• 임산에너지
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• 제18권2호
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• pp.62-69
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• 1999

목재 세포벽중의 셀룰로오스의 알칼리 팽윤구조는 리그닌에 의해 크게 영향을 받는다. 본 연구에서는 알칼리 팽윤특성에 관한 리그닌의 영향을 명확히 하기 위하여 신갈나무의 정상재 및 부후재를 이용하여 X선 회절법과 자외선 현미경법에 의해 검토하였다. 그 결과, 목재 셀룰로오스는 고농도의 알칼리 수용액 중에서 머서화 처리를 하여도 결정변태가 일어나지 않으며 탈리그닌 후에도 결정의 변화는 없었다. 즉, 목재세포벽중의 셀롤로오스 결정은 리그닌의 존재에 의해 알칼리 팽윤이 억제되어 결정의 변태는 발생하지 않으며 탈리그닌 후에도 결정의 구조는 변화되지 않는 것으로 생각되었다.

• 한국가구학회지
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• 제21권4호
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• pp.284-292
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• 2010

This research was carried out to examine the properties of fancy cherry veneer overlaid on the PF resin bonded Meranti plywood floor, which 2.5% green tea leaf powder was applied in the UV varnishes and the adhesives for scavenging the volatile organic compounds. The results were as follows: 1. The various properties of the treated samples, such as density, moisture content, thickness swelling, bending strength(MOR), adhesion shear strength, surface abrasion, curling, cyclic delamination test with boiling water, boiling property, cold-resistance and heat resistance, acid resistance and alkali resistance, and anti-contamination property showed no significant difference between the properties of the control samples. 2.5% green tea leaf powder treated floor gave a little better results than the control for surface scratch test. 2. In case of QUV and weathering test, no difference between the treated sample and control was found. 3. The floor was discolored by adding 10% green tea leaf powder to UV coating, and the floor was also discolored to light green during by the soaking test. The color of floor was not changed up to 5% addition level.

• 폴리머
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• 제34권1호
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• pp.58-62
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• 2010

전분을 매트릭스 고분자로 하여 아크릴 단량체를 유화중합 방법으로 그래프트 중합하였다. 에멀젼의 점도와 입자경은 전분 함량이 증가함에 따라 전분의 히드록시기가 물과 상호작용하고 고분자 입자가 분산매인 물 쪽으로 팽윤함으로 인해 증가하였다. 에멀젼의 화학적 안정성은 전분 함량이 증가할수록 양호하였으나 내수성과 내알칼리성은 전분 함량이 증가할수록 친수성이 증가하면서 감소하였다. 탄산칼슘을 포함한 전분-아크릴 에멀젼 배합물의 불투명도는 전분의 함광이 증가함에 따라 전분 고유의 색깔에 의해 감소하였고 도막의 상태는 전분의 함량이 증가함에 따라 도막의 무정형 상태가 증가하면서 균열이 없는 매끈한 외관을 나타내었다.

• 대한가정학회지
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• 제25권4호
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• pp.9-18
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• 1987

This study is conducted to investigate the influence of addition of quarternary ammonium salt(cetyl trimethyl ammonium bromide: CTAB) when polyester(PET) fabric is treated with sodium hydroxide(NaOH), depending on experimental variables such as CTAB concentration, NaOH concentration, time & temperature, and the change in physical & chemical properties of alkaline-hydrolyzed PET fabrics depending on their weight loss. The results are as follows: 1. By adding CTAB in aqueous NaOH, the weight loss of PET fabric is increased remarkably and until the concentration of CTAB is reached at its cmc, and the higher the concentration of CTAB are, the more weight loss on PET fibrics are. 2. The addition of CTAB in aqueous NaOH is most effective at lower NaON concentration(2%) among various NaOH concentration, on increasing the amount of weight loss, while there are almost similar results through various treatment time and temperature. 3. As the amount of weight of weight loss on PET fabric is increased, the increase of void space in the PET yarn, of softness & dyeability of PET fabric and the decrease of tensile strength are found. On the other hand, the moisture regain shows a little increase by alkaline-hydrolysis on PET fabric while vertical absorption test & water retention value are not sufficiently sensitive to distinguish between the hydrophillicity of untreated and treated PET fabric. The shrinkage of PET fabric is induced by swelling in hot aqueous NaOH regardless of NaOH concentration & addition of CTAB.

• 펄프종이기술
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• 제46권6호
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• pp.94-102
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• 2014

The physical and chemical properties of recycled fibers from mixed waste paper are more and more deteriorated because of unknown history of recycling times. In order to improve the mechanical properties of liner paper, the recycled fibers from wasted cotton clothes were used in papermaking process, and their applicabilities were evaluated in several points of fiber modification. Thus, two kinds of fiberizing methods from waste cotton clothes were considered by using rotary sandpaper and grinder mill. Finally, the rotary sandpaper method was relatively desirable in preserving longer fiber length and fibrillated fiber surface. The recycled cotton fibers by swelling treatment with NaOH and bleaching with reductive chemicals were mixed with OCC fibers, and the handsheets were prepared to basis weight of $80g/m^2$ and evaluated the mechanical properties of paper. The fibrous properties showed outstanding results in freeness and WRV improvements by alkali treatment and high brightness by reductive bleaching treatment. The physical and mechanical properties of sheet by mixing OCC fibers and recycled cotton fibers were also highly improved in tensile, burst strength and specially folding resistance.

• Applied Biological Chemistry
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• 제35권1호
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• pp.10-13
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• 1992

쌀보리 3품종의 전분을 큰 입자$(17{\sim}34$ 미크론)와 작은 입자$(4{\sim}20$ 미크론)로 분리하고 이들의 성질을 비교하였다. 작은 입자의 수는 새쌀보리가 62%, 늘쌀보리와 무등쌀보리는 75%였다. 전분의 일반성분과 물결합 능력은 큰 입자가 가장 낮았고, 청색도 값은 작은 입자가 낮은 값을 보였다. 팽윤력과 용해도는 입자별로 큰 차이가 없었고, 고유점도는 큰 입자가 작은 입자 보다 높았다. X-선 회절도는 큰 입자와 작은 입자 사이에 차이가 없었다. 알칼리에 의한 점도는 큰 입자가 높았고 복굴절성의 소실에 의한 호화 온도는 차이를 보이지 않았다.

• 한국식품조리과학회지
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• 제6권1호
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• pp.13-19
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• 1990

Cowpea, mung bean, Kidney bean and red bean are simular properties. In order to elucidate the similarity among these four starches, some physicochemical properties of starches were compared. Water binding capacity of kidney bean and red bean (199%) starches are higher than mung bean and cowpea. The solubility, swlling power and optical transmittance of the four starches showed a similar pattern, but kidney bean and red bean starches had a lower swelling power than cowpea starches. Cowpea, mung bean, kidney bean and red bean starches had the blue value of 0.41, 0.47, 0.42 and 0.50, the alkali content of 8.4, 8.0, 4.13, 4.13, the amylose content of amylose of 30,000, 29,268, 52, 173 and 33, 611 and glucose unit per segment of amylopectin of 27.6, 26.8, 18.35 and 12.9 respectively. The results of X-ray diffraction studies showed A pattern for four starches.

• Journal of Ginseng Research
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• 제9권2호
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• pp.270-284
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• 1985

In order to investigate the change of physicochemical properties of ginseng root starch during storage and heat treatment, the roots were stored for 15 days at 5 $^{\circ}C$, 15 $^{\circ}C$, 3$0^{\circ}C$ and 45$^{\circ}C$, and heated for 15 hours at 6$0^{\circ}C$, 7$0^{\circ}C$, 8$0^{\circ}C$, 9$0^{\circ}C$, respectively. The starch content was decreased from about 40% to 23-26% and sucrose content was increased from 4% to 12-16% during storage for 15 days at 5-45$^{\circ}C$. Maltose, which was not detected in fresh samples, was increased up to 8.5% during storage or heat treatment. Granular size of the starch was decreased and some of the granules were broken during storage. Amylose content in the starch was decreased from 33% to 20%, and blue value and alkali number of the starch were increased slightly, and solubility and swelling power of the starch were decreased during storage. 3 The higher storage temperature and the longer storage time, the starch was more susceptible to gelatinize, and the viscosity of the starch was lowered with the susceptibility of gelatinization. The susceptibility of degradation of the starch by the amylase was increased and amylolytic activities in ginseng root were, also, increased during storage.

• Applied Biological Chemistry
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• 제27권2호
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• pp.79-85
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• 1984

찰보리 품종(品種)인 창영과 스미레 전분(澱粉)을 분리(分離)하여 입자(粒子)의 성상(成狀)과 이화학적(理化學的) 특성(特性)을 검토(檢討)하였다. 광학현미경으로 본 입자(粒子)의 외형(外形)은 대부분 원형(形)으로 평균직경(平均直徑)은 창영 $13.4{\mu}$, 스미레 $16.6{\mu}$,이었고, X-ray회절도는 $2{\theta}$에서 메보리(영산품종(品種))에 비해 $17.2^{\circ},\;18.0^{\circ}$, 환의 회절강도(强度)가 다소 강했다. Amylose함량은 창영과 스미레 모두 4% blue value는 각각 0.22, 0.18이었고, alkali number는 5.2, 4.9, 팽화력(膨化力)은 167, 172이었다. 전분(澱粉)현탁액(0.1%)의 광투과도(光投過度)는 $51^{\circ}C$ 이후 급격히 증가(增加)했고 $51^{\circ}C{\sim}75^{\circ}C$에서 single stage 호화(糊化)양상을 보였다. Amylograph에 의한 전분(澱粉)의 호화개시온도(糊化開始溫度)는 창영 $63^{\circ}C$, 스미레 $62^{\circ}C$였고 $72^{\circ}C$에서 최고점도(最高粘度) 920, 900 B.U.를 보였으며 냉각점도(冷却粘度)의 상승률(上昇率)이 아주 낮았다. 팽윤현상(膨潤現象)은 $60^{\circ}C$ 이후에 급격히 증가(增加)해서 $90^{\circ}C$에서는 $27{\sim}30$정도(程度)였으며, $2^{\circ}C$에서 저장한 전분(澱粉) gel의 노화(老化)는 완만하게 진행(進行)되어 4일(日)째에는 25%정도(程度)였다.

• 한국식품과학회지
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• 제25권2호
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• pp.123-129
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• 1993

추청벼와 삼강벼를 원료로 하여 전분을 제조하고 그 전분을 이용하여 초산 쌀 전분을 제조하여 얻어진 초산 쌀 전분의 이화학적 성질을 검토하여 다음과 같은 결과를 얻었다. 초산 쌀 전분의 용해도와 팽윤력은 원료 전분에 비하여 높았으며 품종간에 약간의 차이를 나타내었다. 광투과도는 원료 전분에 비하여 높았으며 원료 전분은 $60^{\circ}C$, 초산 쌀 전분은 $50^{\circ}C$부터 증가하기 시작하였으며, blue value는 원료 전분보다 낮게 나타났다. alkali number는 원료 전분보다 약 7배 높았으며, 초산 쌀 전분 겔의 경도, 응집성, 접착성, 점착성 및 저작성은 원료 전분 겔보다 높았으며 품종간에 약간의 차이를 나타내었다. Amylograph에 의한 초산 추청 및 삼강벼 전분의 호화개시온도는 각각 $59^{\circ}C,\;62^{\circ}C$ 로서 초산 처리에 의해 $5{\sim}6^{\circ}C$ 낮아졌고, 초산 쌀 전분의 점도는 원료 전분에 비하여 $14{\sim}38%$ 증가하였으며 추청벼 전분이 삼강벼 전분보다 높았다. 초산 쌀 전분 입자의 표면구조는 원료 전분에 비하여 다소 팽윤되어 헝클어진 형태를 나타냈으며, $70^{\circ}C$ 30분 가열에 의해서 완전히 붕괴되었다.