• Title/Summary/Keyword: anion effect

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Effects of dietary cation and anion difference on eating, ruminal function and plasma leptin in goats under tropical condition

  • Nguyen, Thiet;Chanpongsang, Somchai;Chaiyabutr, Narongsak;Thammacharoen, Sumpun
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.6
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    • pp.941-948
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    • 2020
  • Objective: This study was carried out to determine the effects of elevated dietary cation and anion difference (DCAD) on dry matter intake (DMI) and ruminal fermentation pattern in lactating dairy goats under tropical conditions. Methods: Ten dairy goats were divided into two groups of five animals each. The groups received diets at different DCAD levels, either a control diet (22.81 mEq/100 g dry matter [DM], DCAD-23) or a DCAD-39 diet (39.08 mEq/100 g DM, DCAD-39). After parturition, DMI and water intake were recorded daily. Ruminal fluid and urine were collected, and nutrient digestibility measurements were carried out at 8th weeks postpartum (PP-8). Blood samples were collected at PP-4 and PP-8 to measure plasma leptin. Results: Dry matter intake/body weight (DMI/BW) at PP-8 of the animals fed the DCAD-39 diet was significantly higher than those fed with DCAD-23 diet (p<0.05). Animals fed with DCAD-39 consumed more water than those fed DCAD-23 over 24 h, particularly at night (p<0.05). Ruminal pH, acetate concentration, and urinary allantoin excretion increased with the DCAD-39 diet, whereas ruminal butyrate concentration was lower with the DCAD-39 diet. On the other hand, other ruminal parameters, such as total volatile fatty acid concentration, propionate molar proportion and acetate/propionate average ratio, were not affected by increased DCAD supplementation. Apparent digestibility was improved by increased DCAD supplementation. Plasma leptin concentration was higher with DCAD supplementation. Conclusion: When feeding goats with DCAD-39 under tropical conditions, an increase in DMI was associated with improved apparent digestibility of nutrients, ruminal fermentation and microbial protein synthesis. An increase in plasma leptin concentration could not explain the effect of high DCAD on DMI.

Effect of Current Density and pH of Electrolyte on Anion-Exchange Membrane Fouling (전류밀도와 전해질의 pH가 음이온교환막의 막 오염에 미치는 영향)

  • Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.965-969
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    • 2005
  • Current density is an important operating parameter in the ion-exchange membrane process. We observed the effects of fouling of a Neosepta AMX anion-exchange membrane(Tokuyama Soda, Japan) in 0.02 M NaCl solution containing 100 mg/L sodium humate. Membrane fouling was analyzed by measuring the change in the electrical resistance in the under- and over-limiting current density regions. The experimental results found that membrane fouling was negligible at under-limiting current densities, but was increased significantly when an over-limiting current was supplied. After the fouling experiments, the current-voltage curves for the fouled membranes were measured. From the curves, we observed increased electric resistance and reduced limiting current density(LCD), caused by the accumulation of humic acid on the membrane surface. Furthermore, membrane fouling increased as the acidity of the electrolyte solution containing humic acid increased. This occurred because the fouling of an anion-exchange membrane is affected more by the physicochemical properties of the humic substance than by the surface charge of the humate.

A Study on Ion Exchange Characteristics with Composition and Concentration of Electrolyte, Ratio of Ion Exchange Resin (전해질 성분 및 농도, 이온교환 수지 비율에 따른 이온교환 특성 연구)

  • Ahn Hyun-Kyoung;Rhee In-Hyoung;Yoon Hyoung-Jun;Jeong Hyun-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.4
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    • pp.727-732
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    • 2006
  • The object of this study was to investigate the influence of composition and concentration of electrolyte, ratio of cation to anion exchange resin of mixed ion exchange column in the performance of ion exchange. Also this work examined the removal capability of suspended solids by ion exchange resin and the effect of particule on the characteristics of ion exchange. Breakthrough time was extended as the amount of ions and particles present in liquid was decreased. The case of anion, the breakthrough sequence is $Cl^{-}, but the case of cation, the breakthrough sequence is $Na^{+}. As for the ratio of cation to anion exchange resin of 1:2, the breakthrough time was prolonged compared with that of 1:1 and 1:3. For the electrolyte of equal concentration containing suspended solid, breakthrough time was contracted less than 20%. It results in the increase in the removal capacity of cation exchange resin. For the higher ratio of cation exchange resin, suspended solids are shorten the cation's breakthrough time so that the runtime of ion exchange resin tower is increased.

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Effect of Protopanaxatriol Ginsenosides on the Blood Pressure and Endothelial Dysfunction In the Aorta of Spontaneously Hypertensive Rats (선천성 고혈압 렛드에서 혈압 및 내피의 기능장해에 대한 protopanaxatriol계 배당체의 효과)

  • 김낙두;김순회
    • Journal of Ginseng Research
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    • v.21 no.2
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    • pp.119-124
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    • 1997
  • Chronic hypertension is associated with impaired endothelial function such as reduced synthesis/release of endothelium-derived relaxing factor(EDRF, nitric oxide) and increased synthesis/release of endothelium-derived contracting factor(EDCF) including prostaglandin endoperoxide($PGH_2$) , superoxide anion both in animals and in humans. We have previously shown that ginsenosides lower the blood pressure and enhance the release of nitric oxide(NO) from endothelial cells in the rat aorta of the normotensive rats. The aim of the present study is to examine whether in vivo treatment of spontaneously hypertensive rats(SHRs) with protopanaxatriol ginsenosides(PPT) reduces the blood pressure and improves endothelial function in the isolated thoracic aorta of SHR. In addition, the contractile response to $PGH_2$ and superoxide anion in the aorta treated with PPT was assessed. SHRs at the age of 16 weeks were savaged with PPT(30 mg/kg/ day) for 2 weeks and systolic blood pressure was measured by the tail-cuff method. Whereas blood pressure was significantly increased in SHRs by 5.4 mmHg during this period of treatment, treatment of SHRs with PPT blocked the elevation of blood pressure. Endothelium-dependent relaxation to acetylcholine was significantly increased in the PPT-treated animals. $PGH_2$- and oxygen-derived free radical-induced contractions were significantly suppressed in aortic rings without endothelium from PPT-treated SHR. These findings indicate that PPT reduces the blood pressure of SHR, which may be associated with either increase of NO release or by antagonizing superoxide anion and PGH2 in the aortic smooth muscle.

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Improvement of Comfortability and Ability on Nonwoven Fabric for Disposable Work Clothing Using Yellow Soil Printing (황토 날염을 이용한 일회용 작업복 소재의 쾌적성 및 기능성 향상에 관한 연구)

  • Jung, Myung-Hee;Park, Soon-Ja;Koshiba, Tomoko;Tamura, Teruko;Shin, Jung-Sook
    • The Research Journal of the Costume Culture
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    • v.15 no.2 s.67
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    • pp.276-283
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    • 2007
  • The purpose of this study were to investigate characteristic changes on nonwoven fabric for disposable work clothes by the yellow soil printing. It separate grind yellow soil as two different size of particles $45\sim52{\mu}m$ and $53\sim65{\mu}m$ for hand screen printing on three kind of nonwoven fabrics. To examine the effect of yellow soil printing on nonwoven fabric were to observe, dyeability by using spectrophotometer, moisture regain by oven method, air permeability, anion property and antibacterial activity. The results were as follows: When yellow soil concentration increased from 5 to 10%, K/S value also increased from 1.05 to 1.88. When yellow soil concentration increased, moisture regain also increased. In same concentration, moisture regain occurred higher as particle of small size. Air permeability decreased when the charcoal printing concentration increased. Anion occurrence appeared $140\sim160ion/cc$ from three different kinds of nonwoven fabrics in 3% and 9% yellow soil concentration. Therefore, occurred anion ineffectively. In concentration of 3%, rate of deodorization measured as 89%, 83% and 87%, and 9% concentration caused 96%, 86% and 93% of high deodorization. Antibacterial activity examination in nonfinished nonwoven fabric resulted range of 60%, however, 3% and 9% concentration finished nonwoven fabric resulted 99.9% of excellent antibacterial activity Surface temperature increased $1.5\sim2^{\circ}C$ by yellow soil finishing.

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A Study of Selective Absorption of Metal Ions by Chelating Agent-Loaded Anion Exchange Resins (킬레이트 시약으로 처리한 음이온 교환수지에 의한 금속이온의 선택적 흡착에 관한 연구)

  • Lee Dai Woon;Lee, Won;Yu Euy Kyung
    • Journal of the Korean Chemical Society
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    • v.23 no.3
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    • pp.141-151
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    • 1979
  • The selective absorption of metal ions by chelating agent-loaded resins was studied in aqueous media. The resins were prepared by loading the conventional anion exchange resin, Dowex 1-X8 (50 to 100 mesh) with chelating agents containing sulfonic group, such as 8-hydroxy-quinoline-5-sulfonic acid (HQS) and 7-nitroso-8-hydroxyquinoline-5-sulfonic acid (NHQS). The stability of the resin was markedly influenced by the following factors; (1) the affinity and concentration of anions in the external solution, (2) the pH of the media. The optimum conditions for the absorption of metal ions were determined with respect to the pH, shaking time, and the effect of anion concentration in the medium. Under the optimum condition the order of the absorption of metal ions such as Fe(Ⅲ), Cu(Ⅱ), Pb(Ⅱ), and Zn(Ⅱ) was in accord with that of the stability constants of the chelates. The total capacities of the resins were found in the range of 0.6∼1.6 mmole metal per gram.

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The Experimental Study on Anti-oxidant and Anti-inflammatory Effect of Jogantanggagambang(JGTG) (조간탕가감방(調肝湯加減方)의 항산화활성(抗酸化活性) 및 항염증작용(抗炎症作用)에 대한 실험적(實驗的) 연구(硏究))

  • Byun, Hyung-Kuk;Yoo, Dong-Youl
    • The Journal of Korean Obstetrics and Gynecology
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    • v.21 no.2
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    • pp.76-96
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    • 2008
  • Purpose: This study was performed to evaluate anti-inflammatory effects of Jogantanggagambang(JGTG). Methods: In the study of anti-oxidant activities, JGTG was investigated by DPPH radical scavenger activity, superoxide dismutase activity and superoxide anion radical scavenger activity. In the study of anti-inflammatory effects, JGTG was investigated using cultured cells and murine models. As for the parameters of inflammation, levels of several inflammatory cytokines and chemical mediators which are known to be related to inflammation were measured in mouse lung fibroblast cells(mLFCs) and RAW264.7 cells. Results: 1. JGTG showed a safety in cytotoxicity and toxicity of liver. 2. JGTG effected scavenging activity on DPPH free radical, superoxide dismutase and superoxide anion radical. 3. JGTG in RAW 264.7 cell decreased IL-$1{\beta}$ mRNA expression, IL-6 mRNA expression, TNF-${\alpha}$ mRNA expression at 50, $100{\mu}g/m{\ell}$ and also decreased NOS-II mRNA expression at $100{\mu}g/m{\ell}$, and decreased COX-2 mRNA expression at 10, 50, $100{\mu}g/m{\ell}$. 4. JGTG in RAW 264.7 cell decreased significantly IL-$1{\beta}$, IL-6 and TNF-${\alpha}$ at 50, $100{\mu}g/m{\ell}$. 5. JGTG inhibited significantly IL-$1{\beta}$, IL-6 and TNF-${\alpha}$ production in serum of acute inflammation-induced mice. 6. JGTG decreased significantly IL-$1{\beta}$ mRNA production in spleen tissue. Conclusion: These results suggest that JGTG can be used for treating diverse female diseases caused by inflammation

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Study on the micellization of cetyltrimethyl ammonium bromide in 4-biphenyl acetate solution (4-biphenyl acetate 수용액에서 Cetyltrimethyl Ammonium Bromide의 미셀화에 관한 연구)

  • Oh, Jung Hee
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.107-116
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    • 1995
  • The critical micelle concentration(CMC) of CTAB was determined with changes in absorbance at 202nm band of 4-biphenyl acetate($BPA^-$). With $BPA^-$ as a probe, the effect of temperature on CMC of CTAB has been observed between $30^{\circ}C{\sim}70^{\circ}C$. In this range of temperature the values of CMC are $1.18{\times}10^{-4}{\sim}2.02{\times}10^{-4}M$. The free energy(${\Delta}G^{\circ}m$) and enthalpy(${\Delta}H^{\circ}m$)for the micellization of CTAB was negative and the entropy(${\Delta}S^{\circ}m$) was a large positive value. The micellization of CTAB is considered as a spontaneous process and to involve a phase transition. The orientational binding of 4-biphenyl acetate anion to the CTAB micelle interface has been studied with $300MHz\;H^1-NMR$ data. The change in chemical shift of proton in CTAB as well as those of the protons in $BPA^-$ have been investigated by increasing the mole fraction of the anion in the mixed solutions. The changes in chemical shift with increasing mole fraction of anion($BPA^-$) indicate the formation of mixed micelle between CTAB and $BPA^-$. The changes in chemical shifts of methylene protons in CTAB, demonstrate the penetration of $BPA^-$ into the palisade layer of the CTAB micelle.

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Adsorption Characteristics of Strong Basic Anion Exchanger to Cellulose Reactive Dye (강 염기성 음이온 교환수지의 셀룰로우스 섬유용 반응성 염료에 대한 흡착 특성)

  • Lim, Gyeong-Eun;Chung, Paul-gene;Kwon, Ji-Young
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.27-32
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    • 2007
  • This study focused on estimating the feasibility of a strong basic anion exchanger (PA312OH) as a sorbent for the removal of residual reactive dye and saving chemicals and water. Cellulose reactive dye C.I.RB49 was tested because reactive dye is the largest single group of dyes and that dye needs larger amount of inorganic salts as dyeing agent but nearly 50% of reactive dyes may be lost to the effluent. The adsorption characteristics of PA312OH for C.I.RB49 were as follows. Ion-selectivity among the dye and inorganic salts was Dye > ${SO_4}^{2-}$ > ${CO_3}^{2-}$ > $Cl^-$. C.I.RB49 was exchanged more than 3 times ${SO_4}^{2-}$ and ${CO_3}^{2-}$ and $Cl^-$ was not exchanged absolutely. The exchanging velocity was increased exponentially with increasing temperature. This result is positive effect on treating the high temperature dyeing process wastewater. The exchanged dye percents to initial were 96.8% and 99% at flow rate 20.5 mL/min. and 3.7 mL/min.. The exchanging capacity of PA312OH for C.I.RB49 was 215.2 mg/g at conc.=369.2 mg/L, Temp.=$25^{\circ}C$. 74% inorganic salts were recrystallized from real dark reactive color dyeing wastewater treated with PA312OH.

Separation and Purification for the Determination of Zirconium and Its Isotopes in PWR Spent Nuclear Fuels (PWR 사용후핵연료 중 Zr 및 Zr 동위원소 정량을 위한 분리 및 정제)

  • Kim, Jung Suk;Jeon, Young Shin;Park, Yong Joon;Lee, Chang Heon;Kim, Won Ho
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.421-428
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    • 1998
  • A method has been studied to separate Zr from various fission products in PWR spent nuclear fuels. A solution containing metal ions in place of radioactive fission products was prepared. The Zr was separated with 5 M HCl followed by eluting metal ions such as Ce, Nd, Cs, Rb, Ba, Sr, Ru, Rh, Pd, Ag and Cd with 12 M HCl on Dowex $1{\times}8$, anion exchange resin. The recovery of Zr was more than 95%. The purification of Zr was carried out on anion exchange resin, Dowex $1{\times}8$, in 5 M HCl in order to remove Mo causing isobaric effect during mass spectrometry. The method was applied to separate Zr from a spent PWR fuel. From mass spectrometric measurement, the purified Zr portion was not showed the isobars from other elements such as Mo and Sr.

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