• Title/Summary/Keyword: alkaline rock

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Petrochemical Study on the Alkaline Gabbroic Host Rocks of Titaniferous Magnetite Deposits in Gonamsan, Yeoncheon-Gun, South Korea (고남산(古南山) 함(含)티탄자철광상(磁鐵鑛床)의 모암(母岩)인 알카리반려암질암의 암석화학적(岩石化學的) 연구(硏究))

  • Chang, Ho Wan;Yum, Byoung Woo;Park, No Young
    • Economic and Environmental Geology
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    • v.20 no.2
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    • pp.85-95
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    • 1987
  • The host rocks of titaniferous magnetite deposits in Gonamsan are alkaline gabbros, which are typical of undersaturated alkaline rocks in terms of the lack of normative quartz. According to field occurrences and petrographic features, these alkaline gabbros are divided into 3 rock types: coarse-grained and pegmatitic rock, medium-grained rock with equigranular texture, and layered cumulate rock. All these rocks mainly contain clinopyroxene(salite), plagioclase(An 43-66), pargasite, and ilmenite. The accessory minerals are apatite, sphene, quartz, and sometimes titaniferous magnetite. Pargasite, sphene, and quartz are considered to be secondary minerals formed by the reaction among clinopyroxene, plagioclase and Fe-Ti oxide at deuteric stage. Fe-Ti oxides generally occur as ilmenite in the alkaline rocks, and titaniferous magnetite in the ore deposits. Layered cumulate rocks are characterized by a recurrence of discontinuous thin mesolayer of clinopyroxene-pargasite within leucolayer mainly composed of plagioclase. Clinopyroxene is cumulus mineral whereas plagioclase, ilmenite and apatite occur as intercumulus minerals. According to the variation diagrams of oxide and trace element contents against the differentiation index, incompatible elements, such as Na, Ba and Sr, show positive correlations whereas compatible elements, such as Mg and Cr, show negative correlations. However some compatible elements, such as Co, Ni and V show irregular variations, reflecting relative cumulate status of cumulus and intercumulus minerals. On the de la Roche multicationic diagram, these alkaline gabbros are distributed along the differentiation curve of undersaturated alkaline series from alkaline basaltic composition through basanitic composition to tephritic composition. Layered cumulate rocks, which are distributed between basanitic composition and tephritic composition, reflect their cumulate character, slightly scattering away from the curve. The medium-grained rock shows higher contents in Ba, Sr and light rare earch elements than the coarse-grained and pegmatitic rock. The former shows two times higher contents of total rare earth elements than the latter, $while(La/Lu)_{cn}$ ratios maintain fairly constant values of 5.08~5.06 in these two rocks. This means that coarse-grained and pegmatitic rock, as compared with the medium-grained rock, was formed by the earlier differentiated magma but rare-earth element distribution pattern remained almost parallel during differentiation. From the data the above mentioned, these alkaline gabbros are considered to be comagmatic and to be formed by intrusions of differentiated magmas in its reservoir.

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Petrology of the Cretaceous Volcanic Rocks in the Gyemyeong peak and Janggun peak area, Mt. Geumjeung, Busan (부산 금정산의 계명봉과 장군봉 일대 백악기 화산암류에 관한 암석학적 연구)

  • Kim, Hye-Sook;Kim, Jin-Seop;Moon, Ki-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.18 no.1
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    • pp.1-17
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    • 2009
  • This article carried studies of the petrographical and petrochemical characteristics on the Cretaceous volcanic rocks in the area of Janggun peak and Gyemyeong peak which is located at the northeastern area of Mt. Geumjeong, Busan. The areas are composed of andesitic rock, sedimentary rock, rhyolitic rock, and intrusive hornblende, biotite granites, in ascending order. According to petrochemistry, the major elements show the calc-alkaline rock series ranged medium-K to high-K. With increasing $SiO_2$, $Al_{2}O_{3}$, $Fe_{2}O_{3}$, $TiO_2$ CaO, MgO MnO and $P_{2}O_{5}$ are decreased and $K_{2}O$ and $Na_{2}O$ are increased in the volcanic rocks. The trace element compositions show high LILE/HFSE ratios and negative anomaly of Nb, and REE patterns show enrichments in LREE and (-) anomaly values increase of Eu from the basaltic andesite to andesite facies, therefore the volcanic rocks have typical characteristics of continental margin arc calc-alkaline volcanic rocks, produced in the subduction environment. The volcanic rock show nearly the same patterns in spider and REE diagram. Fractional crystallization of the basaltic magma would have produced the calc-alkaline andesitic magma. And the rhyolitic magma seems to have been evolved from the basaltic andesitic magma with fractional crystallization of plagioclase, pyroxene, hornblende, biotite.

Geochronology and Petrochemistry of Foliated Granites between Damyang and Jinan (담양(潭陽)-진안(鎭安)사이에 분포(分布)하는 엽리상화강암류(葉理狀花崗岩類)에 대(對)한 지질시대(地質時代)와 성인(成因)에 관(關)한 연구(硏究))

  • Kim, Cheong Bin;Kim, Yong Jun
    • Economic and Environmental Geology
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    • v.23 no.2
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    • pp.233-244
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    • 1990
  • Plutons of Damyang-Jinan area consist of gray feldspar granite gneiss, biotite granite gneiss, foliated granites, Namweon granites, gabbro, biotite granite and Ogangri granite in term of mineralogical, texture and field evidence. From Isotope data of study area, chronological order of the Plutons are the Pre-cambrian gray feldspar granite gneiss(Ar39-Ar40, hornblende, $1998.4{\pm}8.3Ma$), middle to late Triassic Daegang foliated granite(Rb/Sr, whole rock, $288{\pm}4Ma$), foliated hornblende biotite granodiorite(K/Ar, hornblende, $198.7{\pm}9.9Ma$), Sunchang foliated granodiorite(Rb/Sr, whole rock, $222{\pm}4Ma$), foliated two mica granite, Samori foliated granite and Namweon granite(Rb/Sr, whole rock, $211{\pm}3Ma$: K/Ar, hornblende, $203{\pm}10.2Ma$), middle Jurassic Gabbro(K/Ar, hornblende, $180.7{\pm}9MA$) and biotite granite, and Cretaceous Ogangri granite. According to variations diagrams of $Al_2O_3$ versus normative PI(100 An)/(Ab+An), Daegang foliated granite is plotted on tholeiitic series, and other foliated granites on calc alkaline rock series which are consider to be formed by magmatism at continental margin and island arc region. And alkalinity versus $SiO_2$ shows that Daegang folited granite and Samori foliated granite are correspond to alkaline region, foliated hornblende biotite granodiorite and Sunchang foliated granodiorite to calc alkaline region, and foliated two mica granite to both regions. According to ACF diagrams, Daegang and Samori foliated granites are plotted on S-type. Foliated hornblende biotite granodiorite and Sunchang foliated granodiorite on I-type, and foliated two mica granite on both type. Foliated granites are a series of differentiated products from cogenetic magma, and effected under ductile sheared zone. Characteristic foliation of foliated granites are considered to be generated by dextral strike slip faulting and ductile shearing.

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Determination of Rare Earth Elements Abundance in Alkaline Rocks by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) (ICP-MS를 이용한 알칼리암의 희토류원소 정량분석)

  • Hur, Soon-Do;Lee, Jong-Ik;Lee, Mi-Jung;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.53-62
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    • 2003
  • Inductively coupled plasma mass spectrometry (ICP-MS) is useful instrument for determining abundance of rare earth elements, due to very low detection limits and rapid data acquisition. In this article, two methods are used for decomposition of alkaline rocks; close vessel acid digestion and $Na_2Co_3$ fusion. The two analytical results show good agreements. Considering total dissolved solids and detection limits, the most adequate dilution factor is 5,000 times. Polyatomic ion interferences during analysis can give rise to Inaccuracies. After correction from oxide and hydroxide interference, the analytical result show 20-30% decrease for Gd and Tm, 10-20% decrease for Tb and Er. In comparing the analytical results from KORDI with other institutes, most rare earth elements abundance show good agreements except Lu.

Diversity of the Cretaceous basaltic volcanics in Gyeongsang Basin, Korea (경상분지내 백악기 현무암질 화산암류의 다양성)

  • 김상욱;황상구;이윤종;고인석
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.1-12
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    • 2000
  • The Cretaceous basaltic rocks in Gyeongsang Basin are temporally and spatially dispersed widely in thick sedimentary piles: Chilgog basaltic rock (CGB) and Cheongyongsa basaltic rock (CSB) in the Shindong Group, and Hakbong basaltic rocks (HBB), Osibbong basalt (OSB), Secheondong basaltic rocks (SCB), Haman basaltic rocks (HAB), Hama basaltic rocks (HMB), and Chaeyaksan basaltic rocks (CYB) in the Hayang Group, upwardly in their stratigraphy. Chilgog basaltic rock is merely identified as pebbles in the Shilla Conglomerate and its provenance has not been found, and it is characteristics that the volcanics except Osibbong basalt and Chaeyaksan basaltic rocks are very small in both of their thickness and extension. Petrochemical diversity of the basaltic rocks are revealed; OSB and SCB distributed in the Yeongyang Minor Basin preserve the calc-alkaline natures in major and immobile minor element geochemistry, but CGB, HBB, HAB, and CYB reflect that they might be originated from calc-alkaline basaltic magma of volcanic arc in continental margin area by trace elements and altered to alkaline suites in the viewpoint of their major element geochemistry. Major and trace element geochemistry of CSB and HMB suggests that they may be derived from within -plate alkaline magma contaminated by the upper continental crust, especially in the case of the former.

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Case Study on the Treatment of Acid Rock Drainage from an Embankment with Pyrite Rocks (황철석 암버럭을 이용한 고속도로 성토체의 산성배수 처리 사례 연구)

  • Gong, Jeong-Sik;Kim, Tae-Hyung;Song, Young-Suk
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.523-532
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    • 2021
  • The treatment of acid rock drainage was reviewed and evaluated for the case of pyrite rocks distributed in a highway embankment. During the highway's construction, neutralization using alkaline water repellent was applied to the embankment section to prevent acid rock drainage. However, it still occurred long after the construction was completed owing to rain infiltration, and the acid rock drainage polluted the surrounding soils and streams. To solve this problem, treatment facilities such as SAPS (Successive Alkalinity Producing Systems) or ecological wetlands and sand filtration were installed. After the installation of the treatment facilities, the effluent and soils contaminated by acid rock drainage nearby the outlet of the facilities were analyzed and evaluated for a period of years. Measurements of the pH of the effluent and analysis of the heavy metal contamination of the soils confirmed that the neutralization treatment for acid rock drainage is being performed properly and that contamination of heavy metals in the acid rock drainage is also being stably controlled by the treatment facilities.

국내 심부 암반지하수의 수리지구화학 진화와 관련된 고농도 불소 산출 특성

  • Kim Gyeong-Ho;Yun Seong-Taek;Chae Gi-Tak;Kim Seong-Yong;Gwon Jang-Sun;Go Yong-Gwon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.101-104
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    • 2005
  • To understand the geologic and hydrogeochemical controls on the occurrence of high fluoride concentrations in bedrock groundwaters in South Korea, we examined a total of 367 hydrochemistry data obtained from deep groundwater wells (avg, depth = 600 m) that were drilled for exploitation of hot springs. The fluoride concentrations were generally very high (avg. 5.65 mg/L) and exceeded the Drinking Water Standard (1.5 mg/L) in 72% of the samples, A significant geologic control of fluoride concentrations was observed: the highest concentrations occur in the areas of granitoids and granitic gneiss, while the lowest concentrations in the areas of volcanic and sedimentary rocks. In relation to the hydrochemical facies, alkaline $Na-HCO_3$ type waters had remarkably higher F concentrations than circum-neutral to slightly alkaline $Ca-HCO_3$ type waters. The Prolonged water-rock interaction occurring during the deep circulation of groundwater in the areas of granitoids and granitic gneiss is considered most important for the generation of high F concentrations. Under such condition, fluoride-rich groundwaters are likely formed through hydrogeochemical processes consisting of the removal of Ca from groundwater via calcite precipitation and/or cation exchange and the successive dissolution of plagioclase and F-bearing hydroxyl minerals (esp. biotite). Thus, groundwaters with high pH and very high Na/Ca ratio within granitoids and granitic gneiss are likely most vulnerable to the water supply problem in relation to the enriched fluorine.

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A geochemical study on the metal contamination of groundwater in Taegu City (대구시 지하수의 금속 오염에 대한 지화학적 연구)

  • 이재영;김영기;이진국;서정율
    • The Journal of Engineering Geology
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    • v.2 no.2
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    • pp.173-200
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    • 1992
  • The quality of groundwater in the central part of Taegu City is influenced by upstreams of Sin-stream and Beomeo-stream because the stream waters are main source of the groundwater, and chemical composition of the upstream waters has close relationship with andesite and monzonite in the igneous rock terrain. The pH of upstreams are weak acid ~ neutral in the igneous rock area and weak alkaline in the sedimentary rock area. Contents of $Ca^{2+}$ and $Mg^{2+}$ in the streams are apparently high, and $Na^{+}$ content is only slightly high in the sedimentary rock area. But $K^{+}$ content is lower in the Panyaweol formation area than in the monzonite area. The contents of heavy metals and $N0_3^{-}$ are also higher in the sedimentary rock area of residential sections and industrial complexes than those in the igneous rock area. The groundwater is contaminated in comparison to the upstream water of the igneous rock areas, and there are some differences in pollution level between the Panyaweol formation area of residential sections and the Haman formation area of industrial complexes. K, Na, Ca, Mg, Cl, $SO_4$ and $NO_3$ contents in the Haman formation area are relatively higher than those in the Panyaweol formation area. But pH is nearly equal in the two areas. The content of heavy metal ions is still lower than the drinking water standard of Korea and only slightly differs in the two sedimentary rock areas. But the groundwater in the Haman formation area is considerably contaminated by Kongdanstream and Dalseo-stream.

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Petrology of the Cretaceous volcanic rocks in northern Yucheon Minor Basin, Korea (북부 유천소분지에 분포하는 백악기 화산암류에 대한 암석학적 연구)

  • Sang Wook Kim;Sang Koo Hwang;Yoon Jong Lee;Jae Young Lee;In Seok Koh
    • The Journal of the Petrological Society of Korea
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    • v.7 no.1
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    • pp.27-36
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    • 1998
  • The volcanic piles in the northern Yucheon Minor Basin area are the Hagbong basaltic rocks, the Chaeyaksan basaltic rocks, the Jusasan andesitic rocks, the Unmunsa rhyolitic rocks, and the Tertiary voicanics. Stratigraphically, from the lowermost, (1) the Hagbong basaltic rocks are composed mainly of basaltic tuff with two olivine basalt flows intercalated, (2) the Chaeyagsan basaltic rocks are predominantly in tuffs and agglomerate with 3 basaltic flow interlayers, (3) the Jusasan andesitic rocks consist of thick piles of alternated sequences of 4 andesite flows and 5 andesitic tuffs and tuffaceous sediments and (4) the Unmunsa rhyolitic rocks which embed some rhyolite and obsidian are dominant in tuffs such as ash flow and crystal welded tuff. These volcanics reveal distinguishable characteristics in petrochemistry. In discriminating by major elements, the Hagbong and the Chaeyagsan basaltic rocks are alkaline, whereas the latter is also spilitic. In comparison, the volcanic rocks of the Jusasan andesitic rocks and the Tertiary sequences are characteristically calc-alkaline although their distribution is spatially separated. On the other hand, the variations in immobile trace elements indicate that the Hagbong basaltic rocks range from alkaline to calc-alkaline and from WPB/VAB transition to VAB, whereas the Chaeyagsan basaltic rocks are calc-alkaline WPB/VAB transition type and the two others calc-alkaline VAB. In order to show such a variety in their rock series of the volcanic rocks, the environment during their magma generation, magma rising, and post-eruption alteration could be positively considered.

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Stratigraphic Implication of the Daljeon Basalt in the Miocene Pohang Basin, SE Korea (한반도 동남부 마이오세 포항분지 내 달전현무암의 층서적 의미)

  • Song, Cheol Woo;Kim, Hyeonjeong;Kim, Jong-Sun;Kim, Min-Cheol;Son, Moon
    • The Journal of the Petrological Society of Korea
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    • v.24 no.4
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    • pp.323-335
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    • 2015
  • Although the Daljeon Basalt in the Pohang Basin is important for interpreting the basin evolution, its relative chronology, stratigraphic position, and isotopic age still remain controversial. In order to clear up the controversies, this study carried out detailed field investigation to determine its distribution and occurrence together with reanalysis of its previous geochemical data and $^{40}Ar/^{39}Ar$ age dating. Based upon the field investigation, the basalt occurring in the central part of the Pohang basin is composed of three main bodies and a dozen of minor dikes and sills that intruded into the Yeonil Group. Their mineral assemblages consist of phenocrysts such as olivine and clinopyroxene and fine groundmasses of clinopyroxene, plagioclase, olivine, and opaque oxide, impling the porphyritic texture of alkaline basalt. All their geochemical data also show the similar geochemical characteristics in TAS, Zr-Ti, and REE/trace elements distribution diagrams. The samples are plotted on alkalic field in the total alkali-versus-silica diagram and show similar patterns to enrichment oceanic basalt or within plate basalt in trace elements. In addition, $^{40}Ar/^{39}Ar$ isochron age of 13.82Ma is obtained. These results indicate that the Daljeon Basalt is an alkaline intrusive rock belonging to the middle Miocene Yeonil Group.