• Title/Summary/Keyword: arrhenius model

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An Accelerated Life Test of LED Lights for Aviation Taxiway (항공유도로등화용 LED 광원의 가속수명시험)

  • Min, Kyong-Chan;Yun, Yang-Gi;Kim, Myung-Soo
    • Journal of Applied Reliability
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    • v.11 no.2
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    • pp.127-140
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    • 2011
  • This paper presents an accelerated life test of aviation taxiway lights installed in the airport to help safe navigation of airplanes at night or in bad weather. Recently halogen lamps of taxiway lights are replaced by LED ones and their reliability needs yet to be verified. Thus, effective test conditions are designed reflecting the failure modes and mechanisms from the previous studies on LED, which include the accelerated degradation process. The test is performed under the temperature $70^{\circ}C$ and $90^{\circ}C$ for two types of LED lights, taxiway center line lights(TCLL) and taxiway edge lights (TEDL). The failure time data were analyzed using lognormal distribution and Arrhenius model to find the life-stress relationship, acceleration factor and life characteristics under the normal condition temperature $30^{\circ}C$.

Dielectric and Electrical Properties of Ce,Mn:SBN

  • Kang, Bong-Hoon;Paek, Young-Sop;Rhee, Bum-Ku;Lim, Ki-Soo;Joo, Gi-Tae
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.615-619
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    • 2003
  • Temperature and frequency dependence of dielectric and electrical properties was investigated in cerium and manganese doped Sr$\_$0.6/Ba$\_$0.4/Nb$_2$O$\_$6/(60SBN) ceramic system. Structural deformation of 60SBN by dopants did not appeared. 1350$^{\circ}C$-10 h sintered specimen had higher densification than 1250$^{\circ}C$-10 h sintered one, to which dielectric properties are related. That the feature of dielectric maxima peaks was typical Diffusive Phase Transition (DPT), it was explained by "random-field Ising model". Even though 60SBN has large dielectric loss at high frequency above 100 ㎑, it is desirable for optical applications because of low dielectric loss at low frequency. From Arrhenius plot of temperature, the activation energy was calculated to 0.45-0.49 eV.

Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation (장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰)

  • Jeon, Han-Yong;Jang, Yeon-Soo;Gong, Hak-Bong
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.222-232
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    • 2009
  • In this study, the real site test conditions were considered and applied to suggest the improved test method for geosynthetics chemical resistance. For this, index and performance tests were done to specify and regulate the more approached test method. Accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through analysis and comparison the overall experimental results, we could suggest the possibility and setup the advanced chemical resistance test method for geosynthetics.

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The investigation of Magnetohydrodynamic nanofluid flow with Arrhenius energy activation

  • Sharif, Humaira;Khadimallah, Mohamed A.;Naeem, Muhammad Nawaz;Hussain, Muzamal;Mahmoud, S.R.;Al-Basyouni, K.S.;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.10 no.5
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    • pp.437-448
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    • 2021
  • In this article, an analytically and numerically 3D nanoliquid flow by a porous rotatable disk is presented in the presence of gyrotactic microorganisms. The mathematical model in the form of partial differential system is transmuted into dimensionless form by utilizing the appropriate transformation. The homotopy analysis approach is applied to attain the analytic solution of the problem. The effect of promising parameters on velocity distribution, temperature profile, nanoparticles volume fraction and motile microorganism distribution field are evaluated through graphs and in tabular form. The existence of Brownian motion and thermophoresis impacts are more proficient for heat transfer enhancement. Further the unique features like heat absorption/generation and energy activation are also examined for the present flow problem. The obtained results are compared with the earliear investigation to check the accuracy of present model.

A Study of Life about Naturally Aged Nitrocellulose by Storage (자연 노화된 니트로셀룰로오스의 수명에 관한 연구)

  • Kim, Dong-seong;Jin, Hong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.595-601
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    • 2020
  • During the safety inspection of nitrocellulose-made explosive containers stored for more than 10 years, cracks were found in the containers. Therefore, a failure cause analysis test was performed. First, the cause of failure through the failure tree analysis was conducted to select the factors that influenced failure. The changes in the properties of the container caused by the acceleration of the reaction were found to be the cause of the failure by confirming the influence on the environment and internal/external factors that may occur during storage. To confirm this, environmental tests, such as thermal shock test and vacuum thermal stability test, were performed using a naturally aged container to analyze the cause of failure, and an accelerated aging test was performed to reproduce the failure. Through this, the chemical reaction was accelerated by heat and charge, as in the result of the fault tree analysis, and it was confirmed that the physical properties of the container were changed. In addition, the service life of the container was estimated using the Arrhenius model for the storage life due to thermal aging.

Compounding and Test of Gasket Rubber for Fuel Cell Stack Application (연료전지 스택 가스켓용 고무재료의 제조와 평가)

  • Hur, Byung-Ki;Kang, Dong-Gug;Kim, Hye-Young;Seo, Kwan-Ho;Park, Lee-Soon
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.232-237
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    • 2007
  • We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

A three-dimensional patent evaluation model that considers the factors for calculating the internal and external value of a patent: Arrhenius chemical reaction kinetics-based patent lifespan prediction (특허의 내적.외적 가치산정요인을 고려한 입체적 특허평가모델: 아레니우스 화학반응속도론 기반의 특허수명예측)

  • Choi, Yong Muk;LEE, JAEWON;Cho, Daemyeong
    • Journal of Digital Convergence
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    • v.19 no.6
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    • pp.113-132
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    • 2021
  • This study is a new evaluation using the Arrhenius equation, which is known as the chemical reaction rate estimation equation, to evaluate the intrinsic and extrinsic value elements of patents as a model. The performance of the evaluation model was superior to the SVM, Logistic reg. and ANN models that were used as patent evaluation models in prior studies. In addition, there was a strong correlation between the predicted lifespan of the patent and the actual lifespan of the patent. These evaluation models may be used for evaluation purposes only, or if an evaluation is required, including a commercialization entity or technical characteristics.

Shelf-life prediction of fresh ginseng packaged with plastic films based on a kinetic model and multivariate accelerated shelf-life testing

  • Jong-Jin Park;Jeong-Hee Choi;Kee-Jai Park;Jeong-Seok Cho;Dae-Yong Yun;Jeong-Ho Lim
    • Food Science and Preservation
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    • v.30 no.4
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    • pp.573-588
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    • 2023
  • The purpose of this study was to monitor changes in the quality of ginseng and predict its shelf-life. As the storage period of ginseng increased, some quality indicators, such as water-soluble pectin (WSP), CDTA-soluble pectin (CSP), cellulose, weight loss, and microbial growth increased, while others (Na2CO3-soluble pectin/NSP, hemicellulose, starch, and firmness) decreased. Principal component analysis (PCA) was performed using the quality attribute data and the principal component 1 (PC1) scores extracted from the PCA results were applied to the multivariate analysis. The reaction rate at different temperatures and the temperature dependence of the reaction rate were determined using kinetic and Arrhenius models, respectively. Among the kinetic models, zeroth-order models with cellulose and a PC1 score provided an adequate fit for reaction rate estimation. Hence, the prediction model was constructed by applying the cellulose and PC1 scores to the zeroth-order kinetic and Arrhenius models. The prediction model with PC1 score showed higher R2 values (0.877-0.919) than those of cellulose (0.797-0.863), indicating that multivariate analysis using PC1 score is more accurate for the shelf-life prediction of ginseng. The predicted shelf-life using the multivariate accelerated shelf-life test at 5, 20, and 35℃ was 40, 16, and 7 days, respectively.

An improvement on the concrete exothermic models considering self-temperature duration

  • Zhu, Zhenyang;Chen, Weimin;Qiang, Sheng;Zhang, Guoxin;Liu, Youzhi
    • Computers and Concrete
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    • v.19 no.6
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    • pp.659-666
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    • 2017
  • Based on the Arrhenius equations, several hydration exothermic models that precisely calculate the influence of concrete's self-temperature duration on its hydration exothermic rate have been presented. However, the models' convergence is difficult to achieve when applied to engineering projects, especially when the activation energy of the Arrhenius equation is precisely considered. Thus, the models' convergence performance should be improved. To solve this problem and apply the model to engineering projects, the relationship between fast iteration and proper expression forms of the adiabatic temperature rise, the coupling relationship between the pipe-cooling and hydration exothermic models, and the influence of concrete's self-temperature duration on its mechanical properties were studied. Based on these results, the rapid convergence of the hydration exothermic model and its coupling with pipe-cooling models were achieved. The calculation results for a particular engineering project show that the improved concrete hydration exothermic model and the corresponding mechanical model can be suitably applied to engineering projects.

Computation of Ionic Conductivity at NASICON Solid Electrolyte (III) Na1$\longrightarrow$mid-Na$\longrightarrow$Na2 Conduction Paths (NASICON 고체 전해질의 이온 전도도 계산 (III) 전도경로가 Na1$\longrightarrow$mid-Na$\longrightarrow$Na2인경우)

  • 최진삼;서양곤;강은태
    • Journal of the Korean Ceramic Society
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    • v.33 no.6
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    • pp.645-652
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    • 1996
  • The ionic conductivity of NASICON (Na Super Ionic Conductor) solid electrolyte was simulated by using Monte Carlo Method (MCM)based on a hopping model. We assumed that the conduction path of Na ions is Na1→mid-Na→Na2 where the mid-Na sites are shallow potential sites to induce 'a breathing-like movement' of Na ions in the NASICON framework. The minimum of charge correlation factor Fc and the maximum of appeared at nearby x=2.0 The occupancy of mid-Na site affected the depth of potential barrier and the conduc-tivity of the NASICON. At above x=0.3 ln σT vs. 1/T* plots have been shown Arrhenius behavior but in (VWfc)vs. 1/T* have been shown the Arrhenius type tendency at x=1 MCM results accorded with the experi-mental procedure. The role of mid-Na on Na+ ion conduction could be explained by an additional driving force and a breating-like movement model for motions of Na+ ions in the NASICON framework. As we couldn't clearly remarked the model which is the better it seems reasonable to conclude that these hypothesies are suitable to explain the FIC behavior at NASICON.

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