• 제목/요약/키워드: and nano-template

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전기화학적 도금을 이용한 wrap-around 게이트 나노구조의 제작 (Fabrication of wrap-around gate nanostructures from electrochemical deposition)

  • 안재현;홍수헌;강명길;황성우
    • 전기전자학회논문지
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    • 제13권2호
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    • pp.126-131
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    • 2009
  • Wrap-around 전계효과 트랜지스터는 채널과 전극간의 커플링을 매우 커서 채널길이가 짧아지면서 생기는 단채널효과(short channel effect)를 개선시킬 수 있는 이유로 많은 관심을 불러왔다. 본 논문에서는 실리콘 나노와이어를 이용하여 상향식의 wrap-around 전계효과 트랜지스터(FET)의 제작 공정을 소개한다. 소자의 제작 공정은 크게 전자빔 리소그래피, 유전영동(dielectrophoresis)을 이용한 나노와이어의 효과적 정렬 그리고 게이트 전극의 전기 화학적 도금(electrochemical deposition)을 이용한 생성 등의 방법들로 이루어진다. 전기 화학적 도금을 위한 용액은 독성을 띄지 않는 유기물 용액을 사용하였다. 액체 질소를 이용하여 polymethyl methacrylate(PMMA)가 전기화학적 도금시 형태를 잃지 않게 함으로써, 패터닝된 PMMA가 wrap-around 게이트 나노구조를 제작하기 위한 나노 템플릿으로 사용될 수 있도록 하였다.

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Co계 자성합금 나노와이어의 특성에 영향을 미치는 전기화학적 변수 (Electrochemical Factors Affecting the Magnetic Properties of Co based Magnetic Nanowires)

  • 이종욱;박호동;이관희;김긍호;정원용
    • 전기화학회지
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    • 제8권3호
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    • pp.125-129
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    • 2005
  • 본 연구에서는 고순도 알루미늄 호일$(t=300{\mu}m)$양극산화 공정을 통해 AAO 나노템플레이트를 자체 제조하였고, 이렇게 제조된 형틀을 가지고 교류 나노전주법에 의해 경자성 합금인 CoP와 연자성 합금인 CoFe를 나노와이어로 제조하였다. 대표적인 Co계 자성합금인 CoP와 CoFe나노와이어는 각기 독특한 자기적 성질을 나타내었다. 경자성 CoP 합금 나노와이어의 경우 교류 인가전압에 따라 hcp와 fcc가 혼재된 구조가 형성되어 자기적 특성에 영향을 미쳤다. 또한 높은 포화자화 값을 갖는 CoFe연자성 합금 나노와이어는 박막 도금 시와는 달리 이상합금도금현상이 거의 나타나지 않았으며 $Co_{30}Fe_{70}$에서 가장 좋은 238emu/g의 포화자화 값을 나타내었다.

메조기공을 갖는 다양한 금속 산화물 촉매를 이용한 사이클로헥사놀의 탈수소화 반응 (Highly Ordered Mesoporous Metal Oxides as Catalysts for Dehydrogenation of Cyclohexanol)

  • 이은옥;김명실;김지만
    • Korean Chemical Engineering Research
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    • 제51권4호
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    • pp.518-522
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    • 2013
  • 사이클로헥사논은 나일론의 단량체로 사용되는 카프로락탐의 원료로 중요한 중간체이며 사이클로헥사놀의 탈수소화반응을 통해 합성된다. 본 연구에서는 탈수소화 반응에 적용하기 위한 촉매로 다양한 메조기공을 가진 금속 산화물(meso-$WO_3$, meso-$TiO_2$, meso-$Fe_2O_3$, meso-CuO, meso-$SnO_2$, meso-NiO)을 나노 복제법에 의해 합성하였다. 그 결과 meso-$WO_3$ >> meso-$Fe_2O_3$ > meso-$SnO_2$ > meso-$TiO_2$ > meso-NiO > meso-CuO 순서로 촉매 활성이 나타났으며, 그 중 meso-$WO_3$가 가장 높은 촉매 활성을 보임을 알 수 있었다. 따라서 사이클로헥사놀을 이용한 탈수소화 반응에 meso-$WO_3$의 폭넓은 응용 가능성을 확인하였다.

Formation Rate of DNA Nanowires According to the APTES Concentration

  • Kim, Taek-Woon;Kim, Nam-Hoon;Roh, Yong-Han
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.143-143
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    • 2008
  • Nanowires are promising options for building nanoscale electronic structures coming from high conductivity of nanowires. In particular, Deoxyribonucleic acid (DNA), which is structurally nanowire, can obtain highly ordered electronic components for nanocircuitry and/or nanodevices because of its very flexible length controllability, nanometer-size diameter, about 2 nm, and self-assembling properties. In this work, we used the method to form DNA-Nanowires (NWs) by using chemical treatment on Silicon (Si) surface, and Aminopropyl-triethoxysilane (APTES) was used as inducer of DNA sequence to modify the characteristics of Si surface. Moreover, we performed tilting technique to align DNA by the direction of flow of DNA solution. We investigated the assembly process between DNA molecules and APTES - coated Si surface according to the APTES concentration, from $1.2{\mu}\ell$ to $120{\mu}\ell$. Atomic Force Microscopy (AFM) images showed the combination rate of DNA molecules by the change of APTES concentration. As APTES concentration becomes thicker, aggregation of DNA molecules occurs, and this makes a kind of DNA networks. In this respect, we confirmed that there's a positive relationship between the concentration of APTES and the formation rate of DNA nanowires. Since there have been lots of research preceded to utilize DNA nanowires as template, so by using this positive relationship with proper alignment technique, realization of nano electronic devices with DNA nanowires might be feasible.

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Cobalt ferrite nanotubes and porous nanorods for dye removal

  • Girgis, E.;Adel, D.;Tharwat, C.;Attallah, O.;Rao, K.V.
    • Advances in nano research
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    • 제3권2호
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    • pp.111-121
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    • 2015
  • $CoFe_2O_4$ nanotubes and porous nanorods were prepared via a simple one-pot template-free hydrothermal method and were used as an adsorbent for the removal of dye contaminants from water. The properties of the synthesized nanotubes and porous nanorods were characterized by electron diffraction, transmission electron microscopy and x-ray powder diffraction. The Adsorption characteristics of the $CoFe_2O_4$ were examined using polar red dye and the factors affecting adsorption, such as, initial dye concentration, pH and contact time were evaluated. The overall trend followed an increase of the sorption capacity reaching a maximum of 95% dye removal at low pHs of 2-4. An enhancement in the removal efficiency was also noticed upon increasing the contact time between dye molecules and $CoFe_2O_4$ nanoparticles. The final results indicated that the $CoFe_2O_4$ nanotubes and porous nanorods can be considered as an efficient low cost and recyclable adsorbent for dye removal with efficiency 94% for Cobalt ferrite nanotubes and for Cobalt ferrite porous nanorods equals 95%.

Dielectric/Magnetic Nanowires Synthesized by the Electrospinning Method for Use as High Frequency Electromagnetic Wave Absorber

  • 좌용호
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.14-14
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    • 2009
  • High frequency electromagnetic(EM) waves are increasingly being applied in industries because of saturationat lower frequency bands as a result of huge demand. However, electromagneticinterference (EMI) has become a serious problem, and as a result, highfrequency EM absorbers are now being extensively studied. Also, recentdevelopments in absorber technology have focused on producing absorbers thatare thin, flexible, and strong. Hence, one-dimension ferrous nano-materials area potential research field, because of their interesting electronic andmagnetic properties. Commercially, EM wave absorbing products are made ofcomposites, which blend the insulating polymer with magnetic fillers. Inparticular, the shape of the magnetic fillers, such flaky, acicular, or fibrousmagnetic metal particles, rather than spherical, is essential for synthesizingthin and lightweight EM wave absorbers with higher permeability. High aspectratio materials exhibit a higher permeability value and therefore betterabsorption of the EM wave, because of electromagnetic anisotropy. Nanowires areusually fabricated by drawing, template synthesis, phase separation, selfassembly, and electrospinning with a thermal treatment and reduction process.Producing nanowires by the electrospinning method involves a conventionalsol-gel process that is simple, unique, and cost-effective. In thispresentation, Magnetic nanowire and dielectric materials coated magneticnanowire with a high aspect ratio were successfully synthesized by theelectrospinning process with heat treatment and reduction. In addition toestimating the EM wave absorption ability of the synthesized magnetic anddielectric materials coated magnetic nanowire with a network analyzer, weinvestigated the possibility of using these nanowires as high-frequency EM waveabsorbers. Furthermore, a wide variety of topics will be discussed such as thetransparent conducting nanowire and semiconducting nanowire/tube with theelectrospinning process.

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Fabrication and Photocatalytic Properties of Visible Light Responsive Cuprous Oxide Cubes

  • Lin, Jiudong;Tao, Feifei;Sheng, Congcong;Li, Jianwei;Yu, Xiaoding
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1110-1116
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    • 2014
  • The cuprous oxide cubes with the special porous surface constructed by nano-prisms have been successfully fabricated by a solvothermal method. The template-free method is simple and facile without any surfactant. The X-ray powder diffraction (XRD) pattern suggests that the as-prepared product is the pure primitive cubic $Cu_2O$. The effects of the experimental parameters, such as the reaction temperature, reaction time and the concentration of sodium acetate anhydrous, on the morphologies of the products were investigated in detail by the scanning electron microscopy (SEM). Based on the time-dependent experiments, the possible formation mechanism was proposed. Using photocatalytic degrading reactive dyes as the model reaction and xenon lamp to simulate sunlight, the $Cu_2O$ cubes with the porous surface might possess higher photocatalytic activity than those of the commercial $Cu_2O$ powder in the visible-light region, indicating the excellent photocatalytic performance.

Simple Purification of the Human Antimicrobial Peptide Dermcidin (MDCD-1L) by Intein-Mediated Expression in E. coli

  • Hong, In-Pyo;Kim, Yong-Seok;Choi, Shin-Geon
    • Journal of Microbiology and Biotechnology
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    • 제20권2호
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    • pp.350-355
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    • 2010
  • Among human antimicrobial peptides (hAMPs), DCD-1L has a broad spectrum of antimicrobial activity over a wide pH range and in high salt concentrations. It offers a promising alternative to conventional antibiotics. The 458-bp-long dermcidin cDNA was amplified by PCR using a human fetal cDNA library as a template. The 147-bp fragment of the MDCD-1L gene encoding an additional methionine residue was subcloned into the pTYB11 vector. Recombinant MDCD-1L was expressed as an intein fusion protein in E. coli, and then purified by affinity chromatography using chitin beads. A small peptide with a molecular mass of about 5 kDa was detected by tricine gel electrophoresis. The recombinant MDCD-1L peptide was purified from the gel and its amino acid sequence was determined by nanoLC-ESI-MS/MS analysis. The initiating amino acid, methionine, remained attached to the N-terminal region of recombinant MDCD-1L. Purified MDCD-1L showed antimicrobial activity against a Micrococcus luteus test strain.

SnO2 Hollow Hemisphere Array for Methane Gas Sensing

  • Hieu, Nguyen Minh;Vuong, Nguyen Minh;Kim, Dojin;Choi, Byung Il;Kim, Myungbae
    • 한국재료학회지
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    • 제24권9호
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    • pp.451-457
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    • 2014
  • We developed a high-performance methane gas sensor based on a $SnO_2$ hollow hemisphere array structure of nano-thickness. The sensor structures were fabricated by sputter deposition of Sn metal over an array of polystyrene spheres distributed on a planar substrate, followed by an oxidation process to oxidize the Sn to $SnO_2$ while removing the polystyrene template cores. The surface morphology and structural properties were examined by scanning electron microscopy. An optimization of the structure for methane sensing was also carried out. The effects of oxidation temperature, film thickness, gold doping, and morphology were examined. An impressive response of ~220% was observed for a 200 ppm concentration of $CH_4$ gas at an operating temperature of $400^{\circ}C$ for a sample fabricated by 30 sec sputtering of Sn, and oxidation at $800^{\circ}C$ for 2 hr in air. This high response was enabled by the open structure of the hemisphere array thin films.

미소구체를 이용한 3차원 Sn-C 복합체 제조 (Fabrication of 3-dimensional Sn-C Composites Using Microsphere)

  • 박보건;김석범;박용준
    • 한국전기전자재료학회논문지
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    • 제23권9호
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    • pp.741-746
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    • 2010
  • Three-dimensionally ordered macro-porous Sn-C composites were prepared by using polystyrene microsphere as a template. The Sn-C composites were composed of well-interconnected pore with circular shape and wall structure with wall thickness of a few tens of nano-meters. This porous three-dimensional structure is readily and uniformly accessible to the electrolyte, which facilitates lithium ion diffusion during charge-discharge reactions. The wall thickness of the composites was increased as the increase of Sn content of the composite. From EDS analysis, it is confirmed that the Sn was dispersed uniformly in Sn-C composites. The capacity was increased as the Sn content increased, which is due to Sn anode with high capacity. The Sn-C composites with high Sn content showed superior cyclic performances. Such enhancement is ascribed to the thick wall thickness and small pore size of the sample with high Sn content. The Sn-C composite with Sn 30 wt% showed relatively high capacity and stable cycle life, however, the stability of the 3-dimensional structure should be enhanced by further work.