• Title/Summary/Keyword: anodized layer amount

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Effects of structure and morphology of anodized Al thin film on magnetic properties (알루미늄 양극산화 피막의 구조 및 형상이 자기적 특성에 미치는 영향)

  • 권용덕;박용수
    • Journal of the Korean institute of surface engineering
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    • v.26 no.2
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    • pp.45-54
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    • 1993
  • In this study, magnetic properties of anodized Al film deposited with ferro-magnetic metals in the capacity of perpendicular magnetic recording media were measured and evaluated to find out the role of structure and morphology of the oxide films on magnetic characteristics. The object of this work was to present the conditions of magnetic thin film formation with more superior magnetic property. Anodizing was carried out under various conditions, and then the anodized film were electro-deposited with Co, Ni, Fe and their alloys. Coercive force and residual magnetization in perpendicular direction increased as the pore length of anodized film increased. It was attributed to the increase of the amount of depoisted metals and the ratio of length/diameter of pores. Morphology of anodized films in phosperic acid was not similar to that of sulfuric acid, and thin films in the former solution had perpendcular magnetic anisostropy because of large diameter, irregular length and distribution of the pores. It was found that magnetic properties of the thin films, which had doubled layer of two metals, were dominated by the metal electrodeposited on the surface of the anodized oxide films.

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The Study on the Surface Structure of Domestic CTP Thermal Plate (국산 CTP Thermal Plate의 표면 구조에 관한 연구)

  • Ha, Young-Baeck;Oh, Sung-Sang;Kang, Hyoung-Gon;Yoo, Keun-Ryong;Lee, Jae-Su
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.2
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    • pp.59-70
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    • 2011
  • Even though we could not count the total amount of plates in Korean printing industry per year, we would suppose the total amount of plates about $20,000km^2$ to $22,000km^2$ per year through our printing experience. On the standard of the end of 2010, it would be the market share of plates are that CTP plate is $9,000km^2$, CTcP plate is$4,000km^2$ and PS plate is $9,000km^2$, such as total amount of plates are $22,000km^2$. When there was no installed CTP setter in Korea, the domestic plate would be over 60% market share of plate in Korean printing industry. But now it would be less than 25% market share of plate. It is necessary to develop domestic CTP thermal plate from now because we have to keep the market share of domestic plate. On the study of the surface structure of substrate, roughness, anodized layer amount and coating amount between domestic CTP thermal plate and foreign CTP thermal plate, it would be the basic to develop domestic CTP thermal plate.

Fabrication of Crystalline $ZrO_2$ Nanotubes by ALD

  • Kim, Hyeon-Cheol;Panda, Sovan K.;Yu, Hyeon-Jun;Kim, Myeong-Jun;Yang, Yun-Jeong;Lee, Seon-Hui;Sin, Hyeon-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.241.1-241.1
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    • 2011
  • Numerous possible applications for $ZrO_2$ nanotubes exist such as for catalyst support structures, for sensing or for applications as a solid state electrolyte. Especially, because of a large specific surface area, high efficiency for solid oxide fuel cell (SOFC) application at low temperature can be expected for nanotublar structures in even small size. A zirconium precursor, Tetrakis (ethylmethylamino) zirconium, TEMAZr and $H_2O$ oxidant were used to deposit$ZrO_2$ thin films on an anodized aluminum oxide (AAO) templates having sub-100nm cylindrical pores by atomic layer deposition (ALD) in the temperature range of 150~250$^{\circ}C$. The crystalline structures of as-prepared and post-annealed $ZrO_2$ nanotubes were characterized by x-ray diffraction and high-resolution transmission electron microscopy. The as-prepared samples at $150^{\circ}C$ and $200^{\circ}C$ were showed amorphous, whereas a mixed phase of tetragonal, monoclinic and amorphous polymorph was observed at $250^{\circ}C$. In the bulk, zirconia remains monoclinic phase up to $1,175^{\circ}C$, however, $ZrO_2$ nanotubes were showed tetragonal phase upon post thermal treatments merely at $400^{\circ}C$. This trend may be indicative of high-curvature surfaces of nanotubes and thereby the presence of intrinsic compressive strain. The amount of amorphous structures in the mixed phase as well as as-grown $ZrO_2$ nanotubes were also gradually decreased by subsequent heat treatment.

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