• Journal of the Korea Concrete Institute
• /
• v.25 no.6
• /
• pp.621-630
• /
• 2013

Several techniques for steel corrosion detection are proposed and HCP (half cell potential) technique is widely adopted for field investigation. If concrete has cracks on surface, steel corrosion is rapidly accelerated due to additional intrusion of chloride and carbon dioxide ions. This study is for an evaluation of HCP in cracked concrete exposed chloride attack. For this work, RC (reinforced concrete) beams are prepared considering 3 w/c ratios (0.35, 0.55, and 0.70) and several cover depths (10~60 mm) and various crack widths of 0.0~1.0 mm are induced. For 35 days, SST (salt spraying test) is performed for corrosion acceleration, and HCP and corrosion length of rebar are evaluated. With increasing crack width, w/c ratios, and decreasing cover depth, HCP measurements increase. HCP evaluation technique is proposed considering the effects of w/c ratios, crack width, and cover depth. Furthermore anti-corrosive cover depths are obtained through Life365 program and the results are compared with those from this study. The results shows relatively big difference in cracked concrete, however provide similar anti-corrosive conditions in sound concrete.

• Journal of Wind Energy
• /
• v.15 no.1
• /
• pp.82-90
• /
• 2024

Bio-fouling has positive aspects that are used as a fish resource, but there are also negative aspects such as corrosion of the surface of the support structure, aesthetics and work safety problems. A specimen was produced using a polyurea material with excellent anti-fouling and methodology, and contact angle, high water pressure, adhesion, and real sea area tests were performed. As a result of measuring the contact angle of the specimen with a 10 cm x 10 cm area of polyurea, There was found to be an average of 124.4 ° at nine points. No surface damage was found even above 5 Mpa when high water pressure was sprayed, and adhesive strength of 300LSE adhesives was confirmed between 22.84 and 23.04 Mpa with an adhesion test. During the 6-month real sea area test, it was confirmed that about 17.24 % of the polyurea film was less generated than the comparison group.

• Journal of the Korean Society of Safety
• /
• v.24 no.6
• /
• pp.150-156
• /
• 2009

The oil pressure switch(OPS) for automobile is very important part to prevent an overheated engine and other problems by checking the operation of an engine oil system and displaying oil signs on a dashboard. OPS is the part that receives various stress caused by temperature, vibration, and corrosion in an engine room. Regarding existing steel OPS cases, there occur field errors due to the rust, and much concern comes from the low anticorrosion caused by CR6+ Free according to the restrictions of heavy metals. Therefore, the study analyzed average life, the failure rate, and reliability through the tests of performance according to temperature changes, mechanical strength, and run-test in order to confirm if the use of the oil pressure switch with Al of anti-corrosion can improves the reliability, instead of the existing steel products.

• Plant Journal
• /
• v.6 no.4
• /
• pp.63-71
• /
• 2010

The best way to prevent the corrosion of piston rod is a selection of quality of the material and method of construction which minimize the porosity. The high velocity oxy fuel(HVOF) method, which generates lower porosity than existing plasma spray, was applied to ceramic laminated bond layer. Porosity percentage fell to bellow 2%, lower than that of plasma spray at 7%. Coating material of ceramic-coated main layer was selected as the $Cr_2O_3$ affiliation material, which is more dense than $Al_2O_3$ affiliation. To fill up the pores formed after the coating process, we sealed the bond layer and main layer. Sealing process was performed twice, once after the coating and once after the grinding. Upon the anti-corrosion test on the sealed sample and on the non-sealed sample, it is confirmed that the sealed sample was not corroded for 1,000 hours while the non-sealed sample was corroded within 48 hours.

• Journal of the Korean institute of surface engineering
• /
• v.25 no.5
• /
• pp.263-269
• /
• 1992

To enhancing efficiency of hard chrome plating solution more highly, cathode current efficiency were surveyed connected with hardness of deposits, surface morphology, TEM analysis and corrosion test of anode materials. Efficiency war increased up to 26% values by adding catalyst and two kind of additives. With given bath composition and 6$0^{\circ}C$, 60A/d$\m^2$ electrolosis conditionss bright and micro cracked deposits were well obtained, which showed HV 1000 values. From corrosion tests, anode materials such as Pb-Te (0.02%) and Pb-Ag(1%) showed most anti-corrosive results. Through SEM micrograph observations, ef-fects of additives on levelling, brightness and micro crack properties of hard chrome deposits could be con-firmed. Also, through TEM analysis the fact that deposits from crack free solution or high speed solution were more fine than from sargent solution could be confirmed.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2007.04a
• /
• pp.153-154
• /
• 2007

Mg thin films were prepared by PVD method on electroplated Zn steel substrate. And the influence of gas pressure on their morphology and crystal orientation of the deposited films were investigated by scannig electron microscopy(SEM) and X-ray diffraction(XRD), respectively. In addition, the effect of corrosion resistance of these films as a funtion of morphology and crystal orientation was evaluated by anodic polarization test. From the measured results, it is investigated that the film of granular structure which deposited in condition of high gas pressure had the highest corrosion resistance.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.2
• /
• pp.619-626
• /
• 2020

The development of new antifreeze mixtures containing non-amine-type corrosion inhibitors, which considers environmental protection, has become a major issue. In this study, four non-amine-type corrosion inhibitors were synthesized and used to produce five kinds of new antifreeze for automobiles to evaluate the rate of copper corrosion. The effects were evaluated by the weight change, surface observation, roughness measurement, and measurement of copper elution in the solution. The amount of copper eluted measured by ICP from Sample 4 was small, and the elution rate was prolonged. Sample 4 showed the best anti-corrosion performance owing to a corrosion suppression effect by passivating copper because the metal surface was smooth after the test, and the corrosion product layer was formed evenly on the surface as small local corrosion was observed. The major corrosion inhibitor added to Sample 4 was 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole, which contained a certain amount in Sample 5 to show relatively high local corrosion but passivation in progress. Therefore, among the four corrosion inhibitors, 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole had the highest corrosion inhibitory effect. This corrosion inhibitor prevents corrosion by promoting the passivation of copper on the antifreeze.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.153-153
• /
• 2016

Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2017.05a
• /
• pp.77-77
• /
• 2017

Titanium and its alloys offer attractive properties in a variety of applications. These are widely used for the field of biomedical implants because of its good biocompatibility and high corrosion resistance. Titanium anodizing is often used in the metal finishing of products, especially those can be used in the medical devices with dense oxide surface. Based on SAE/AMS (Society of Automotive Engineers/Aerospace Material Specification) 2488D, it has the specification for industrial titanium anodizing that have three different types of titanium anodization as following: Type I is used as a coating for elevated temperature forming; Type II is used as an anti-galling coating without additional lubrication or as a pre-treatment for improving adherence of film lubricants; Type III is used as a treatment to produce a spectrum of surface colours on titanium. In this study, we have focused on Type II anodization for the medical (dental and orthopedic) application, the anodized surface was modified with gray color under alkaline electrolyte. The surface characteristics were analyzed with Focused Ion Beam (FIB), Scanning Electron Microscopy (SEM), surface roughness, Vickers hardness, three point bending test, biocompatibility, and corrosion (potentiodynamic) test. The Ti-6Al-4V alloy was used for specimen, the anodizing procedure was conducted in alkaline solution (NaOH based, pH>13). Applied voltage was range between 20 V to 40 V until the ampere to be zero. As results, the surface characteristics of anodic oxide layer were analyzed with SEM, the dissecting layer was fabricated with FIB method prior to analyze surface. The surface roughness was measured by arithmetic mean deviation of the roughness profile (Ra). The Vickers hardness was obtained with Vickers hardness tester, indentation was repeated for 5 times on each sample, and the three point bending property was verified by yield load values. In order to determine the corrosion resistance for the corrosion rate, the potentiodynamic test was performed for each specimen. The biological safety assessment was analyzed by cytotoxic and pyrogen test. Through FIB feature of anodic surfaces, the thickness of oxide layer was 1.1 um. The surface roughness, Vickers hardness, bending yield, and corrosion resistance of the anodized specimen were shown higher value than those of non-treated specimen. Also we could verify that there was no significant issues from cytotoxicity and pyrogen test.

• Journal of the Korean institute of surface engineering
• /
• v.51 no.3
• /
• pp.172-178
• /
• 2018

In this paper, effects of potassium permanganate, pottasium dichromate, sodium molybdate on lean duplex stainless steel were studied by GDOES, OCP, potentiodynamic curves. The stainless steels were chemically passivated in each nitric acid solutions containing 4wt.% oxidants for 1 hour. As a result, when potassium dichromate or sodium molybdate was added, content of Fe was decreased and content of Cr was increased. Consequently, corrosion resistance of passive film was increased. But in case of potassium permanganate was added, contrastively, content of Fe was increased and content of Cr was decreased. So corrosion resistance was decreased. Adding sodium molybdate in nitric acid for chemical surface treatment process was the most effective among oxidants and also it showed the most stable anti-corrosion in SST.