• Title/Summary/Keyword: alkaloid

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Simultaneous - Automated Determination of Nicotine Alkaloid, Reducing Sugar, Total Sugar and Ammonia on the Same Extract of Tobacco Leaf. (니코틴 알카로이드, 환원당, 전당, 암모니아의 동시자동분석법)

  • 김신일;황건중;김찬호
    • Journal of the Korean Society of Tobacco Science
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    • v.4 no.1
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    • pp.73-78
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    • 1982
  • A procedure for the simultaneous determination of reducing sugar, nicotine alkaloid, total sugar and ammonia has been developed. The four components of tobacco extracted from ground tobacco sample with 2 % acetic acid were deter mined with a Technicon autoanalyzer system. The relative errors in burley and flue-cured tobacco leaves were 3.6% in comparison with each official methods.

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Studies on the Alkaloid from Polygala tenuifolia Willdenow (원지의 염기성성분에 관한 연구)

  • 김제훈
    • YAKHAK HOEJI
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    • v.8 no.2
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    • pp.59-61
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    • 1964
  • A new alkaloid, named tenuidine was isolated from Polygala tenuifolia Willdenow. Its molecular formula corresponded to $C_{21}$ $H_{31}$ $O_{5}$ $N_{3}$ and its constants were m.p.256, [.alpha.]$_{D}$$^{18.5}$=1200.deg.(ethanol). Its infrared absorption spectra exhibited bands at 3.300, 1600, 1580, 1500 $cm^{-1}$ / confirming indole ring and at 2800-2700 $cm^{-1}$ / indicating quinoline ring. Bands at 1610, 1530 $cm^{-1}$ / indicated the presences of benzene ring and 1642$cm^{-1}$ / carbochelate.e.e.

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Studies on the Culture of Ergot Fungus.(I) (맥각균의 배양에 관한 연구 I)

  • 김병각
    • YAKHAK HOEJI
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    • v.12 no.3_4
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    • pp.85-88
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    • 1968
  • To select sclerotia to be used for strain isolation, water-soluble and water-insoluble alkaloids contents of the sclerotia of ergot fungus were determined. The sclerotia parasitic on the genus Elymus were found to contain greater amount of the alkaloids, up to 1.44%, than the sclerotia from the genus Agropyron. The major portion of the total alkaloid contents was the water-insoluble alkaloids. No correlation was found between the alkaloid contents and the lipid contents of the sclerotia analyzed.

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Spinacine from panax ginseng

  • Han, Young-Nam;Ryu, Si-Yong;Han, Byung-Hoon;Woo, Lin-Keun
    • Archives of Pharmacal Research
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    • v.10 no.4
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    • pp.258-259
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    • 1987
  • An alkaloid was isolated form water-soluble fraction of Panax ginseng roots. It was characterized by spectroscopic data and dynthesis as 4, 5, 6, 7-tetrahydroimidazo (4, 5-c) pyridine-6-carboxylic acid or spinacine, which was first isolated from the plant kingdom.

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Studies on the Alkaloidal Components of the Fruits of Lycium chinense

  • Han, Byung-Hoon;Park, Jeong-Hill;Park, Myung-Hwan;Han, Yong-Nam
    • Archives of Pharmacal Research
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    • v.8 no.4
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    • pp.249-252
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    • 1985
  • $N_{9}$-Formylharman, 1-carbomethoxy-$\beta$-carboline and perlolyrine with an unidentified alkaloid ($C_{10}H_{13}NO_{2}$, $M^{+}$ 179.094) have been isolated from the fruits of Lycium chinense Miller (Solanaceae) and characterized on the basis of chemical and physical evidence.

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Optically Active Intermediate from the Degradation of (-)-Laudanosine, a Benzylisoquinoline Alkaloid, with Ethyl Chloroformate

  • Dong-Ung Lee;W. Wiegrebe
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.373-376
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    • 1991
  • Degradation of (-)-laudanosine, a 1-benzyl-1,2,3,4-tetrahydroisoquinoline alkaloid, with ethyl chloroformate (ECF) afforded an optically active chloro-carbamate as an intermediate. The reason why this intermediate exhibits an optical activity was investigated by comparison with the reactions of some model compounds with ECF. It may be supposed that the chloride group in a hypothetic carbenium ion intermediate stands very closely to the chiral center, so conserving optical activity. However, a neighboring group effect can not be excluded.

Piperoctadecalindine, a New Piperidine Alkaloid from Piper retrofractum Fruits

  • Ahn Jong Woong;Lee Chong Ock;Kim Eun Joo;Zee Ok Pyo;Kim Hyung Jin
    • Bulletin of the Korean Chemical Society
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    • v.13 no.4
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    • pp.388-391
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    • 1992
  • A chemical investigation of the fruits of Piper retrofractum (Piperaceae) has led to the isolation and characterization of a novel piperidine alkaloid, piperoctadecalidine together with three known alkaloids piperine, pipernonaline and guineensine. The structure of the new compound was detemined to be (2E,4E,14Z)-N-(2,4,14-Octadecatrienoyl) piperidine by spectral and synthetic methods.

Stereocontrolled asymmetric synthesis of pancratistatin

  • Park, Je-Eun;Kim, Sang-Hee;Ko , Hyo-Jin
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.362.1-362.1
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    • 2002
  • Pancratistatin is a highly oxygenated phenanthridone alkaloid. exhibits a high level of in vitro and in vivo cancer cell growth in inhibitory activity. and antiviral activity. The asymmetric synthesis of this alkaloid has been. accomplished from the commercially available (R)-(+)-3-Butyn-2-ol. We utilized the Claisen rearrangment and metathesis to install stereogenic centers in the cyclohexene ring that has absolute chemistry. (omitted)

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On the Contents of Alkaloids in the Cho O by Processing Methods

  • Kim, Ho-Kyoung;Lee, Hye-Won;Jeon, Won-Kyung
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.368.1-368.1
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    • 2002
  • Mesaconitine and hypaconitine were isolated from Cho O and identified by the spectroscopic methods. The contents of alkaloid (mesaconitine. aconitine and hypaconitine) in the Cho O and its processed products were determined by high performance liquid chromatography. Processed 1 and 2 methods reduced the contents of alkaloid than those of processed 3 and commercially processed Aconiti Tuber powder. (omitted)

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