaltic materials, which occur abundantly in the Eoil Basin, are totally absent in the Ipcheon Subbasin. The observations of the dacitic tuff and tuffaceous mudstone in the subbasin, on slabs and under microscope, suggest that they have lithologies very similar to those of the Yondongri Tuff in the Waup Basin. The Middle Miocene non-volcanic sediments of the Waup and Eoil basins and the Ipcheon Subbasin are distributed consistently in the southwestern part of each basin. It is thus concluded that the extension of the Ipcheon Subbasin began at about 22 Ma together with the Waup Basin and was lulled during the main extension period of the Eoil Basin between 20-18 Ma. At about 17 Ma, the subbasin was re-extended due to the activation of the Yeonil Tectonic Line associated with the propagating rifting toward SW. This event is interpreted to have provided new sedimentation space for the Middle Miocene sediments in the southwestern parts of the Waup and Eoil basins and the Ipcheon Subbasin as well.

• The Journal of the Petrological Society of Korea
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• v.18 no.1
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• pp.19-30
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• 2009

The main fault of Yangsan Fault Zone (YFZ) and Quaternary fault were found in a trench section with NW-SE direction at an entrance of the Sinheung village in the northern Eonyang, Ulsan, Korea. We interpreted the movement history of the southern part of the YFZ from the geometric and kinematic characteristics of basement rock's fault of the YFZ (Sinheung Fault) and Quaternary fault (Quaternary Sinheung Fault) investigated at the trench section. The trench outcrop consists mainly of Cretaceous sedimentary rocks of Hayang Group and volcanic rocks of Yucheon Group which lie in fault contact and Quaternary deposits which unconformably overlie these basement rocks. This study suggests that the movement history of the southern part of the YFZ can be explained at least by two different strike-slip movements, named as D1 and D2 events, and then two different dip-slip movements, named as D3 and D4 events. (1) D1 event: a sinistral strike-slip movement which caused the bedding of sedimentary rocks to be high-angled toward the main fault of the YFZ. (2) D2 event: a dextral strike-slip movement slipped along the high-angled beddings as fault surfaces. The main characteristic structural elements are predominant sub-horizontal slickenlines and sub-vertical fault foliations which show a NNE trend. The event formed the main fault rocks of the YFZ. (3) D3 event: a conjugate reverse-slip movement slipped along fault surfaces which trend (E)NE and moderately dip (S)SE or (N)NW. The slickenlines, which plunge in the dip direction of fault surfaces, overprint the previous sub-horizontal slickenlines. The fault is characterized by S-C fabrics superimposed on the D2 fault gouges, fault surfaces showing ramp and flat geometry, asymmetric and drag folds and collapse structures accompanied with it. The event dispersed the orientation of the main fault surface of the YFZ. (4) D4 event: a Quaternary reverse-slip movement showing a displacement of several centimeters with S-C fabrics on the Quternary deposits. The D4 fault surfaces are developed along the extensions of the D3 fault surfaces of basement rocks, like the other Quaternary faults within the YFZ. This indicates that these faults were formed under the same compression of (N)NW-(S)SE direction.