• Title/Summary/Keyword: ambient cascade impactor

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Measurement of Atmospheric Dry Deposition and Size Distribution of Particulate PCBs in 1999 at Seoul

  • Park, Seong-Suk;Shin, Hye-Joung;Yi, Seung-Muk;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E1
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    • pp.35-43
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    • 2006
  • Ambient particle size distributions of PCBs and their dry deposition fluxes were measured at a site in Seoul to quantify dry deposition fluxes of PCBs and size characteristics of PCBs in the air, and to estimate ambient concentrations of gaseous PCBs and dry deposition fluxes. The dry deposition plate was used to measure dry deposition fluxes of particulate mass and PCBs and a cascade impactor and rotary impactor were used to measure ambient particle size distributions for small ($D_p<9{\mu}m$) and large ($D_p>9{\mu}m$) particles, respectively. Six sample sets were collected from April to July 1999. The fluxes of particulate total PCBs (the sum of 43 congeners) ranged from 160 to $607ng\;m^{-2}day^{-1}$. The size distribution of total PCBs was bimodal with two peaks in small particle size ($D_p{\sim}0.6\;and\;6{\mu}m$, respectively) and, thus, mass concentration being dominant in small particles. The mean particulate PCBs concentration was $6.9{\mu}g$ PCBs/g. The concentrations of PCB homologues in the gas phase were estimated based on the particle/gas partition coefficient ($K_p$) with the measured values of particulate PCBs in this study and they were comparable to those observed in other previous studies. Dry deposition fluxes were estimated by calculating dry deposition velocities.

Characteristics of Ionic Components in Size-resolved Particulate Matters in Suwon Area (수원지역 분진의 입경별 이온성분 분포특성에 관한 연구)

  • Oh, Mi-Seok;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.46-56
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    • 2009
  • The main purpose of this study was to investigate air quality trends of ambient aerosol with obtaining size-fractionated information. The suspended particulate matters were continuously collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005 $\sim$ Sep. 2007) in Kyung Hee University-Global Campus. 8 ionic species ($Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an IC after performing proper pretreatments of each sample filter. The average concentration levels of each ion were $9.24{\mu}g/m^3$ of ${SO_4}^{2-}$, $7.35{\mu}g/m^3$ of ${NO_3}^-$, $2.81{\mu}g/m^3$ of ${NH_4}^+$, $2.11{\mu}g/m^3$ of $Ca^{2+}$, $1.65{\mu}g/m^3$ of $Cl^-$, $1.87{\mu}g/m^3$ of $Na^+$, $0.80{\mu}g/m^3$ of $Mg^{2+}$, and $0.54{\mu}g/m^3$ of $K^+$, respectively. The distribution pattern of $Na^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, and ${NO_3}^-$ was bi-modal and two peaks appeared in the range of $0.4{\sim}0.7{\mu}m$ and $3.3{\sim}4.7{\mu}m$, respectively. On the other hand, ${SO_4}^{2-}$, ${NH_4}^+$, and $K^+$ showed patterns of uni-modal distribution, mostly abounded in the fine mode group.

Characteristics of Size Distribution and Fugitive Emissions of Particulate Matter in Foundries (주물사업장의 입자상물질 입경분포 및 비산배출 특성)

  • Park, Jeong-Ho;Jang, Min-Jae;Kim, Hyoung-Kab
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.1
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    • pp.30-37
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    • 2016
  • Objectives: This study was performed to measure and evaluate the concentration, size distribution and fugitive emission of particulate matter from process operations at foundries. Methods: Particle matter was collected from three foundries, and samples were also collected from a background site for calculating the fugitive emission concentration of the foundries. For the collection of the samples, a Nanosampler cascade impactor was used. Results: The concentration of TSP in the samples collected from the three foundries was $0.675{\sim}1.222mg/m^3$, $PM_{10}$ was $0.525{\sim}1.018mg/m^3$ and $PM_{2.5}$ was $0.192{\sim}0.615mg/m^3$. The mass size distribution was bimodal or monomodal with maximum peak at two stage(size $2.5{\sim}10{\mu}m$). The mass median aerodynamic diameter(MMAD) was $1.80{\sim}3.98{\mu}m$. The fugitive emission concentration of TSP varies in the range of 0.65 to $1.21mg/m^3$, which exceeds the emission standard of fugitive dust($0.5mg/m^3$). Conclusions: Particle concentration and size is an important industrial hygiene factor to protect foundry workers. Furthermore, the presence of high emission of particulate pollutants has a significant negative impact on the ambient air of the study area. Therefore, it is important to improve both the process and prevention facility in oder to reduce particulate pollutants in foundries.

Quantitative Source Estimation of Particulate Matters in Suwon Area Using the Target Transformation Factor Analysis Based on Size Segregation Scheme (입경 분류에 입각하여 목표변환 인자분석법을 이용한 수원지역 분진 오염원의 정량적 기여도 추정)

  • 김동술;이태정
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.1
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    • pp.44-50
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    • 1993
  • The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 2 years (Dec. 1989 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentration on each stage was estimated by a microbalance and further chemical element concentrations were determined by an XRF system. The study focused on developing of a receptor model using the TTFA (target transformation factor analysis) to apportion aerosol mass with the 30 ambient data sets. Each data set consists of the 8 size-ranged subdata sets characterized by 13 element variables. Even though a couple of sources could not be identified, three to five sources were extracted from each aerosol size-range, and then 9 statistical source profiles were generated. Finally, source contribution of particulate matters on each size-range could be estimated in Suwon area.

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A Study on the Size Distribution of Trace Metals Concentrations in the Ambient Aerosols (대기부유분진 중 미량 금속원소의 입경별 농도분포에 관한 연구)

  • 신훈중;이태정;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.1
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    • pp.67-77
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    • 1996
  • Total suspended particulate matters (TSP) were collected based on a size segregation method by a cascade impactor for 6 consecutive years (form Dec. 1989 to sep. 1994) in the Kyung Hee University-Suwon Campus, and 6 trace metals (Ca, Si, Fe, Pb, Cu, Zn) were determined by an x-ray fluorescence spectroscopy. Total number of samples collected during the study are 118 sets and each set of sample comsists of 9 filters. The levels of TSP and 6 trace metals were then used to examine seasonal and annual variations with respects to their size distributions. For statistical analyses, raw data were initially transformed by both logarithmic and root transformating to approximately normalize them, and then size distribution functions for each trace element were separately developed season-to-season by a regression analysis in order to obtain maximum amount of physical information, Subsequently, each developed model was verified by comparing with supervised data collected on 1994. The result showed that each prediction model was in good agreement except the fall, partly due to lack of the data collected on fall, 1994.

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Estimation of Source Contribution for Ambient Particulate Matters in Suwon Area (수원지역 입자상 오염물질의 오염원 기여도의 추정)

  • 이태정;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.4
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    • pp.285-296
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    • 1997
  • The suspended particulate matters had been collected on quartz fiber fiters by a cascade impactor having 9 size stages for 4 years (Sep. 1991 to Dec. 1995) in Kyung Hee University-Suwon Campus. Membrane filters were used to collected the particulate matters on each stage. The weight concentration on each stage was obtained by a microbalance and further chemical element levels were determined by an x-ray fluorescence system. Based on these chemical information, our study focused on applying the target transformation factor analysis (TTFA), a receptor model, to identify aerosol sources and to apportion quantitatively their mass contribution. There are total of 63 ambient data sets. Each data set consists of the 8 size-ranged subdata sets characterized by 16 elemental variables. By the results, four to five sources were extracted from each size range and some sources reappeared in other size ranges. Then total of 8 source profiles were statistically generated from all the ranges, such as oil burning source, soil source, field burning source, gasoline related source, coal burning source, marine source, glass related source, and unknown sources. Apportioning aerosol mass to each source was intensively examined by investigating emission inventories near the study area. The results showed that soil particle source was the most significant contributor. However, coal and oil burning sources were the major anthropogenic ones. The study finally proposed some air quality control strategies to achieve the clean air quality in Suwon area.

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Changeable Qualitative Characteristics of Mold Aerosols on Each Occasion of Dust Episodes (2000 ~ 2002) in West Korea

  • Yeo, Hwan-Goo
    • Korean Journal of Environmental Biology
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    • v.21 no.3
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    • pp.240-244
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    • 2003
  • Conidia of molds within the Asian dust were captured in the ambient air of mid-west Korea, in springtime of 2000~2002. An eight-stage Cascade impactor and 0.22 $\mu\textrm{m}$ pore size membrane filters were used for the dust samples. Several kinds of molds grown from the samples were identified to the genus level. Those are Aspergillus, Basipetospora, Epicoccum, Fusarium, Monotospora and Penicillium. Relatively diversified mycelia of hyphomycetes were grown on the fine dust sample (1.1~2.1 $\mu\textrm{m}$) in the first year Asian dust episode (23~24 March, 2000). On the other hand, some fluffy molds and dark molds aggregations were grown on even the backup particle sample less than 0.43 $\mu\textrm{m}$ during the second year episode (24~26 April, 2001). The result of the last year episode (21~22 March, 2002) showed various mycelia grown on the sample contained from 1.1 to 2.1 $\mu\textrm{m}$ sized particles, just like the result of the first year episode (23~24 March, 2000). These variations between the episodes might be caused by the difference of the dust origins.

A Case Study of Ionic Components in the Size-resolved Ambient Particles Collected Near the Volcanic Crater of Sakurajima, Japan

  • Ma, Chang-Jin;Kim, Ki-Hyun;Kang, Gong-Unn
    • Asian Journal of Atmospheric Environment
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    • v.4 no.2
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    • pp.72-79
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    • 2010
  • In this study, the ionic composition of volcanogenically derived particles and their temporal and spatial distributions have been investigated to evaluate the impact of the volcanic eruption on the local ecosystem and residents. To this end, an intensive field study was conducted to measure the size-segregated particulate matters at the east part of Sakurajima in Japan. Fractionated sampling of particles into > $PM_{10}$, $PM_{10-2.5}$, and $PM_{2.5}$ was made by a multi nozzle cascade impactor (MCI). The concentration of various ions present in the size-resolved particles was determined by Ion chromatography. The time dependent 3-dimensional Volcanic Ash Forecast Transport And Dispersion (VAFTAD) model developed by the NOAA Air Resources Laboratory (ARL) indicated that the sampling site of this work was affected by the volcanic aerosol particles plume. The temporal distributions of sulfate and $PM_{2.5}$ during the field campaign were significantly variable with important contributions to particle mass concentration. The chlorine loss, suspected to be caused by acidic components of volcanic gases, occurred predominantly in fine particles smaller than $10\;{\mu}m$.

The Importance of Dry Deposition : Dry Deposition Fluxes of Heavy Metals In Seoul, Korea During Yellow-Sand Events

  • Yi, Seung-Muk
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2003.06a
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    • pp.76-85
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    • 2003
  • Mass and elemental dry deposition fluxes and ambient particle size distributions were measured using dry deposition plates and a cascade impactor, from March to November 1998 in Seoul, Korea. During the spring sampling period several yellow sand events characterized by long range transport from China and Mongolia impacted the area. During these events the mass fluxes were statistically the same as during springtime non-yellow-sand events. However, most elemental fluxes were higher. In general, the flux ratios of both crustal (Al, Ca, Mn) and anthropogenic elements (Ni, Pb) to total mass measured during the daytime yellow-sand events were substantially higher than those measured in spring daytime during non-yellow-sand time periods. During all seasons the average measured daytime fluxes were about two times higher than at nighttime. The flux of primarily anthropogenic metals (Cu, Ni, Pb, Zn) and Mn was on average one to two orders of magnitude lower than the flux of the crustal metals Al and Ca. As is typically found two modes, fine (0.1∼l.0 $\mu\textrm{m}$) and coarse (1.0∼10.0 $\mu\textrm{m}$) were present in the measured size distributions (<10 $\mu\textrm{m}$). The particles in the coarse mode constitute a major portion of the measured mass size distribution during the yellow-sand events possibly due to the long-range transport of those particles from China.

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Characteristics of Aerosol Composition at Jeju City, Korea

  • Hu, Chul-Goo;Lee, Ki-Ho;Oh, Tae-Gwon;Kang, Chun-Hee;Yang, Soon-Mi
    • Journal of Environmental Science International
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    • v.12 no.5
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    • pp.541-549
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    • 2003
  • Aerosol measurement were carried out to investigate the characteristics of its chemical composition directly affected by the local emissions of Jeju City, Jeju Island by using an eight-stage cascade impactor from Dec. 1999 to Aug. 2000. The ambient aerosol concentrations measured at Jeju City were generally very low but the fine particle concentrations were to be higher than the US standard of PM2.5. The majority of sulfate were non sea salt and contained in the fine particles. In the fine particles, the concentrations of Na$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/, Cl$\^$-/ and NO$\sub$3$\^$-/ had a tendency to increase during the springtime rather than the other seasons. However, the springtime sulfate and ammonium concentrations in the fine particles were slightly lower than those during the other seasons. On the other hand, associated with the coarse particles, the concentrations of ionic species except potassium and ammonium were elevated during the springtime. The calcium concentrations in the coarse particles were increased up to 8 times relative to the other seasons.