• Title/Summary/Keyword: alloy loss

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Corrosion resistance and Hardness of Tin-Nickel Electrodeposits (주석-니켈합금 도금층의 내식성 및 경도)

  • 예길촌;채영욱
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.521-530
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    • 1999
  • The corrosion resistance and the hardness of the tin-nickel alloy deposits electroplated in pyrophosphate bath were invesitigated according to electrolysis conditions and microstructure of the alloy. The weight loss of alloy deposits increased with the Sn content of single phase (Ni-Sn) alloy showing the lowest weight loss in the alloy with 54∼57wt% Sn. On the other hand, the multiphase alloy with 35∼42wt% Sn showed the highest one. The CASS test result was consistent with that of immersion test, and was good agreement with the corrosion data of polarization measurements. The hardness of alloy deposits decreased with the increase of Sn ratio in bath due to the grain size increase of the alloy. However, it increased noticeably with decreasing current density in the bath condition of low Sn ratio (0.1)

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Electromagnetic Wave Absorption Characteristics of Nanocrystalline FeCuNbSiB Alloy Flakes/Polymer Composite Sheets with Different Flake Thickness

  • Lee, Tae-Gyu;Kim, Ju-Beom;Noh, Tae-Hwan
    • Journal of Magnetics
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    • v.14 no.4
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    • pp.155-160
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    • 2009
  • This study examined the effects of a decrease in thickness of magnetic alloy flakes on the electromagnetic wave absorption characteristics of nanocrystalline $Fe_{73.5}Cu_1Nb_3Si_{15.5}B_7$ (at.%) alloy flakes/polymer composite sheets available for a quasi-microwave band. The thickness of FeCuNbSiB alloy flakes decreased to 1-2 $\mu$m with increasing milling time up to 24 h, and the composite sheet including alloy flakes milled for 24 h exhibited considerably enhanced power loss properties in the GHz range compared to the sheets having non-milled alloy powders. Although a considerable increase in loss factor upon milling was observed in the narrow frequency range of 4-6 GHz, there was no correlation between the complex permeability and flake thickness. However, the complex permittivity increased with increasing milling time, and there was good agreement between the milling time and the frequency dependences of the complex permittivity and power loss.

Effect of Reinforcement Content on Damping Capacities for Castable Aluminum Matrix Composites Reinforced with SiC and Graphite Particles (SiC와 흑연 입자 강화 주조용 Al기지 복합재료의 진동감쇠능에 미치는 강화입자조성의 효과)

  • 최유송
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.1
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    • pp.47-58
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    • 2004
  • Loss factors of A356, Mn-Cu alloy and aluminum matrix composites reinforced with $SiC_p$ and Ni-coated graphite particles at various contents have been investigated using clamped-free cantilever beam method. The loss factors of half-power bandwidth of the specimens were measured over a wide range of frequencies from 50 to 3300Hz. Among the specimens, Al-10%$SiC_p$-10%$C_p$ showed the highest loss factor at the mode I, while Mn-Cu alloy showed the highest loss factors at the modes II and III. Consequently, at the mode I the Al-10%$SiC_p$--10%$C_p$ showed the loss factor of 0.00093, which is 2.64 and 1.58 times higher than those of A356 and Mn-Cu alloy, respectively.

Relationship Between AC and DC Magnetic Properties of an Iron-Based Amorphous Alloy for High Frequency Applications

  • Choi, Y.S.;Noh, T.H.;Lim, S.H.
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.24-30
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    • 1996
  • The relationship between effective permeability and the remanence ratio of an Fe-based amorphous alloy (Metglas 2605S3A) is investigated over a wide frequency range, in an effort to understand magnetization behavior of the alloy. In the frequency range from 1 to 200 kHz, the permeability is maximum at the remanence ratio of 0.4-0.5 and, at frequencies over 500 kHz, the correlation with negative coefficients emerges indicating that the permeability decreases with the remanent ratio, except for the ribbon coated with an insulating layer of MgO which exhibits both high values of the effective permeability and remanence ratio. It is considered from the correlation results that the boundary at which the dominant magnetization mechanism changes from domain wall motion to spin rotation is near 500 kHz. The core loss is also investigated as a function of annealing time when the samples are annealed at a fixed temperature of $435^{\circ}C$. The core loss in most cases decreases with the annealing time, the degree of the loss may consist of the hysteresis loss and anomalous eddy current loss. The two loss components are considered to be of similar magnitudes at low frequencies while, at high frequencies, the dominant contribution to the total loss is the anomalous loss.

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Wear Resistance of Al Alloy Matrix Composites Using Porous Iron Aluminide-$SiC_p$ Preforms (Iron Aluminide-$SiC_p$ 혼합 예비성형체를 사용한 Al합금기 복합재료의 내마모 특성)

  • Cha, Jae-Sang;Oh, Sun-Hoon;Choi, Dap-Chun
    • Journal of Korea Foundry Society
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    • v.23 no.1
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    • pp.30-39
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    • 2003
  • Porous hybrid preforms were fabricated by reactive sintering using the compacts consisting of SiC particles, Fe and Al powders. Squeeze casting processing was employed to produce the composite in which the matrix phase is Al-Si7Mg. The microstructural change and wear resistance of the composites were investigated in terms of an amount of SiC particles. The wear loss was increased with increasing the contact pressure in the alloy containing SiC particles coated with Cu. The most drastic change was found to the specimen tested at 2.5 MPa of contact pressure. Concerning the alloys containing SiC particles coated with Ni-P, a drastic increase in the wear loss exhibited at 2 MPa of contact pressure in those alloys containing 4 and 8 wt. % of SiC particles coated with Ni-P. In the alloy containing 16 wt. % a proportional increase in wear loss was observed to the change of contact pressure. With respecting to the sliding velocity, the wear loss of the alloy containing SiC particles coated with Cu increased at the initial stage of wear process and then decreased. Similar result was found in the alloys containing SiC particles coated with Ni-P. On the basis of the present results obtained, it was found that wear resistance of the alloys tested was improved to show in the order of the alloy reinforced by coated SiC particles > by uncoated SiC particles > by intermetallic compound without SiC particles.

Laser Cladding with Al-36%Si Powder Paste on A319 Al Alloy Surface to Improve Wear Resistance (A319 알루미늄 합금 표면에 Al-36%Si 합금분말의 레이저 클래딩에 의한 내마모성 향상)

  • Lee, Hyoung-Keun
    • Journal of Welding and Joining
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    • v.35 no.2
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    • pp.58-62
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    • 2017
  • A319 aluminum alloy containing 6.5% Si and 3.5% Cu as major alloying elements has been widely used in machinery parts because of its excellent castability and crack resistance. However it needs more wear resistance to extend its usage to the severe wear environments. It has been known that hyper-eutectic Al-Si alloy having more than 12.6% Si contains pro-eutectic Si particles, which give better wear resistance and lubrication characteristics than hypo-eutectic Al-Si alloy like A319 alloy. In this study, it was tried to clad hyper-eutectic Al-Si alloy on the surface of A319 alloy. In the experiments, Al-36%Si alloy powder was mixed with organic binder to make a fluidic paste. The paste was screen-printed on the A319 alloy surface, melted by pulsed Nd:YAG laser and alloyed with the A319 base alloy. As experimental parameters, the average laser power was changed to 111 W, 202 W and 280 W. With increasing the average laser power, the melting depth was changed to $142{\mu}m$, $205{\mu}m$ and $245{\mu}m$, and the dilution rate to 67.2 %, 72.4 % and 75.7 %, and the Si content in the cladding layer to 16.2 %, 14.6 % and 13.7 %, respectively. The cross-section of the cladding layer showed very fine eutectic microstructure even though it was hyper-eutectic Al-Si alloy. This seems to be due to the rapid solidification of the melted spot by single laser pulse. The average hardness for the three cladding layers was HV175, which was much higher than HV96 of A319 base alloy. From the block-on-roll wear tests, A319 alloy had a wear loss of 5.8 mg, but the three cladding layers had an average wear loss of 3.5 mg, which meant that an increase of 40 % in wear resistance was obtained by laser cladding.

Analysis of Mechanical Fixation Made of Aluminum Alloy in an Axial Flux Permanent Magnet Machine

  • Lee, Jiyoung;Park, Byounggung;Koo, Daehyun
    • Journal of Magnetics
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    • v.19 no.3
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    • pp.309-313
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    • 2014
  • This paper presents an eddy current loss analysis of a Mechanical Fixation (MF) made of 6061 aluminum alloy, which is used for an NS type double-rotor single-stator axial flux permanent magnet machine. The prototype MF made of aluminum alloy shows good mechanical performance, but poor electro-magnetic performance, since the machine's efficiency can decrease because of eddy current loss in the MF. In order to prevent efficiency decrease, a modification of the MF structure is also introduced. Three-dimensional finite element analysis (FEA) is used for magnetic field analysis, and eddy current losses are computed. The analysis results are compared to, and verified by the test results.

DEPENDENCY OF SINGLE-PHASE FAC OF CARBON AND LOW-ALLOY STEELS FOR NPP SYSTEM PIPING ON PH, ORIFICE DISTANCE AND MATERIAL

  • Moon, Jeong-Ho;Chung, Hung-Ho;Sung, Ki-Woung;Kim, Uh-Chul;Rho, Jae-Seong
    • Nuclear Engineering and Technology
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    • v.37 no.4
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    • pp.375-384
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    • 2005
  • To investigate the flow-accelerated corrosion (FAC) dependency of carbon steel (A106 Gr. B) and low-alloy steels (1Cr-1/2Mo, 21/4Cr-1Mo) on pH, orifice distance, and material, experiments were carried out. These experiments were performed using a flow velocity of 4 m/sec (partly 9 m/sec) at pH $8.0\~10.0$ in an oxygen-free aqueous solution re-circulated in an Erosion-Corrosion Test Loop at $130^{\circ}\;{\ldots}$ for 500 hours. The weight loss of the carbon steel specimens appeared to be positively dependent on the flow velocity. That of the carbon and low-alloy steel specimens also showed to be distinguishably dependent on the pH. At pH levels of $8.0\~9.5$ it decreased, but increased from 9.5 to 10.0. Utility water chemistry personnel should carefully consider this kind of pH dependency to control the water system pH to mitigate FAC of the piping system material. The weight loss of the specimens located further from the orifice in the distance range of $6.8\~27.2$ mm was shown to be greater, except for 21/4Cr-1Mo, which showed no orifice distance dependency. Low alloy steel specimens exhibited a factor of two times better resistance to FAC than that of the carbon steel. Based on this kind of FAC dependency of the carbon and low-alloy steels on the orifice distance and material, we conclude that it is necessary to alternate the composition of the secondary piping system material of NPPs, using low-alloy steels, such as 21/4Cr-1Mo, particularly when the system piping has to be replaced.

Effects of W Contents in Co Matrix of the Thermal Sprayed WC-Co on the Corrosion Behavior in Molten Zinc

  • Seong, Byeong-Geun;Hwang, Sun-Young;Kim, Kyoo-Young;Lee, Kee-Ahn
    • Corrosion Science and Technology
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    • v.6 no.4
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    • pp.147-153
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    • 2007
  • This study sought to investigate the reaction of Co-binder containing tungsten with molten zinc. Four kinds of Co-W alloys (pure, 10%W, 20%W, 30%W) were prepared using the powder metallurgy method. The specimens were immersion-tested in molten pure zinc baths at $460^{\circ}C$. To evaluate the corrosion property in molten zinc, the weight loss of the specimen was measured after the immersion tests at different immersion times (10~300 min.). Co-10%W alloys, compared with pure cobalt, showed no effect of tungsten addition on the reaction rate in molten zinc. The relationship between the weight loss and the square root of immersion period represents a straight line in both pure cobalt and Co-10%W alloy. The Co-Zn reaction layer in Co- 1O%W alloy consists of $\gamma2$, $\gamma1$, $\gamma$ and ($\beta1$ phases. The rate of weight loss significantly increases and the weight loss behavior is not well accord with the linear relationship as the tungsten content in the Co-W alloy increases. The $\beta1$ layer was not formed on the Co-20%W alloy and neither was a stable Co-Zn intermetallic compound layer found on the Co-30%W alloy. The main cause of increase in reaction rate with increasing tungsten content is related with the instability of the Co-Zn reaction phases as seen on micro-structural analysis.

Microstructural Change and Magnetic Properties of Nanocrystalline Fe-Si-B-Nb-Cu Based Alloys Containing Minor Elements

  • Nam, Seul-Ki;Moon, Sun-Gyu;Sohn, Keun Yong;Park, Won-Wook
    • Journal of Magnetics
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    • v.19 no.4
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    • pp.327-332
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    • 2014
  • The effect of minor element additions (Ca, Al) on microstructural change and magnetic properties of Fe-Nb-Cu-Si-B alloy has been investigated, in this paper. The Fe-Si-B-Nb-Cu(-Ca-Al) alloys were prepared by arc melting in argon gas atmosphere. The alloy ribbons were fabricated by melt-spinning, and heat-treated under a nitrogen atmosphere at $520-570^{\circ}C$ for 1 h. The soft magnetic properties of the ribbon core were analyzed using the AC B-H meter. A differential scanning calorimetry (DSC) was used to examine the crystallization behavior of the amorphous alloy ribbon. The microstructure was observed by X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscope (SEM). The addition of Ca increased the electrical resistivity to reduce the eddy current loss. And the addition of Al decreased the intrinsic magnetocrystalline anisotropy $K_1$ resulting in the increased permeability. The reduction in the size of the ${\alpha}$-Fe precipitates was observed in the alloys containing of Ca and Al. Based on the results, it can be concluded that the additions of Ca and Al notably improved the soft magnetic properties such as permeability, coercivity and core loss in the Fe-Nb-Cu-Si-B base nanocrystalline alloys.