• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1994년도 추계 학술발표회
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• pp.135-136
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• 1994

Anionic water dispersible copolyesters were synthesized by the polycon-densation of dimethyl isophathalate/5-sodium sulfo dimethyl isophathalate with ethylene glycol/diethylene glycol. Structrual analyses such as NMR, Irm WAXD analyses were done and copolyesters were found to be correctly synthesized. Relation between feed ratio and composition ratio of EG/DEG in copolyesters was confirmed by NMR analysis. Solubility test was done to find out optimum conditon of DMS feed ration of 10 mol% in dimethyl esters. Water resistance of copolyesters decreased with the increase of DMS or DEG molar feed ratio.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 1994년도 추계 학술발표회
• /
• pp.137-138
• /
• 1994

Anionic water dispersible copolyesters were synthesized and characterized. Viscosity of the copolyester is lower than that of routine acrylic water dispersible polymers. Adhesive force of the copolyester was much higher than that of water dispersible acrylic polymers. Particle size of the copolyesters in water decreased with the increase of DMS or DEG feed ratio. With the conclusive study of the data of particle size and potential, it was found that the dispersion stability of copolyesters in water increased with the increase of DMS or DEG feed ratio. Judging from the results of potential and particle size of copolyesters, there seems to be competition between two dispersion stability factors, i.e. electrostatic stabilization and steric stabilization and as a result, morphological change of particles occurrs. Tg decreased with the increase of DEG molar feed ratio or oil contents.