• Title/Summary/Keyword: alumina tube

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Hydrogen Permeance of Silica Membrane Prepared by Chemical Vapor Deposition Method on an $\alpha$-Alumina Support Tube (기상 화학증착법에 의해 $\alpha$-Alumina 지지관 상에 제조한 Silica막의 수소투과 특성)

  • 김성수;이재홍;서동수;박상욱;서봉국
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.669-677
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    • 1998
  • A porous $\alpha$-alumina tube of 2.5 mm O.D. and 1.9 mm I.D. was used as the support of an inorganic membrane. Macropores of the tube, about 150 nm in size, were plugged with silica formed by thermal decomposition of tetraethylorthosilicate at $600^{\circ}C$. The forced cross-flow CVD method that reactant was evacuated through the porous wall of the support was very effective in plugging macropores. The H$_2$ permeance of the prepared membrane was of the order of $10^{-8}/ molㆍs^{-1}/ㆍm^{-2}/. Pa{-1}$/, while the $N_2$ permeance was below $10^{-11}/ molㆍs^{-1}/ㆍm^{-2}/ㆍPa^{-1}$/ at $600^{\circ}C$. This was comparable to that of silica-modified Vycor glass whose size was 4 nm.

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Development of Ceramic Arc-tube by the PIM Process

  • Rhee, Byung-Ohk;Choi, Seung-Chul;Park, Jeong-Shik;Kim, Byoung-Kyu;Kim, Hyung-Soo;Kim, Sang-Woo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.205-206
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    • 2006
  • A ball-shape alumina arc-tube for low-wattage lamp was developed by the PIM process. An ultra high purity translucentgrade alumina powder was used. In injection molding process, a hot-runner type mold was developed. The translucent-grade alumina powder was extremely sensitive to contamination so that the injection molding condition and atmosphere control in the furnace should be taken care of with extreme caution. Contamination sources were pinpointed with EPMA. The arc-tube was molded in half and two halves were bonded in the middle by a new bonding technique at room temperature developed in this study.

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Synthesis of Silica/Alumina Composite Membrane Using Sol-Gel and CVD Method for Hydrogen Purification at High Temperature (Sol-gel 및 CVD법을 이용한 고온 수소 분리용 silica/alumina 복합막의 합성)

  • 서봉국;이동욱;이규호
    • Membrane Journal
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    • v.11 no.3
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    • pp.124-132
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    • 2001
  • Silica membranes were prepared on a porous ${\alpha}$-alumina tube with pore size of 150nm by sol-gel and chemical vapor deposition(CVD) method for hydrogen separation at high temperatures. Silica and ${\gamma}$-lumina membranes formed by the sol-gel method possessed a large amount of mesopores of a Knudsen diffusion regime. In order to improve the $H_2$ selectivity, silica was deposited in the sol-gel derived silica/${\gamma}$-alumina layer by thermal decomposition of tetraethyl orthosilicate(TEOS) at $600^{\circ}C$. The CVD with forced cross flow through the porous wall of the support was very effective in plugging mesopores that were left unplugged in the membranes. The CVD modified silica/alumina composite membrane completely rejected nitrogen permeation and thus showed a high $H_2$ selectivity by molecular sieve effect. the permeation of hydrogen was explained by activated diffusion and the activation energy was 9.52kJ/mol.

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Development and Performance Evaluation of X-Ray Shields using Fe2O3 and Al2O3 (산화철, 알루미나를 이용한 X선 차폐체 개발 및 성능 평가)

  • Hui-Su, Yang;Ji-Hwan, Kim;Min-Cheol, Jeon
    • Journal of Advanced Technology Convergence
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    • v.1 no.2
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    • pp.19-25
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    • 2022
  • It is intended to evaluate the performance of the shield after manufacturing a shield with cheap and eco-friendly iron oxide and alumina instead of lead, which is a radiation shielding material. After manufacturing the shield by mixing iron oxide and alumina with gypsum, the performance is evaluated by comparing it with gypsum board and lead apron using an X-ray tube. As a result of the experiment, the shielding performance of alumina was lower than that of the gypsum board, and when 50% of alumina was contained, the shielding performance was similar to that of the gypsum board. Iron oxide became similar to the shielding performance of lead apron when it contained about 75%. A shielding material using alumina shows shielding performance similar to that of gypsum, so it is not suitable as a substitute for lead. However, since iron oxide exhibits similar shielding performance to lead, it can be used as an X-ray shielding material to replace lead in the future, so further research is needed.

Magnetic Abrasive Polishing for Internal Face of Seamless Stainless Steel Tube using Sludge Abrasive Grain

  • Kim, Hee-Nam
    • Journal of the Speleological Society of Korea
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    • no.78
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    • pp.23-27
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    • 2007
  • In this paper, we have investigated the characteristics of the magnetic abrasive using sludge on polishing of internal finishing of seamless stainless steel tube applying magnetic abrasive polishing. Either white alumina grain was used to resin sludge at a low temperature, and the sludge of magnetic abrasive powder was synthesized and crushed into 200 meshes. Surface roughness was measured before and after polishing, and more than 40% of improvement of surface roughness was achieved when grain was used under a specific condition. Even though some degree of surface roughness due to deeper scratches still exist, but the result showed a prospective magnetic abrasive polishing using sludge with white alumina grains.

Microsturcture Control of Metallized Alumina Ceramics for Electronic Devices (전자부품용 메탈라이즈드 알루미나 세라믹스의 미세구조 제어)

  • Jo, Beom-Rae
    • Korean Journal of Materials Research
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    • v.11 no.12
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    • pp.1086-1090
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    • 2001
  • Composition effects on microstructure and metallizing properties of the alumina sintered body were evaluated to develop the metallized alumina tubes having superior properties for electronic devices. SEM observation revealed that resultant micrographs and fractographs were varied with composition chance of additives and $SiO_2$-rich specimens showed better microstructural characteristics with uniform distribution of fine and round particles than other CaO-rich or MgO-rich ones. The resultant interfacial microstructure of the $SiO_2$-rich metallized alumina tubes also showed good metallizing properties with no defects between layers and uniform thickness of metallizing layer.

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Development of Ceramic Composite Membranes for Gas Separation: I. Coating Characteristics of Nanoparticulate SiO2 Sols (기체분리용 세라믹 복합분리막의 개발: I. 극미세 입자 실리카 졸의 코팅 특성)

  • ;Marc A. Anderson
    • Journal of the Korean Ceramic Society
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    • v.29 no.6
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    • pp.496-504
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    • 1992
  • Alumina tubes suitable for the support of gas separation membranes have been prepared by the slipcasting technique. These supports have the average pore size of 0.1 ${\mu}{\textrm}{m}$ within the narrow distribution. The sol-gel dipcoating process of nanoparticulate sols is very sensitive to microstructure of the support, and the coating on the inside surface of the tube is found to be more successful than on the outside surface. Nanoparticulate silica sols (0.82 mol/ι) have been synthesized by an interfacial hydrolysis reaction between TEOS and high alkaline water. When coating an alumina tube with these sols, the minimum limits of the particle size and the aging time required for forming the coated gel layer at the given pH are provided. It is optimum to coat the support with less concentrated sols stabilized through aging for the appropriate time (more than 22 days) at the lower pH (pH 2.0) for producing a reproducible crack free thin film coating in composite membranes.

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Magnetic Abrasive Polishing for Internal Face of STS Tube using Sludge Abrasive Grain

  • Kim, Hee-Nam;Soh, Dea-Wha;Hong, Sang-Jeen;Lee, Byung-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.128-132
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    • 2005
  • In this paper, we have investigated the characteristics of the magnetic abrasive using sludge on polishing of internal finishing of seamless stainless steel (STS304) tube applying magnetic abrasive polishing. Either white alumina (WA) or green carborundum (GC) grain was used to resin sludge at a low temperature, and the sludge of magnetic abrasive powder was synthesized and crushed into 200 meshes. Surface roughness was measured before and after polishing, and more than $40\%$ of improvement of surface roughness was achieved when WA grain was used under a specific condition. Even though some degree of surface roughness due to deeper scratches still exist, but the result showed a prospective magnetic abrasive polishing using sludge with WA or GC grains.

A Study on Optimization of Alumina and Catalysts Coating on Tube Reactor for Endothermic Reaction of n-Dodecane Under Supercritical Conditions (고온, 고압 조건에서 n-dodecane 액체연료의 흡열분해를 위한 관벽 내 알루미나 및 촉매 코팅 최적화 연구)

  • Kim, Sung Su;Lee, Sang Moon;Lee, Ye Hwan;Lee, Dong Yoon;Gwak, Ji-Yeong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.3
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    • pp.56-61
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    • 2021
  • In this study, Al2O3 and H-ZSM-5 were coated on the inner wall of the stainless steel tube for the stable use of liquid hydrocarbon fuel and an endothermic catalyst used as coolant for hypersonic flying vehicles. Coke production is inevitable by the endothermic decomposition reaction of the liquid hydrocarbon fuel, and Fe, Ni metals induce the production of the filamentous coke by using a stainless steel tube reactor as a cooling channel. By coating the stainless steel with H-ZSM-5, Fe and Ni metals are prevented from being directly exposed to the liquid hydrocarbon fuel, and the formation of the filamentous coke is inhibited. In addition, Al2O3 is coated between the stainless steel and H-ZSM-5 to enhance adhesion bond strength.

Optical Properties with Arc Tube Structure of Ceramic Metal-Halide Lamps (세라믹 메탈할라이드 램프의 아크튜브 구조에 따른 광학적 특성)

  • Kim, Woo-Young;Jang, Hyeok-Jin;Yang, Jong-Kyung;Park, Hyung-Jun;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.378-379
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    • 2009
  • High intensity metal halide discharge lamp performance, specifically the generated luminous flux and light color content, depends critically on the arc tube design. Factors influencing the design and consequent lamp efficacy include : lamp size, geometry, arc tube composition, fill chemistry, electrode design and excitation modes. Shaping of Polycrystalline Alumina(PCA) can be realized by conventional ceramic processes. Several processes are applied nowadays. Well-known in the ceramic high pressure field for decades are the pressing and the extrusion method. Newly developed slurry and precious forming technologies give the one-body seamless tubes, which improve thickness uniformity and lighting performance. Now, we reported some optical properties with different arc tube structures of ceramic metal halide lamps.

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