• Title/Summary/Keyword: anion size

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Preparation and Application of Pore-filled PVDF ion Exchange Membranes (Pore-filled PVDF 이온교환막의 제조 및 응용)

  • 변홍식;박병규;홍병표;여광수;윤무홍;강남주
    • Membrane Journal
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    • v.14 no.2
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    • pp.108-116
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    • 2004
  • In this study, the pore-filled ion-exchange membranes were prepared by using the asymmetric PVDF membrane as a nascent membrane. First, the solution of PVBCI having the chlorornethylate aryl ring of 80 percents and DABCO was made with the mixed solvent of THF and DU (8:2). These mixed solution was then, filled in the pores of PVDF membrane, and left for a day to complete the gelation. Finally the pore-filled anion-exchange membrane is obtained fallowed by the amination of the remaining chloromethyl groups with trimethylamine (TMA, 40 wt% in water) forming the positive ammonium ion sites. This 2 step procedure enabled us to produce the pore-filled membranes without change of size, and to control the properties of final membrane with various degree of cross-linking. The results of SEM and AFM showed the polyelectrolyte existed in the pores of nascent membrane as a certain configuration. From the investigation of the solvent affecting much to the permeability and rejection, it was found that the membranes using mixed solvent of THE and DMF (8:2) showed better performances than the membranes produced by THF only. The result of an investigation for the water permeability of the final membrane at low pressure (100 Kpa) showed a typical ultrafiltration membrane's permeability (8 ∼ 10 kg/$m^2$hr) and good values of rejection (55∼60 percent).

Characteristics of the soil loss and soil salinity of upland soil in saemangeum reclaimed land in western South Korea

  • Kim, Young Joo;Lee, Su Hwan;Ryu, Jin Hee;Oh, Yang Yeol;Lee, Jeong Tae
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.316-316
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    • 2017
  • The objective of this study is to estimate quantitatively soil salinity and soil loss at upland soils in agriculture land region in Saemangeum reclaimed land on the south Korea coasts. Soil loss and soil salinity are the most critical problem at reclaimed tidal saline soil in Korea. The several thematic maps of research area such as land cover map, topographic and soil maps, together with tabular precipitation data used for soil erosion and soil salinity calculation. Meteorological data were measured directly as air temperature, wind speed, solar radiation, and precipitation. The experiment was conducted 2% sloped lysimeter ($5.0m{\times}20.0m$) with 14 treatments and it were separated by low salinity division (LSD) and high salinity division (HSD) install. The cation content in ground water increased during time course, but in the case of land surface water the content was variable, and $K^+$ was lower than that of $Na^+$ and $Mg^{2+}$. At the LSD under rainproof condition, the salinity was directly proportional to soil water content, but at the HSD the tendency was no reversed. In condition of rainproof, the amount of soil salinity was higher at the HSD than at the LSD. Positive correlation was obtained between the soil water content and available phosphorous content at the rainfall division, but there was no significance at the surface soil of the rainproof division. Sodium adsorption ratio and anion contents in soil were repressed in the order of vinyl-mulching > non-mulching > bare field. According to the result of analyzing soil loss, soil loss occurred in a vinyl-mulching, a non-mulching and a bare field in size order, and also approximately 11.2 ton/ha soil loss happened on the reclaimed land area. The average soil loss amount by the unit area takes place in a non-mulching and bare field a lot. Our results indicate that soluble salt control and soil erosion are critical at reclaimed tidal saline soil and the results can provide some useful information for deciding management plans to reduce soil loss and salt damage for stable crop production and diverse utilization or cultivation could be one of the management options to alleviate salt damage at reclaimed tidal saline soil in Korea.

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Studies on the Separation of Immunoglobulin and Immunological Response from Korean Native Cattle (한우초유중 Ig의 분리 ${\cdot}$ 정제 및 면역 반응에 관한 연구)

  • Baick, Seung-Cheon;Kim, Yong-Hwi;Shin, Je-Ho;Yu, Je-Hyeon
    • Journal of Dairy Science and Biotechnology
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    • v.15 no.1
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    • pp.1-9
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    • 1997
  • This study was conducted to efficiently separate the Ig from Korean native cattle colostrum and to utilize them as an immunogen for the production of antibodies aginst rabbit. The results obtained were as follows : 1. About 84% of Ig G could be separated from Korean native cattle colostrum by·gel filtration using Superose 12 column on HPLC. The separation profile of Korean native cattle colostral immunoglobulin was similar that of Holstein colostral Ig. 2. Separation of Korean native cattle colostral Ig by anion exchange chromatography using Mono Q column on HPLC was poor resolution chromatographic pattern. 3. Hi-Trap Protein G column showed better results than the Protein A Sepharose CL-4B column in the Ig G binding capacity from Korean native cattle colostral Ig. 4. Protein G Sepharose Fast Flow system resulted in higher Ig g binding capacity as the industrial size scale-up approach. 5. Sufficient titer reaction of antibody to Korean native cattle colostral Ig G was confirmed by ELISA.

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Preparation and Properties of Aminated Poly(ethersulfone) Ion-Exchange Membrane by UV Irradiation Method (UV 조사에 의한 아민화 Poly(ethersulfone) 이온교환막의 제조 및 특성)

  • Choi, Kuk-Jong;Hwan, Eui-Hwan;Rhee, Young-Woo;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.70-76
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    • 2008
  • The PES-g-BTCA membrane was synthesized by UV irradiation method and then used to be modified into the PES anion exchange membrane by the amination reaction. Their chemical structures and adsorption properties were investigated. The degree of grafting and amination were increased with increasing the reaction time and had the maximum values of 138% and 1.20 mmol/g at 80 min, respectively. The initial thermal degradation temperature of PES membrane was $400^{\circ}C$. Which was reduced as the surface modification reaction had proceeded. The values of contact angle for PES membrane were decreased from 68.1 to $40.2^{\circ}$ with increasing the extent of amination, the water up-take and ion exchange capacity were also increased with increasing UV irradiation time until 80 min. The average pore size and BET surface area were decreased in order of PES, PES-g-BTCA, and aminated PES ion exchange membrane. Their average pore sizes were 624.8, 359.7, and 138.5 ${\AA}$, and their surface areas were 10.1,9.7 and 1.7 $m^2/g$, respectively.

Environmental Geological Characteristics of Suspended Matter and Turbidity Water at Gachang Dam in 2004 (2004년 가창댐 탁수의 원인과 부유물질의 환경지질학적 특징)

  • Choo Chang-Oh;Koh Eun-Young;Oh Soo-Jiu;Lee Seong-Woo;Kim Byoung-Ki;Lee Ji-Eun;Kim Yeong-Kyoo
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.1 s.47
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    • pp.49-61
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    • 2006
  • This study was undertaken to investigate the origin of suspended matter to induce turbidity water in Gachang dam in view of environmental geology. During the period from May to August 2004, field works and sampling were carried out three times at the dam and along its streams, and chemical and mineralogical analyses such as ICP, IC, particle size analyzer, XRD and SEM were made on water, soil and suspended matter in water. Electrical conductivity (EC), turbidity, the contents of cation and anion increase from upstream toward the dam mostly due to the geological factors such as weathring of the rocks causing the increase of the total ion content. Vermiculite, illite, kaolinite, quartz, feldspar and iron hydroxide are commonly found in suspended matters in water and soils. Finer particles (d10) in soil increase slightly toward downstream and the vermiculite content is highest in the dam water. Since geological differences are not significant, mineralogy are similar in suspended matters and soils. Clay mineral compositions present in suspended matters were alsmost the same as those in soils, indicating the origin of soils by weathering of host rocks and being transported to the dam by stream water.

A Study of Properties and Coating Natural Mineral Pumice Powder of in Korea (한국산 천연 광물 부석 파우더 코팅 및 특성에 관한 연구)

  • Kim, In-Young;Noh, Ji-Min;Nam, Eun-Hee;Shin, Moon-Sam
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.498-506
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    • 2019
  • This study is based on a coating method that provides utilization value as a micronised powder for cosmetic raw materials using natural minerals buried in Bonghwa, Gyeongsangbuk-do in Korea. The mineral powder name is called Buseok, and chemical name is pumice powder. The results of a study on the efficacy of cosmetics are reported by the development of particulate powder to assess the performance of this powder. First of all, in order to coat the surface of this powder with oil, aluminum hydroxide was coated on the particulate surface and then coated with alkylsilan. In addition, it was coated with vegetable oil to prevent condensation of the powder and increase the dispersion in the oil phase. First; the particle size of pumice powder was from 10 to 50mm having porous holes on the surface of the particles. Second; The components of this powder contained $SiO_2$, $Al_2O_3$, $Fe_2O_3$, MgO, CaO, $K_2O_2$, $Na_2O$, $TiO_2$, $TiO_2$, MnO, $Cr_2O_3$, $V_2O_5$. Third: The particles of this powder have a planetary structure and are reddish-brown with porosity through SEM and TEM analysis. Fourth; the far-infrared radiation rate of this parabolic powder was $0.924{\mu}m$, and the radiative energy was $3.72{\times}102W/m^2$ and ${\mu}m$. In addition, the anion emission is 128 ION/cc, which shows that the coating remains unchanged. Based on these results, it is expected to be widely applied to basic cosmetics such as BB cream, cushion foundation, powderfect, and other color-coordinated cosmetics, sunblock cream, wash-off massage pack as an application of cosmetics. (Small and Medium Business Administration: S2601385)