• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 춘계학술대회 논문집
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• pp.498-498
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• 2008

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 추계학술대회논문집
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• pp.203-206
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• 2004

Copper-based bulk amorphous alloy composite was synthesized by using the copper-coated $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ amorphous powder which was obtained by argon gas atomization. The amorphous powder having a super-cooled liquid region of 53 K was coated by crystalline copper by electroless coating. The consolidation was carried out by manufacturing performs and by the subsequent warm extrusion at 743 K. During the compression test at the room temperature, the composite containing a large fraction of crystalline copper displayed a larger plastic strain after yielding. FEM simulation revealed change in fracture modes in the composites depending on the amount of crystalline copper in the composites.

• 대한금속재료학회지
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• 제47권11호
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• pp.687-693
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• 2009

Experiments have demonstrated that a moderate amount of Be added to $Zr_{57.5}Cu_{38.3}Al_{4.2}$ amorphous alloy enhances the plasticity of the alloy. In particular, $Zr_{54}Cu_{36}Al_{4}Be_{6}$ alloy exhibited 19% of strain to fracture along with a strength exceeding 2 GPa. Energy dispersive x-ray spectroscopy conducted on the $Zr_{54}Cu_{36}Al_{4}Be_{6}$ alloy exhibited the presence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by the nm-scale phase separation on the plasticity was investigated in terms of structural disordering, structural softening and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

• 한국전기전자재료학회논문지
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• 제32권4호
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• pp.341-348
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• 2019

This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as $Fe_2Al_3Si_3$, $FeSi_2$, and $Fe_{0.42}Si_{2.67}$, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately $700mAh^{g-1}$, and exhibited a high Coulombic efficiency of 99.0~99.6% from the $2^{nd}$ to $70^{th}$ cycles.

• 한국자기학회지
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• 제4권2호
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• pp.126-129
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• 1994

희토류원소 Pr의 첨가가 Fe-B계 비정질합금의 자왜에 미치는 영향을 조사하기 위하여 비정질 $Fe_{86-x}B_{14}Pr_{x}(2{\leq}x{\leq}8\;at.%)$ 합금을 급속응고법을 이용하여 제조하였다. 급 속응고상태 비정질 $Fe_{86-x}B_{14}Pr_{x}$ 합금의 포화자왜는 Pr이 증가할 수록 증가하여 x=8에 서 약 50 ppm이 얻어졌다. 특히 $300^{\circ}C$에서 2시간 열처리된 비정질 $Fe_{84}B_{14}Pr_{2}$ 합금의 포화자왜는 70 ppm으로 증가하였다. $300^{\circ}C$에서 2시간 열처리된 비정질 $Fe_{84}B_{14}Pr_{2}$ 합금의 교류 자기이력손실 및 교류투자율$(f=50\;kHz,\;B_{m}=0.1\;T)$은 각각 15 W/kg, $5.5{\times}10^{3}$이었다.

• 한국수소및신에너지학회논문집
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• 제19권4호
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• pp.359-366
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• 2008

Hydrogen as a high-quality and clean energy carrier has attracted renewed and ever-increasing attention around the world in recent years, mainly due to developments in fuel cells and environmental pressures including climate change issues. In this processes for hydrogen production from fossil fuels, separation and purification is a critical technology. $(Ni_{60}-Nb_{40})_{95}-Pd_5$ alloy ingots were prepared by arc-melting the mixture of pure metals in an Ar atmosphere. Melt-spun ribbons were produced by the single-roller melt-spinning technique in an Ar atmosphere. Amorphous structure and thermal behavior were characterized by XRD and DSC. The permeability of the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy membrane was characterized by hydrogen permeation experiments in the temperature range 623 to 773 K and pressure of 2 bars. The maximum hydrogen permeability was $3.54{\times}10^{-9}[mol{\cdot}m^{-1}s^{-1}{\cdot}pa^{-1/2}]$ at 773 K for the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy.

• 한국재료학회지
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• 제24권1호
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• pp.60-65
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• 2014

Fe-based amorphous coatings were fabricated on a soda-lime glass substrate by the vacuum kinetic spray method. The effect of the gas flow rate, which determines particle velocity, on the deposition behavior of the particle and microstructure of the resultant films was investigated. The as-fabricated microstructure of the film was studied by field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HR-TEM). Although the activation energy for transformation from the amorphous phase to crystalline phase was lowered by severe plastic deformation and particle fracturing under a high strain rate, the crystalline phases could not be found in the coating layer. Incompletely fractured and small fragments 100~300 nm in size, which are smaller than initial feedstock material, were found on the coating surface and inside of the coating. Also, some pores and voids occurred between particle-particle interfaces. In the case of brittle Fe-based amorphous alloy, particles fail in fragmentation fracture mode through initiation and propagation of the numerous small cracks rather than shear fracture mode under compressive stress. It could be deduced that amorphous alloy underwent particle fracturing in a vacuum kinetic spray process. Also, it is considered that surface energy caused by the formation of new surfaces and friction energy contributed to the bonding of fragments.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1757-1760
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• 2005

This paper is concerned with spring back after sheet forming of bulk amorphous alloys in the super cooled liquid state. The temperature-dependence and strain-rate dependence of Newtonian/non-Newtonian viscosities as well as the stress overshoot/undershoot behavior of amorphous alloys are reflected in the thermo-mechanical Finite Element simulations. Hemispherical deep drawing operations are simulated for various forming conditions such as punch velocity, die corner radius, friction, blank holder force, clearance and initial forming temperature. Here, spring back by an instantaneous elastic unloading was followed by thermal deformation during cooling and two modes of spring backs are examined in detail. It could be concluded that the superior sheet formability of an amorphous alloy can be obtained by taking the proper forming conditions for loading/unloading.

• 소성∙가공
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• 제14권9호통권81호
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• pp.751-755
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• 2005

This paper is concerned with spring back after sheet forming of bulk amorphous alloys in the super cooled liquid state. The temperature-dependence and strain-rate dependence of Newtonian/non-Newtonian viscosities as well as the stress overshoot/undershoot behavior of amorphous alloys are reflected in the thermo-mechanical Finite Element simulations. Hemispherical deep drawing operations are simulated for various forming conditions such as punch velocity, die comer radius, friction, blank holder force, clearance and initial funning temperature. Here, spring back by an instantaneous elastic unloading was followed by thermal deformation during cooling, and two modes of spring back are examined in detail. It could be concluded that the superior sheet formability of an amorphous alloy can be obtained by taking the proper forming conditions for loading/unloading.

• Journal of Magnetics
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• 제3권3호
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• pp.78-81
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• 1998

Large magneto crystalline anisotropy energy and demagnetization energy of rare earth-transition metal (RF-TM) alloys play roles of bottlenecks towards their commercial applications for giant magnetostrictive and blue wavelength magneto optical recording materials, respectively. To solve the above problems, boron is added into amorphous RE-TM alloys to produce its electron transferring. The boron added amorphous RE-TM alloys show novel magnetic and magneto-optical properties as follows; 1) an amorphous $(Sm_{33}Fe_{76})$97B3 alloy obtains the magnetostriction of$ -550{times}10^{-6}$ at 400 Oe compared with saturation magnetostriction of$ -60{\times}10^{-6}$ in conventional Ni based alloys, 2) an amorphous$ (Nd_{33}Fe_{67})_{95}B_5$ alloy increases effective magnetic anisotropy to$ -0.5{\times}10^{-6} ergs/cm^3 from -3.5{\times}10^6 ergs/cm^3$ without boron, which correspond to the polar Kerr rotation angles of 0.52$^{\circ}$and 0.33$^{\circ}$, respectively. These results attribute to selective 2p-3d electron orbits exchange coupling (SEC).