• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1033-1034
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• 2006

Metallic compound of ternary Al-B-C system was prepared by mechanical alloying (MA) using Al, boron and graphite powders as starting materials. MA was carried out using Spex 8000 mixer/mill for 50 hours in an argon atmosphere without process control reagent such as methyl alcohol. The MA powders obtained were heat-treated in vacuum at the temperature of 873 and 1273 K for 5 hour. Pure ternary Al-B-C compound was obtained in the chemical content of Al:B:C=55:27:18. The ternary compound obtained in this study has a new phase whose crystal structure is not identified yet.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.831-832
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• 2006

Solid-state processing via the bulk mechanical alloying enables us to directly fabricate $Mg_2X$ semi-conductive material performs. Precise control of chemical composition leads to investigation on the dilution and enrichment of X in $Mg_2X$. Two types of solid-state reactivity are introduced: e.g. synthesis of $Mg_2Si$ from elemental mixture Mg-Si is nucleation-controlled process while synthesis of $Mg_2Sn$ from Mg-Sn, diffusion-controlled process. Thermoelectricity of these $Mg_2X$ is evaluated for discussion on the validity and effectiveness of this new PM route as a reliable tool for fabrication of thermoelectric compounds.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.950-951
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• 2006

[ $Mg_{55}Y_{15}Cu_{30}$ ] metallic glass powders were prepared by the mechanical alloying of pure Mg, Y, and Cu after 10 h of milling. The thermal stability of these $Mg_{55}Y_{15}Cu_{30}$ amorphous powders was investigated using the differential scanning calorimeter (DSC). $T_g$, $T_x$, and ${\Delta}T_x$ are 442 K, 478 K, and 36 K, respectively. The as-milled $Mg_{55}Y_{15}Cu_{30}$ powders were then consolidated by vacuum hot pressing into disk compacts with a diameter and thickness of 10 mm and 1 mm, respectively. This yielded bulk $Mg_{55}Y_{15}Cu_{30}$ metallic glass with nanocrystalline precipitates homogeneously embedded in a highly dense glassy matrix. The pressure applied during consolidation can enhance thermal stability and prolong the existence of amorphous phase within $Mg_{55}Y_{15}Cu_{30}$ powders.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1290-1291
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• 2006

Fabrication of $Fe_3AlC$ matrix in-situ composite, reinforced by a FeAl phase, was studied by using the powder metallurgical processing route. Especially, in order to disperse the second phase more finely, we chose the mechanical alloying process. We investigated the microstructural and mechanical properties of the consolidated material. After consolidation by vacuum hot pressing, the compact showed almost full density and consisted of a $Fe_3AlC$ matrix and FeAl second phase (average particle size was less than 1m). The compact showed HV746, which was higher than that of the arc melted $Fe_3AlC$ monolithic material, HV603.

• 한국분말재료학회지
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• 제3권1호
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• pp.42-48
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• 1996

To investigate the phase transformation behaviors of mechanically alloyed Nb-25 at%Al powders, the mixed Nb-25 at%Al powders were mechanically alloyed in SPEX 8000 Mixer/Mill. Mechanical alloying(MA) time was varied between 0.5 hour and 72 hours. The phase formation behaviors of these mechanically alloyed powders were examined using X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), and differential thermal analysis(DTA). Appreciable amorphization started from 6 hours of MA. The powders mechanically alloyed for 10 hours were in almost amorphous phase. DTA results showed that the powders mechanically alloyed for 12 hours had a strong exothermic peak about$600^{\circ}C$, whereas the powders mechanically alloyed for 6 hours had two exothermic peaks. The first peak was found to be due to the stress relief effect and the second one due to the formation of$Nb_{3}Al,Nb_{2}Al and Nb_{2}C$phases by crystallization.

• 한국분말재료학회지
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• 제10권3호
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• pp.164-167
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• 2003

The mechanical alloying effect has been studied on the three Cu-based alloy systems with a positive heat of mixing. The extended bcc solid solution has been formed in the Cu-V system and an amorphous phase in the Cu-Ta system. However, it is round that a mixture of nanocrystalline Cu and Mo Is formed in the Cu-Mo system. The neutron diffraction has been employed at a main tool to characterize the detailed amorphization process. The formation of an amorphous phase in Cu-Ta system can be understood by assuming that the smaller Cu atoms preferentially enter into the bcc Ta lattice during ball milling.

• 통합자연과학논문집
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• 제1권2호
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• pp.84-88
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• 2008

The formation and thermal properties of the $BaO_2$ and $TiO_2$ mixtures were prepared by mechanical alloying method was investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM), and thermogravimetric/differential thermal analysis (TG/DTA). The rotating speed of 750 rpm shows more effects on the formation of $BaTiO_3$ single phase. The internal strain calculated using Williamson-Hall method was $4.27{\times}10^{-3}$ for the mixture milled for 300 min, the crystallite size was calculated using the Scherrer method decreased with milling time. The $BaTiO_3$ crystal improved crystallinity was formed by thermal annealing at a temperature of $600^{\circ}C$ for 1 h for the mixture milled for 300 min.

• 한국세라믹학회지
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• 제29권8호
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• pp.630-638
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• 1992

Ta2O5 alloying into 3 mol% Y2O3-stabilized tetragonal ZrO2 polycrystals (3Y-TZP) increased the degradation during aging at 265℃ and the fracture toughness; both are determined by the amount of transformed m-ZrO2. It was proposed that the mechanism underlying the t→m transformation when aged at low temperatures is attributed to the reorientation of (Zzr'V ). complexes parallel to [111] lattice direction, which is accompanied by a relaxation of TZP lattice during annealing at low temperature. A small strain which results from the reorientation gives rise to a localized mechanical instability, thus lowering the nucleation barrier so that the t→m phase transformation (degradation) proceeds. The amount of transformed m-ZrO2 during aging becomes greater as the chemical free energy change related to the transformation, ΔGo, increases with increasing the Ta2O5 alloying content.

• 한국주조공학회지
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• 제9권6호
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• pp.483-489
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• 1989

In the stable eutectoid transformation of austenite in ductile cast iron, ferrite forms around the graphite spheroid. As carbon diffuses through the ferrite ring, the graphite spheroid must eularge and the ferrite ring must deform plastically to accomodate this growth. A model has been proposed to clarify this mechanism. The alloying effects of molybdenum, nickel and copper were studied in a series of heats cast into a range of casting section sizes. Regression analysis was used to illustrate the effects of alloying and cooling rate on the microstructure of ductile cast iron.

• 한국표면공학회지
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• 제27권4호
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• pp.215-222
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• 1994

The role dispersoids has been studied in a number of researches as a key point for the high strength application of dispersion strengthened aluminum alloy. The mechanical alloying(MA) process with high mechanical properties of dispersion strengthened MA Al-8Ti-1B alloys were invested in order to evaluate their stress corrosion cracking(SCC) application. SCC properties of the mechanically alloyed Al-8Ti-1B were studied using slow strain rate test(SSRT). In this study Al-8Ti-1B alloy were more susceptible to SCC in solutions of pH=2.01 and 13.2 than pH=6.81 solution. In this study Al-8Ti-1B alloys by MA had more SCC resistance than Al-8Ti alloys or Al 7075-T73 alloys. So Al-8Ti-1B alloys by MA had more resistance in SSRT SCC susceptinility test than any other above alloying metals.