• Title/Summary/Keyword: aluminum contents

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Twenty-Eight-Day Repeated Inhalation Toxicity Study of Aluminum Oxide Nanoparticles in Male Sprague-Dawley Rats

  • Kim, Yong-Soon;Chung, Yong-Hyun;Seo, Dong-Seok;Choi, Hyun-Sung;Lim, Cheol-Hong
    • Toxicological Research
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    • v.34 no.4
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    • pp.343-354
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    • 2018
  • Aluminum oxide nanoparticles ($Al_2O_3$ NPs) are among the most widely used nanomaterials; however, relatively little information about their risk identification and assessment is available. In the present study, we aimed to investigate the potential toxicity of $Al_2O_3$ NPs following repeated inhalation exposure in male Sprague-Dawley rats. Rats were exposed to $Al_2O_3$ NPs for 28 days (5 days/week) at doses of 0, 0.2, 1, and $5mg/m^3$ using a nose-only inhalation system. During the experimental period, we evaluated the clinical signs, body weight change, hematological and serum biochemical parameters, necropsy findings, organ weight, and histopathology findings. Additionally, we analyzed the bronchoalveolar lavage fluid (BALF), including differential leukocyte counts, and aluminum contents in the major organs and blood. Aluminum contents were the highest in lung tissues and showed a dose-dependent relationship in the exposure group. Histopathology showed alveolar macrophage accumulation in the lungs of rats in the $5mg/m^3$ group during exposure and recovery. These changes tended to increase at the end of the recovery period. In the BALF analysis, total cell and neutrophil counts and lactate dehydrogenase, tumor necrosis factor-${\alpha}$, and interleukin-6 levels significantly increased in the 1 and $5mg/m^3$ groups during exposure. Under the present experimental conditions, we suggested that the no-observed-adverse-effect level of $Al_2O_3$ NPs in male rats was $1mg/m^3$, and the target organ was the lung.

Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water (고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향)

  • Lee, Sun Gi;Han, Seung Woo;Kang, Lim Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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Properties and Casting Characteristics of Al-Zn-Fe-Si Alloys (Al-Zn-Fe-Si 합금의 물성 및 주조특성)

  • Yun, Ho-Seob;Kim, Jeong-Min;Park, Joon-Sik;Kim, Ki-Tae
    • Journal of Korea Foundry Society
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    • v.33 no.1
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    • pp.8-12
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    • 2013
  • Although aluminum-silicon based commercial casting alloys have been used in applications that demand high electrical or thermal conductivity, new aluminum casting alloys that possess higher conductivities are currently required for advanced applications. Therefore, there is much research into the development of new high conductivity aluminum casting alloys that contain lower amounts of or no silicon. In this research, the properties and casting characteristics of Al-Zn-Fe-Si alloys with various Fe and Si contents were investigated. Two types of AlFeSi phases were formed depending on the Fe and Si contents. As the silicon content increased, the tensile strength of the Al-Zn-Fe-Si alloy increased slightly, while the electrical conductivity decreased slightly. It was also observed that both the fluidity and hot cracking susceptibility of the investigated alloys were closely related to the formation of the AlFeSi phases.

Formation of Thicker Hard Alloy Layer on Surface of Aluminum Alloy by PTA Overlaying with Metal Powder (알루미늄 합금의 표면경화)

  • Lee, Young-Ho
    • Proceedings of the KWS Conference
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    • 1996.10a
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    • pp.3-15
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    • 1996
  • The formation of a thicker hard alloyed layer have been investigated on the surface of aluminum cast alloy (AC2B) by PTA overlaying process with Cr, Cu and Ni motel powders under the condition of overlaying current 125-200A. overlaying speed 150 mm/min and different powder feeding rate 5-20 g/min. In addition the characteristics of hardening and wear resistance of alloyed layer here been examined in relation to the microstructure of alloyed layer. Main results obtained were summarized as follows: 1) There was an optimum overlaying condition to get a good alloyed layer with smooth surface. This good layer became easy to be formed as increasing overlaying current and decreasing powder feeding rate under a constant overlaying speed. 2) Cu powder was the most superior one in metal powders used due to a wide optimum overlaying condition range, uniform hardness distribution of Hv250-350, good oar resistance and freedom from cracking in alloyed layer with fine hyper-eutectic structure. 3) On the contrary, irregular hardness distribution was usually obtained in Cr ar Ni alloyed layers of which hardness was increased as Cr or Ni contents and reached to maximum hardness of about Hv400-850 at about 60wt%cr or 40wt%Ni in alloyed layer. 4) Cracking occurred in Cr or Ni alloyed layers with higher hardness than Hv250-300 at mere than 20-25wt% of Cr or Ni contents in alloyed layer. Porosity was observed in all alloyed layers but decreased by usage of spherical powder with smooth surface.

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Effect of Tio2 particles on the mechanical, bonding properties and microstructural evolution of AA1060/TiO2 composites fabricated by WARB

  • Vini, Mohamad Heydari;Daneshmand, Saeed
    • Advances in materials Research
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    • v.9 no.2
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    • pp.99-107
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    • 2020
  • Reinforced aluminum alloy base composites have become increasingly popular for engineering applications, since they usually possess several desirable properties. Recently, Warm Accumulative Roll Bonding (WARB) process has been used as a new novel process to fabricate particle reinforced metal matrix composites. In the present study, TiO2 particles are used as reinforcement in aluminum metal matrix composites fabricated through warm accumulative roll bonding process. Firstly, the raw aluminum alloy 1060 strips with TiO2 as reinforcement particle were roll bonded to four accumulative rolling cycles by preheating for 5 min at 300℃before each cycle. The mechanical and bonding properties of composites have been studied versus different volume contents of TiO2 particles by tensile test, peeling test and vickers micro-hardness test. Moreover, the fracture surface and peeling surface of samples after the tensile test and peeling test have been studied versus different amount of TiO2 volume contents by scanning electron microscopy. The results indicated that the strength and the average vickers micro-hardness of composites improved by increasing the volume content of TiO2 particles and the amount of their elongation and bonding strength decreased significantly.

Effects of Chemical Additives Containing Al and Ca on Volatile Fatty Acids and Nitrogen Contents of Litter (Al과 Ca을 함유한 화학제재의 첨가가 깔짚내 휘발성 지방산과 질소 함량에 미치는 영향)

  • Choi, In-Hag;Choi, Jung-Hoon
    • Journal of Environmental Science International
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    • v.17 no.2
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    • pp.225-232
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    • 2008
  • The objectives of this study were conducted to determine the effects of two chemical amendments on volatile fatty acids (VFA) and nitrogen contents in poultry litter after broiler chicks were raised in poultry houses for 6 weeks. Two different additives were applied as a top dressing to the litter at a rate of $AlCl_3{\cdot}6H_2O$ (200 g)+$CaCO_3$ (50 g) or Alum (200 g)+$CaCO_3$ (50 g)/kg of rice bran; untreated litter served as controls. Application of $AlCl_3+CaCO_3$ and Alum+$CaCO_3$ reduced total VFA contents by 67% and 51% at 6 weeks, respectively, compard to the control groups. The decrease in litter pH with two chemical treatments results in decreased proportion of VFA and increased nitrogen contents of the litter. These results indicate that treating $AlCl_3+CaCO_3$ and Alum+$CaCO_3$ to poultry litter offers the potential for reducing an environmental impact.

Front Aluminum Subframe of High Level Vacuum Die-casting (고진공 다이캐스팅 공법 적용한 알루미늄 서브프레임 개발)

  • Cho, Young-Gun;Lim, Tae-Seong;Jang, Sang-Gil;Cho, Cheol-Hwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.4
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    • pp.52-59
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    • 2012
  • The subframe has been generally manufactured by using stamped steel material. Recently, automotive designers are considering aluminum as lightweight material. This paper describes the development process of an aluminum subframe which is made by high level vacuum die casting process, which is beneficial for minimizing gas contents and material properties. The weight of manufactured subframe is reduced by 4kg with the comparison of steel subframe. The aluminum subframe is packaged for the current vehicle layout and the imposed requirement is to attain a better structural performance that is evaluated in terms of mounting stiffness, noise and vibration, and endurance performance. The NVH evaluation results show that sound level is decreased by 8dB with the help of high roll-rod mounting stiffness as well as high structural modes.

Effect of Aluminum, Manganese, and Zirconium on the Content of Nickel in Molten Magnesium (마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향)

  • Jeong, Dae-Yeong;Moon, Young-Hoon;Moon, Byoung-Gi;Park, Won-Wook;Sohn, Keun-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.1
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    • pp.8-14
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    • 2015
  • Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

Properties of Yttria Stabilized Zirconia-Alumina Powders Prepared by Coprecipitation Method (공침법으로 제조한 아트리아 안정화 지르코니아-알루미나 분말의 특성)

  • 오경영
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1113-1120
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    • 1997
  • The 2, 4, 6 and 8mol% Y2O3 doped-ZrO2 powders (20 kinds) with the addedtion of Al2O3 upto 8wt% were prepared by coprecipitation method using the zirconium oxyacetate, yttrium chloride and aluminum nitrate as starting materials. The coprecipitated powders were characterized by XRD, TG-DTA, FT-IR and SEM. The sintering properties of zirconia-alumina composites prepared by 2YSZ and 8YSZ powders containing various Al2O3 contents were also investigated. With increasing the yttria stabilizer contents, the amount of exothermic heat for zirconia crystallization decreased. And it was confirmed that the crystallizing temperature of coprecipitated zirconia powders increased and the crystallization process occurred in a wide temperature range, as Al2O3 content increased in 8YSZ.

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Comparison of Colorimetric Methods for the Determination of Flavonoid in Propolis Extract Products (프로폴리스추출물 제품의 플라보노이드 함량분석을 위한 비색법의 비교)

  • Kim, Eun-Jeong;Lee, Hwa-Jung;Kim, Hye-Jeong;Nam, Hye-Seon;Lee, Mi-Keong;Kim, Hae-Young;Lee, Jin-Ha;Kang, Yun-Sook;Lee, Jong-Ok;Kim, Hee-Yun
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.918-921
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    • 2005
  • Quantitative analysis of flavonoids in commercial propolis extract products were compared by three colorimetric methods; aluminum chloride method, dinitrophenylhydrazine method and aluminum nitrate method, Aluminum nitrate method in Korea Health Supplement Food Code was proved to be specific only for flavones and flavonols same as aluminum chloride method, while dinitrophenylhydrazine method was specific for flavanones and dihydroflavonols. Therefore, the sum of flavonoid contents determined by 2,4-Dinitrophenylhydrazine method and aluminum nitrate method may represent the real content of total flavonoids. As for the 25 commercial propolis extract products examined, the contents of flavonoid varied from 2.15% to 9.53% except for one product.