• Journal of Sericultural and Entomological Science
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• v.39 no.2
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• pp.169-173
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• 1997

The behavior of tyrosine(Tyr.) residue of Bombyx mori silk fiber from yellow fluorescent cocoon has been examined for the dependence of pH in aqueous silk solution under the presence of orange II salt. Through the peak separation of angular dependence of spectral pattern of 15N-Tyr. and [1-13C]-Tyr. between the fiber axis and the molecular bond direction, N-H bond in fiber as well as the orientation distribution around the fiber axis were analyzed. Also, and sericin component was obtained from these angular dependence of oriented spectral pattern. The pH dependence of the 13C NMR chemical shift of B. mori silk fibroin was examined in aqueous solution in the presince of orange II are broad at pH$\geq$7.0. However, these become sharper at pH$\geq$8.0 and remain sharp at higher pH. In these higher pH range, a chemical shift change occurs due to the deprotonation of the Tyr. side group of fibroin. At higher pH. such a hydrophobic cluster is destroyed because of the electrostatic interaction according to the deprotonation of the Tyr-OH group.

• Journal of Magnetics
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• v.2 no.3
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• pp.101-104
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• 1997

Vector Moving Preisach model has been applied to the unoriented Co-based alloy thin film media. In the model, the out-of plane easy axis distribution of the particles was derived directly from the texture coefficient phkl obtained from XRD analysis, which corresponds to the fraction of the grains that have the {hkl} plane lying parallel to in-plane direction. The model was validated, by its prediction of a variety of responses, including major loop, minor loop, and the angular dependence of coercivities.

• Journal of Magnetics
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• v.21 no.1
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• pp.35-39
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• 2016

$Cr_{100-x}Ti_x$ amorphous texture-inducing layers (TIL) were investigated to realize highly (002) oriented $L1_0$ FePt-C granular films through hetero-epitaxial growth on the (002) textured bcc-$Cr_{80}Mn_{20}$ seed layer (bcc-SL). As-deposited TILs showed the amorphous phase in Ti content of $30{\leq}x(at%){\leq}75$. Particularly, films with $40{\leq}x{\leq}60$ kept the amorphous phase against the heat treatment over $600^{\circ}C$. It was found that preference of the crystallographic texture for bcc-SLs is directly affected by the structural phase of TILs. (002) crystallographic texture was realized in bcc-SLs deposited on the amorphous TILs ($40{\leq}x{\leq}70$), whereas (110) texture was formed in bcc-SLs overlying on crystalline TILs (x < 30 and x > 70). Correlation between the angular distribution of (002) crystal orientation of bcc-SL evaluated by full width at half maximum of (002) diffraction (FWHM) and a grain diameter of bcc-SL indicated that while the development of the lateral growth for bcc-SL grain reduces FWHM, crystallization of amorphous TILs hinders FWHM. $L1_0$ FePt-C granular films were fabricated under the substrate heating process over $600^{\circ}C$ with having different FWHM of bcc-SL. Hysteresis loops showed that squareness ($M_r/M_s$) of the films increased from 0.87 to 0.95 when FWHM of bcc-SL decreased from $13.7^{\circ}$ to $3.8^{\circ}$. It is suggested that the reduction of (002) FWHM affects to the overlying MgO film as well as FePt-C granular film by means of the hetero-epitaxial growth.

• Wind and Structures
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• v.14 no.2
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• pp.167-186
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• 2011

This paper presents the results of measurements relating to the aerodynamic forces on flat square plates which were allowed to rotate at different speeds about their horizontal axis, by modifying the velocity of the incoming flow. A 1 m square test-sheet and a 0.3 m square test-sheet were fitted with a number of pressure sensors in order to obtain information relating to the instantaneous pressure distribution acting on the test-sheet; a compact gyroscope to record the angular velocity during the rotational motion was also implemented. Previous work on autorotation has illustrated that the angular velocity varies with respect to the torque induced by the wind, the thickness and aspect ratio of the test-sheet, any frictional effects present at the bearings, and the vorticity generated through the interaction between the plate and the wind flow. The current paper sets out a method based on the solution of the equation of motion of a rotating plate which enables the determination of angular velocities on autorotating elements to be predicted. This approach is then used in conjunction with the experimental data in order to evaluate the damping introduced by the frictional effects at the bearings during steady autorotation.

• Progress in Superconductivity and Cryogenics
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• v.17 no.1
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• pp.6-9
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• 2015

For many applications of $ReBa_2Cu_3O_{7-x}$ (ReBCO) tapes it is needed to know the anisotropic properties of the used conductor in a broad range of magnetic field. In this paper we present the results of transport measurements on the SuNAM tape (GdBaCuO) with the rotation of the sample in magnetic fields up to 5 T in liquid nitrogen. The critical current over the magnetic field orientation ($I_c({\theta})$) curves demonstrate the appearance of distinct second peak around c-axis in low fields. This peak almost vanishes in the fields over 3 T. The evolution of the ab-peak form is also presented: the peak consistently reduces its height with the magnetic field going up and in the high fields the shoulders rise, changing the type of the distribution. To describe experimental curves the vortex path model was applied to the angular distributions of the critical current in magnetic field. Good agreements of the experimental data with the analytical expressions were obtained that confirm the vortex path model approach.