• Title/Summary/Keyword: alkaline metal

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Cultural Condition of the Production of Alkaline Pretense by f parahaemolyticus(1) (V. parahaemolyticus에 의한 Alkaline Pretense 생산조건(1))

  • 양지영;한종흔;강현록;황미경;차재호
    • Journal of Food Hygiene and Safety
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    • v.15 no.2
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    • pp.176-178
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    • 2000
  • V parahaemolyticus possessed an extracellular alkaline pretense activity during the stationary growth phase. Various factors such as nitrogen sources, the concentration of NaCl and metal ions were investigated for optimizing the production of alkaline pretense from V. parahaemolyticus ATCC 17802. Among the nitrogen sources tested skim milk showed the distinct increase of the activity and the activity was the highest at 2% in final concentration after 60 hours incubation. The addition of NaCl and metal ions did not increase the alkaline pretense activity. CoC$_2$, CuC1$_2$, and HgCl rather highly inhibited alkaline protease production.

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Effect of Alkaline Earth Metal Oxides addition on the Low-voltage Characteristics of MgO Films as a Protective layer for AC PDPs (PDP 보호막용 MgO 박막의 저전압 특성에 미치는 알카리토금속산화물 첨가 효과)

  • Jo, Jin-Hui;Kim, Rak-Hwan;Kim, Jeong-Yeol;Lee, Yu-Gi;Kim, Hui-Jae;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.441-445
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    • 1999
  • Alkaline earth metal oxides were added to the conventional MgO films as a protective layer for dielectric materials to have lower firing voltage(Vf) of the plasma display panel(PDP). Panels with various protective layers of MgO-alkaline earth metal oxides were prepared on glass by using e-beam evaporation and its effect on firing voltage characteristics were investigated. (Ba-Mg)O films had poor voltage characteristics because of higher activation energy of BaO. But, (Sr-Mg)O, (Ca-Mg)O and (Ca-Sr-Mg) O had better voltage characteristics than the conventional MgO. A mixture film of (Mg-Ca-Sr)O show the lowest firing voltage which is less than that of MgO by 20V. The chemical composition to have lowest firing voltage is MgO:SrO:CaO ratio of 6:2:2. The mixture of MgO-Alkaline earth metal oxides films showed good transmittance properties within the visual range.

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Grain Growth Behavior of (K0.5Na0.5)NbO3 Ceramics Doped with Alkaline Earth Metal Ions

  • Il-Ryeol Yoo;Seong-Hui Choi;Kyung-Hoon Cho
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.135-141
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    • 2023
  • The volatilization of alkali ions in (K,Na)NbO3 (KNN) ceramics was inhibited by doping them with alkaline earth metal ions. In addition, the grain growth behavior changed significantly as the sintering duration (ts) increased. At 1,100 ℃, the volatilization of alkali ions in KNN ceramics was more suppressed when doped with alkaline earth metal ions with smaller ionic size. A Ca2+-doped KNN specimen with the least alkali ion volatilization exhibited a microstructure in which grain growth was completely suppressed, even under long-term sintering for ts = 30 h. The grain growth in Sr2+-doped and Ba2+-doped KNN specimens was suppressed until ts = 10 h. However, at ts = 30 h, a heterogeneous microstructure with abnormal grains and small-sized matrix grains was observed. The size and number of abnormal grains and size distribution of matrix grains were considerably different between the Sr2+-doped and Ba2+-doped specimens. This microstructural diversity in KNN ceramics could be explained in terms of the crystal growth driving force required for two-dimensional nucleation, which was directly related to the number of vacancies in the material.

The Behavior of Electrolytes in Nonaqueous Solutions (IV). Relative Viscosities and Osmotic Coefficients of Alkaline Metal Iodides (물아닌 용액에서의 전해질의 행동에 관한 연구 (제4보). 요오드화알칼리금속의 상대점도와 삼투계수)

  • Si-Joong Kim;Jin-Ho Kim;Kyu-Seong Choi
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.349-354
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    • 1984
  • The relative viscosities and the osmotic coefficients of alkaline metal iodides (NaI, KI, RbI, CsI) in methanol, ethanol, dimethylsulfoxide (DMSO), and sulfolane (TMS) have been measured by Ubbelohde viscometer and vapor pressure osmometry at 45 ∼ $120^{\circ}C.$ The order of A and B coefficients in viscosity for alkaline metal iodides are MeOH > EtOH > TMS > DMSO, and TMS > EtOH > DMSO > MeOH. dB/dT values for the alkaline metal iodides are in the order of NaI > KI > RbI > CsI in the protic solvents, while those for the aprotic solvents are in the reverse order. The order of the osmotic coefficients for the alkaline metal iodides is EtOH > DMSO > MeOH > TMS.

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Competitive Solvent Extraction of the Mixture of Alkali Metal and Alkaline Earth Metal Cation containing Crown Ether Carboxylic Acid and Crown Ether Phosphonic Acid (크라운에테르 카르복시산과 크라운에테르 포스포닉산을 포함한 알칼리 금속과 알칼리 토금속 양이온 혼합물의 경쟁적 용매추출)

  • Chung, Yeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.219-227
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    • 2005
  • Competitive solvent extraction of the mixure of alkali metal and alkaline earth cation from water into organic solvent containing the crown ether carboxylic acid and anlogous crown ether phosphonic acid was investigated as follows. The lipophilic group is found to strongly influence to the selective extraction in the mixed systems from only alkali metal cation for sym-(n-decyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ to mostly alkaline earth metal cation for sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxyacetic acid $\underline{3}$. Monoethyl sym-(n-decyldibenzo)-16-crown-5-oxymethylphosphonic acid $\underline{2}$. and monoethyl-sym- bis]4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{4}$ showed good selectivity for $Na^+$ over $Mg^{2+}$, the second extracted ion. Structural variation in the crown ether phosphonic acid somewhat was influenced to the extraction selectivity in the mixed systems. when variation of the ionized group is influenced in the mixed systems, the selectivity of $Na^+$ as the second extracted ion was much better crown ether carboxylic acid $\underline{1}$ than crown ether phosphonic acid $\underline{2}$, while the efficiency of $Na^+$ extraction was better $\underline{2}$ (83% total loading) than $\underline{1}$ (32%).

Production and Properties of Alkaline Pretense from Bacillus sp. Strain in Thermophilic and Alkaline Condition (Bacillus속 AP-5 균주의 고온성 알카리 배양에 따른 Alkaline Pretense의 생성 및 성질)

  • 이광배
    • Journal of environmental and Sanitary engineering
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    • v.5 no.2
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    • pp.103-110
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    • 1990
  • For production of thermophilic and alkaline protease, Bacillus sp. strain AP-5 was isolated from a compost. The production of the protease was reached at maximum for 4 days at $55^{\circ}$ in standing culture. Chitin and Cellulose as carbon source, and Skim Milk as nitrogen source were favorable for the production of the enzyme. Optimal temperature and optimal pH of the enzyme was $55^{\circ}$ and 11, respectively. Metal ion didn't effect on the enzyme activity, the protease was very stable at heat treatment of 30 min at $55^{\circ}$.

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Solvent Extraction of Alkali Metal and Alkaline Earth Metal Cations Using a Mono-Crown Ether and Bis-(Crown Ether)s (Mono-Crown Ether와 Bis-(Crown Ether)s를 이용한 알칼리금속과 알칼리토금속 양이온들의 용매추출)

  • Shin, Young-Kook;Kim, Hae-Joong
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.60-65
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    • 1997
  • Solvent extraction of alkali metal and alkaline earth metal cations by mono-crown ether(benzo-15-crown-5) and bis-(crown ether)s(ethylenediamine bis(4'-formyl benzo-15-crown-5)) containing benzo-15-crown-5 moieties were investigated with water-chloroform system at $25^{\circ}C$. The order of the extraction equilibrium constants($K_e$) and the complexation constants($K_c$) for the alkali metal and alkaline earth metal cations with mono-crown ether and bis-(crown ether)s were Ca(II)>Na(I)>Sr(II)>K(I)>Mg(II)>Rb(I) and Sr(II)>Ca(II)>K(I)>Rb(I)>Mg(II)>Na(I) respectively. These results were explained in terms of the size effect of metal cation and electron density effect. Also, the bis-(crown ether)s was found to extract metal cations more effectively than the corresponding mono-crown ether.

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Alkali & Alkaline-Earth Metal Sources for OLED Devices

  • Tominetti, S.;Cattaneo, L.;Longoni, G.;Bonucci, A.;Toia, L.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1763-1768
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    • 2006
  • Low work function alkali metals and alkaline earths successfully lower the electron injection barrier and increase electron injection into the organic layer in OLED displays, but their implementation is not easy. AlkaMax technology can ensure the required metal evaporation rate in a fast, homogeneous and easily controllable way.

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Ion Exchange Characteristics of Novel HDBPDA and Dowex Ion Exchange Resins (새로운 HDBPDA와 Dowex 이온교환수지의 이온교환 특성)

  • Kim, Dong Won;Kim, Chang Suk;Choi, Ki Young;Jeon, Young Shin;Jeong, Young Kyu;Yoon, Yeo Hag;Hon, Choon Pyo
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.463-469
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    • 1993
  • HDBPDA ion exchange resin, {(4, 5) : (13, 14)-Dibenzo-6, 9, 12-trioxa-3, 15, 21, -triazabicyclo [15. 3. 1]heneicosa-(1, 17, 19)(18, 20, 21) triene ion exchange resin : HDBPDA ion exchange resin} had a capacity of 3.8meq/g dry resin. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA and strongly acidic cation exchange resin, Dowex 50W-X8(200-400mesh) in water, and the various concentrations of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions for the HDBPDA ion exchange resin, but generally the distribution coefficient slightly increased with decreasing concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those in various hydrochloric acid concentration. The distribution coefficients of alkali and alkaline earth metal ions for the Dowex 50W-X8 ion exchange resin increased with decreasing hydrochloric acid concentration. Especially, the distribution coefficients of alkaline earth metal ions increased rapidly compared to those for alkali metal ions. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA ion exchange resin increased in a linear manner with decreasing acid concentration, and the slope, d log Kd/d log $M_{HCl}$ is about -0.2. Of the distribution cofficients of alkali metal ions on Dowex 50W-X8, at range of moderate hydrochloric acid concentration, the slope is about -1, while the slope for alkaline earth metal ions is about -2. However, at very low hydrochloric acid concentration, the linear variation between distribution coefficient and acid concentration was not occurred, but the slope was deviated from above values at low acid concentration.

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