• 에너지공학
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• 제17권1호
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• pp.38-45
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• 2008

본 연구는 캐나다산 아사바스카 오일샌드 역청(Athabasca Oilsands Bitumen)의 용매 불용분 실험(Solvent-Insolubles Experiment)을 통하여 아스팔텐(Asphaltenes : Solvent-Insolubles) 및 말텐(Maltenes : Solvent-Solubles)에 대한 다양한 물리 화학적 특성변화를 살펴보기 위하여 수행되었다. 용매는 n-Heptane, n-Hexane, n-Pentene의 3가지 용매를 사용하였고, 아스팔텐의 분리는 ASTM D 3279 방법을 응용하여 실시하였다. 역청, 아스팔텐, 말렌에 대한 분석항목은 원소분석, 분자량 분포, 비점 분포, 중금속 함량, API 비중, 점도, SARA 분포 등이다. 분석 결과 모든 말텐의 황 함량, 중금속 함량 및 분자량은 역청에 비하여 낮은 경향을 보였다. 그리고 n-Pentane 용매를 사용한 경우가 다른 용매에 비하여 말텐의 점도가 감소하였고, 황, 중금속 함량 및 분자량도 상대적으로 낮게 측정되었다. 따라서, 본 실험결과는 합성원유(SCO) 생산을 위한 역청의 경질화 공정에 필요한 기초자료로 활용할 수 있다고 판단된다.

• 한국산업융합학회 논문집
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• 제4권1호
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• pp.11-19
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• 2001

This study was carried out to investigate the feasibility of the used frying oil as a bin-oil which was one of the alternative fuel for diesel engine. From tests of engine performance, it was shown that the bio-oil and blends and the sufficient potential as alternative fuels of diesel engine except NOx and Smoke emission.

• Korean Chemical Engineering Research
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• 제45권2호
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• pp.109-116
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• 2007

기존의 경질유가 고갈됨에 따라 새로운 자원개발이 필요해지고 있다. 석유화학산업의 수요를 충족하기 위하여 중질유 혹은 비투맨 등과 같은 중질원료를 사용하고 있다. 비투맨은 복잡하고 고리가 긴 탄화수소의 일종으로 오일샌드로 부터 얻을 수 있는데, 캐나다 앨버타에 매장되어 있는 오일샌드로부터 약 8,300억 배럴의 오일을 얻을 수 있는 것으로 추정된다. 본 보문에서는 (1) 오일샌드, 비투맨, 중질유의 기본 개념, (2) 오일샌드에서 오일을 뽑아내는 방법들, (3) 업그레이드하여 합성원유(synthetic crude oil)를 만드는 방법, (4) 기술의 경제성 평가 등에 대하여 소개하고자 한다.

• Journal of Advanced Marine Engineering and Technology
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• 제36권7호
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• pp.885-893
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• 2012

DME (Dimethyl ether) is regarded as one of the candidates of alternative fuels for diesel engine, because of its higher cetane number suitable for a compression ignition engine. Also, DME is a simple chemical structure, colorless gas that is easily liquefied and transported. On the other hand, Bunker oil (JIS C heavy oil) has long been used as a basic fuel in marine diesel engines and is the lowest grade fuel oil. In this study, the combustion and emission characteristics were measured experimentally in the direct injection type diesel engine operated with DME and Bunker oil mixed fuel. From our experimental results, it is induced that DME and Bunker oil blended fuel would be an effective fuel which can reduces the concentration of harmful matter in exhaust gases.

• 대한기계학회논문집B
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• 제30권3호
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• pp.208-214
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• 2006

Dimethoxy methane$(CH_3-O-CH_2-O-CH_3)$, also known as methylal or DMM, is an oxygenated additive that contains 42.5% oxygen by weight and is soluble in diesel fuel. It is a colorless liquid and a gas-to-liquid chemical 방tat has been evaluated for use as a diesel fuel component. Experiments were conducted by using the five blends with different volumetric percentage of DMM(2.5, 5, 7.5, 10, and 12.5%) in baseline diesel fuel. The test engine was single cylinder, four stroke, DI diesel engine unmodified. Also, data was collected for steady state operation at 24 engine speed-load conditions. The focus of this study was to investigate the effects of the addition of oxygenated fuel to diesel fuel on the engine-out emissions and the performance. Smoke emissions of all DMM blends were reduced substantially in comparison with conventional diesel fuel. These results indicate that DMM may be an effective blendstock for diesel fuel as an environment-friendly alternative fuel. Besides, this study showed that simultaneous reduction of smoke and NOx emissions could be achieved by oxygenated fuel and EGR method that was applied to decrease NOx emissions increasing with smoke emissions reduction.

• 한국자동차공학회논문집
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• 제19권2호
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• pp.142-147
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• 2011

Compressed natural gas (CNG) is well known as one of the cleanest burning alternative fuels. Bi-fuel CNG vehicle can also run on gasoline or another fuel while dedicated natural gas vehicle is designed to run on natural gas only. Recently, increased attention has been focused on bi-fuel CNG/LPG taxi because of good fuel economy of CNG. A number of LPG taxis modified to CNG Bi-fuel vehicles are running in many cities. In this paper, the emissions characteristics of in-use passenger cars running on CNG and LPG were investigated. Chassis dynamometer test was used to measure exhaust emissions from an in-use fleet of 5 cars. Exhaust emissions were collected for CVS-75 driving mode. The test results showed that for CNG fuel mode, CO, $CO_2$ and NMHC emissions decreased to 9%, 12% and 14% respectively, and $CH_4$ and $NO_x$ emissions increased to 317% and 47% respectively.

• 대한기계학회논문집B
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• 제33권5호
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• pp.299-310
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• 2009

Fuel cells are expected to be promising future power sources in both aspects of thermal efficiency and environmental friendliness. Accordingly, worldwide research and development efforts have been enormously increasing recently in various applications such as power plants, transportation and portable power sources. Among others, high temperature fuel cells, such as solid oxide fuel cells and molten carbonate fuel cells, are suitable for electric power plants. Moreover, their high operating temperature is quite appropriate to construct further advanced integrated systems. This paper reviews recent literatures on research and development of integrated power generation systems based on high temperature fuel cells. Research and development efforts are summarized in the area of fuel cell/ gas turbine hybrid systems, application of carbon capture technology to fuel cell systems, integration of coal gasification with fuel cells, and the use of alternative fuels.

• Tribology and Lubricants
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• 제28권6호
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• pp.321-327
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• 2012

Paraffin bio-based hydrotreated biodiesel(HBD) is originated from vegetable oil(the process can also be applied to animal fat) with the the chemical structure $C_nH_{2n+2}$. In the number of process of the oil or fat, the hydrogenation is significantly important to create a bio-based diesel fuel. This study is focused on lubricity characteristics of BTL diesel blends to use alternative diesel fuel in Korea. The BTL diesel are blended the different volume ratios (HBD 5(5 vol.% HBD - 95 vol.% diesel), HBD 10, HBD 20, HBD 30, HBD 40 and HBD 50. HBD with paraffin compounds showed a very high centane number, low sulfur content and free aromatic compound. Especially, the wear scar of HBD showed poor lubricity compared to automotive diesel due to the fuel composition, low sulfur content and free aromatic compound. Also, the lubricity specification of automotive diesel with different six HBD blends is within the limit by the Korean standards. Finally, HBD as an alternative diesel fuel is challengeable in transportation sector of Korea.

• 한국자동차공학회논문집
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• 제17권5호
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• pp.53-60
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• 2009

In this study, LPG-blended DME fuel was experimentally investigated in CI(compression ignition) engine. In particular, performance, emissions characteristics (including hydrocarbon, CO, and NOx emissions), and combustion stability of engine fueled with LPG-blended DME fuel were examined. The extent of LPG fuel in the blended fuel was 0-40 wt%. Results showed that stable engine operation was possible in a wide range of engine loads on DME blended with maximum 30% of LPG by mass in a CI engine. Considering the results of the engine power output and exhaust emissions, blended fuel up to 30% of LPG by mass can be used as an alternative to diesel in a CI engine. LPG blended DME fuel is expected to have potential for enlarging the DME market.

• 방사성폐기물학회지
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• 제11권4호
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• pp.303-309
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• 2013

사용후핵연료의 지층처분의 대안으로 심부시추공을 설치하여 지하 3-5 km 구간에 사용후핵연료를 처분하는 개념이 여러나라에서 제시된 바 있다. 특히 미국 샌디아국립연구소의 최근 연구 결과를 분석하고, 국내 적용을 위한 한국형 캐니스터 디자인과 심부시추공 디자인 개념을 처분 소요 면적과 함께 제시하였다.