• Carbon letters
• /
• v.11 no.3
• /
• pp.184-191
• /
• 2010

Carbon nanotubes are unique tubular structures of nanometer diameter and large length/diameter ratio. The nanotubes may consist of one up to tens and hundreds of concentric shells of carbons with adjacent shells separation of ~0.34 nm. Multiwalled carbon nanotubes were synthesized by arc-discharge technique. MWCNTs were formed at the cathode deposit along with other carbonaceous materials like amorphous carbon, graphite etc. However, to get the best advantage of carbon nanotubes in various advanced applications, these undesired carbonaceous materials to be removed which is a challenging task. In the present study, various techniques were tried out for purifying MWCNTs such as physical filtration, chemical treatment and thermal annealing. SEM, FTIR, TGA and BET techniques were used to characterize the CNTs at various stages. Results shows that suitable chemical treatment followed by thermal annealing under controlled flow of oxygen gives the better route for purification of carbon nanotubes.

• The Transactions of the Korean Institute of Electrical Engineers B
• /
• v.51 no.9
• /
• pp.522-529
• /
• 2002

In this paper, computer simulations of the physical Phenomena occurring in the arc region before and after current zero were carried out to evaluate the thermal recovery characteristics of a Laval nozzle. A commercial CFD program "PHOENICS" is used for the simulation and the user-coded subroutines to consider the arcing phenomena were added to this program by the authors. The computed results were verified by the comparison with the test results presented by the research group of GE Co.(General Electric Company). In order to investigate the state of the arc region after current zero, the simulation was carried out with three steps. They are steady state arc simulation, transient arc simulation before current zero, and transient hot-gas flow simulation after current zero. The semi-experimental arc radiation model is adapted to consider the radiation energy transport and Prandtl's mixing length model is employed as the turbulence model. The electric field and the magnetic field were calculated with the same grid structure used for the simulation of the flow field. The post-arc current was calculated to evaluate the thermal recovery characteristics after current zero. Compared with the results obtained by GE Co., it has been found that the critical RRRV(ratio of rise of recovery voltage) will be determined previously by this study.his study.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2506-2511
• /
• 2007

The coupled simulation is performed to find out the interaction of arc plasmas with surrounding materials in a thermal puffer plasma chamber. In order to be more realistic, PTFE nozzle ablation and Cu electrode evaporation, which are caused by high temperature of arc plasmas, are considered together. Pressure rise and temperature inside the chamber generated during the whole arcing history are investigated with the applied currents. It is very important to define how thermal flow and mass transfer are processing between the arc plasma and surrounding materials for further understanding complex physics inside the chamber. It is concluded that the result might be very useful to understand the mechanism happened inside and to design thermal puffer plasma chambers, but further experimental studies are required to verify the results for the more practical applications.

• Journal of the Korean Society of Safety
• /
• v.16 no.2
• /
• pp.75-79
• /
• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.22 no.4
• /
• pp.55-60
• /
• 2018

The thermal property is one of the most important characteristics in the field of energetic materials. Because energy materials release decomposition heat, differential scanning calorimetry (DSC) is frequently used for thermal analysis. However, thermodynamic events, such as melting can interfere with DSC kinetic analysis. In this study, we use isothermal mode for DSC measurement to avoid thermodynamic issues. We also merge accelerating rate calorimetry(ARC) data with DSC data to obtain a robust prediction results for small scale samples and for large scale samples as well. For the thermal property prediction, advanced kinetics and technology solutions(AKTS) programs are used.

• The Transactions of the Korean Institute of Electrical Engineers
• /
• v.45 no.3
• /
• pp.415-425
• /
• 1996

This study presents an analytical method of solving the behaviors of arc plasma in a nozzle constricting transferred-type torch and purposes to obtain the basic data for the design of a plasma torch, which can be obtained from the temperature, pressure, velocities and voltage distributions. We have to solve some conservation equations simultaneously and need to know the exact thermal gas properties in order to obtain the correct behaviors of arc plasma. It is also necessary to give the relevant physical or geometric boundary conditions. For the simplicity of analysis, we assumed that (a) the plasma flow is laminar, (b)the local thermodynamic equilibrium, i.e. LTE, prevails over the entire arc column region. The electrode sheath effects were neglected and the nozzle area was excluded from the analysis by assuming that the current flow into the nozzle is zero. We solved the momentum transfer equation including the self-magnetic pinch effect, and obtained the temperature distribution from the energy conservation equation. From this temperature, we could get arc voltage distribution. (author). refs., figs., tabs.

• Bulletin of the Society of Naval Architects of Korea
• /
• v.14 no.3
• /
• pp.5-12
• /
• 1977

In shipyard production processes, lots of steel plates are assembled by welding. Some rectangular steel plates are buttwelded to build a large block in panel production lines. There are some advantages to take the tandem arc welding in butt joints of rectangular plates with respect to welding speed. Hence, the thermal stresses and the temperature distribution of the tandem arc welding are studied in this paper. The solutions in the case of the infinite plate with two instantaneous point heat sources have been obtained. And then the solutions have been extended to the case of two moving heat sources corresponding to the tandem arc welding with the aid of Duhamel's superposition integral. It was found that the temperature distribution was good agreement with the results of the experiments by Rosenthal and Park and the thermal stresses calculated were acceptable with respect to a physical phenomenon. These solutions are able to be applied to the problem such as a line heating.

• Proceedings of the KIEE Conference
• /
• 1998.07a
• /
• pp.167-169
• /
• 1998

Recently $SF_6$ gas circuit breakers utilizing the thermal-expansion principle are increasingly used in distribution power system. Active researches and developments have been conducted to reduce the size and weight, and to improve the interrupting performance of the circuit breakers. It was first developed a programme which could show the hot gas flowing into the thermal-expansion arc chamber. This programme, using so-called FLIC method basically, adopted 'Simplified Enthalpy Arc Model' which was somewhat modified to estimate the arc quenching process. The computation by it was compared with the measured results of the pressure rise in the chamber, and both showed fairly good agreement.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.22 no.2
• /
• pp.59-65
• /
• 2018

We conducted an isothermal slow cook-off(ISCO) test for an aluminized explosive containing AP. The sample bulged before the run-away reaction, and therefore we were unable to obtain the ISCO data. However, these phenomena did not occur for a certain AP grade, which means that the quality of the AP exerted a significant effect on the thermal stability of the explosive formulation. In this study, we investigated the thermal stability difference between a good and bad AP grade. First, we characterized the thermal properties of all APs by Differential Scanning Calorimeter(DSC) and correlated them to the ISCO phenomena. In addition to the DSC study and ISCO test, we also investigated and calculated the SADT and self-heating rate by the ARC of the different AP qualities to interpret the thermal stability of the explosive formulation. Moreover, we investigated the impurity of the AP and a preparation method to remove the included impurity and crystallization. Finally, we implemented qualification methods to identify the quality of AP by DSC using a high-pressure crucible.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2020.11a
• /
• pp.52-53
• /
• 2020

The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.