• 제목/요약/키워드: ambient pressure x-ray photoemission spectroscopy

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In-situ monitoring of oxidation states of vanadium with ambient pressure XPS

  • Kim, Geonhwa;Yoon, Joonseok;Yang, Hyukjun;Lim, Hojoon;Lee, Hyungcheol;Jeong, Changkil;Yun, Hyungjoong;Jeong, Beomgyun;Ethan, Crumlin;Lee, Juhan;Ju, Honglyoul;Mun, Bongjin Simon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.125.2-125.2
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    • 2015
  • The evolution of oxidation states of vanadium is monitored with ambient pressure X-ray photoemission spectroscopy. As the pressure of oxygen gas and surface temperature change, the formations of various oxidation states of vanadium are observed on the surface. Under 100mTorr of the oxygen gas pressure and 523K of sample temperature, VO2 and V2O5 are formed on the surface. The temperature-dependent resistance measurement on grown sample shows a clear metal-insulator transition near 350K. In addition, the measurement of Raman spectroscopy displays the structural change from monoclinic to rutile structures across the phase transition temperature.

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