• Title/Summary/Keyword: alkali materials

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Durability of glass fiber under the alkali environment (알카리 환경하에서 유리섬유의 내구성)

  • Kim, T.J.;Kim, K.S.;Choi, L.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.204-209
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    • 1999
  • 각종섬유를 연속섬유 보강재로 사용하는 경우, 일반적으로 수지를 매트릭스로 하여 봉재 형상(FRP rod)으로 제조하고있다. 성형된 섬유는 수지가 섬유의 보호재 역할을 하기 때문에, 콘크리트내의 알칼리와 절연되어 열화가능성이 작다고 고려된다. 그러나, 일반적으로 섬유를 둘러싼 수지는 그 두께가 수 {$mu}m$이하로 특히 얇고, 운반이나 보관시에 수지가 물리적 변형 및 자외선에 의한 열화가 일어날 가능성이 높다. 또 알칼리에 의하여 에스테르의 가수분해반응에 따른 폴리머의 부식 등, 수지에 알칼리의 침입을 완전히 막는 것이 불가능하게 여겨진다.

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A New Improvement of Traditional Hanji(Korean Paper) Manufacturing Technology from Paper Mulberries (닥나무류를 이용한 전통한지 제조 기술의 개선에 관한 연구 ( I ))

  • Cho, Nam Seok
    • Journal of Conservation Science
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    • v.4 no.1 s.4
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    • pp.43-52
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    • 1995
  • This study was carried out to investigate the papermaking characteristics for New Hanji (Korean Paper) products from paper mulberries by new pulping processes. So far wood ash extractives or NaOH only have been used for cooking chemicals at the atmospheric condition. Also bast fibers only have been used as raw materials for Hanji, In this study, as the alternatives to the conventional cooking, alkali, alkali-peroxide and sulfomethylated cookings were applied at the pressurized condition for Hanji pulping, Also bast fibers, woody parts and whole woods are attempting for being utilize as new raw materials for special Hanji. Anatomical and chemical properties of 3 paper mulberry species and their pulping characteristics were analyzed.

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Study of Rice Husk Pulping for utilization of Rice Husk Fiber (왕겨섬유 활용을 위한 왕겨 펄프화 연구)

  • Oh, Min-Taek;Sun, Yong-Joo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.63-69
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    • 2012
  • The rice husk is one of the major agricultural residue in KOREA. In this paper, the effects of various pulping conditions on the properties of rice husk pulp and handsheets made of rice husk fiber were evaluated in order to utilize the rice husk as an alternative source for wood pulp. Two typical alkali pulping, such as soda pulping and Kraft pulping were applied with various conditions of the pulping processes. The higher effective alkali and higher pulping temperature resulted in the higher efficiency in removal of lignin and ash, which leaded to the higher strength properties of handsheets made of rice husk fiber, but the lower yield of rice husk pulp. The better efficiency in production of rice husk pulp and the stronger handsheets were obtained by the Kraft pulping.

Strength Behaviour and Hardening Mechanism of Chemical Bonded Fly Ash Mortar (화학적 결합에 의한 Fly ash 경화체의 강도 발현 메카니즘)

  • Jo Byung Wan;Moon Rin Gon;Park Seung Kook;Ko Hee Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.373-376
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    • 2005
  • The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_{2}$ and $Al_{2}O_{3}$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^{-}$ through alkali activators. We used alkali activators for supplying it with additional $OH^{-}$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time.

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A Study on the Preparation of Alumina Powders from Bauxite by Wet Acid Process and Their Utilization (II) : Mullitization of Pyrophyllite-Aluminum Hydrate Gel Mixture (Bauxite로부터 습식산처리법에 의한 알루미나 분체의 제조 및 그 이용에 관한 연구(II) : 납석-Aluminum Hydrate Gel 혼합물의 Mullite화 거동)

  • 이승현;조철구;배원태
    • Journal of the Korean Ceramic Society
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    • v.27 no.8
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    • pp.1011-1019
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    • 1990
  • Pyrophyllite, which has low impurities, was used in the synthesis of mullite to decrease the glass phase, which can be formed from impurities such as alkali and alkali earth elemetns present in raw materials. But, as pyrophyllite has less alumina content than other aluminosilicate materials such as kaolin, more alumina sources were needed in the synthesis of mullite. In other to investigate the effect of particle size of alumina sources on the mullitization of pyrophyllite, aluminum hydrate gel and activated alumina were used. When activated alumina, which has large particle size, was added to pyrophyllite, mullitization was not fully accomplished regardless of temprature. In the case of aluminum hydrate gel, which has small particle size, the maximum yield of mullite was about 90.3% at 1700$^{\circ}C$, and grain size of mullite was larter than the case of activated alumina was added.

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Strength Development and Hardening Mechanism of Alkali Activated Fly Ash Mortar (알카리 활성화에 의한 플라이애쉬 모르타르의 강도 발현 및 경화 메커니즘)

  • Jo, Byung-Wan;Park, Min-Seok;Park, Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.449-458
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    • 2006
  • The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

Melt Properties of Plasma Display Panel Substrate Glasses Based on Float Process (Float 공법을 고려한 Plasma Display Panel용 기판유리 용융체의 특성)

  • Kim, Ki-Dong;Jung, Woo-Man;Jung, Hyun-Su;Kwon, Sung-Ku;Choi, Se-Young
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.433-438
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    • 2006
  • In order to examine the working condition of melts in tin bath of float process it was investigated Sn diffusion behavior and solidification rate of melts for alkali-alkaline earth-silica PDP substrate glasses such as commercial CaO rich CS-77 glass, commercial $Al_2O_3$ rich PD-200 glass and self developed $SiO_2$ rich T-series (T-2, T-4, T-6) glasses. In the case of Sn depth and concentration created in glass surface by ion exchange between Sn and alkali, T-series showed lower value than CS-77, especially T-2 is more excellent than PD-200. The solidification rate of melts expressed by cooling time between $log{\eta}=4\;and\;7.6dPa{\cdot}s$ was low for T-series comparing with CS-77 and PD-200. Therefore, it was concluded that T-series is desirable considering forming condition in the tin bath of the float process.

Near Infrared Shielding Properties of Quaternary Tungsten Bronze Nanoparticle Na0.11Cs0.22WO3

  • Moon, Kyunghwan;Cho, Jin-Ju;Lee, Ye-Bin;Yoo, Pil J.;Bark, Chung Wung;Park, Juhyun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.731-734
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    • 2013
  • Reduced tungsten bronze nanoparticles of ternary and quaternary compounds were prepared by adding sodium and cesium to crystal structures of tungsten trioxides ($Na_xCs_{0.33-x}WO_3$, x = 0, 0.11) while maintaining the overall alkali metal fraction at 0.33, in an attempt to control near infrared (NIR) shielding property in the particular wavelength range of 780 to 1200 nm. The structure and composition analysis of the quaternary compound, $Na_{0.11}Cs_{0.22}WO_3$, revealed that 93.1% of the hexagonal phase was formed, suggesting that both alkali metals were mainly inserted in hexagonal channel. The NIR shielding property for $Na_{0.11}Cs_{0.22}WO_3$ was remarkable, as this material demonstrated efficient transmittance of visible light up to 780 nm and enhancement in NIR shielding because of the blue-shifted absorption maximum in comparison to $Cs_{0.33}WO_3$.

Effect of the thickness of an emitting zone by the thin alkali compound films for highly efficient $Alq_3-based$ OLEDs

  • Kim, Young-Min;Lee, Joo-Won;Park, Jung-Soo;Kim, Jai-Kyeong;Sung, Man-Young;Ju, Byeong-Kwon;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1306-1309
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    • 2005
  • Highly efficient and bright organic light-emitting diodes (OLEDs) have been realized using the thin alkali compound films (TACFs) at the interface between an emitting layer and an electron transporting layer with conventional organic layers. By comparing the performance of the device as a function of position with the TACFs, we propose the optimal position of the TACFs in the tris-(8-hydroxyquinoline) aluminum (Alq3). A device with the ACFs showed high luminance of over 12 500 cd/m2, luminance efficiency of more than 12 cd/A, and power efficiency of more 4.5 lm/W, respectively.

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Synthesis of Photoconductive N-unsaturated Alkylcarbazole Derivatives (광전도성 N-불포화알킬카르바졸 유도체의 합성)

  • Jung, Eun-Sil;Cho, Eul-Hoon;Chung, Pyung-Jin
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.548-553
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    • 1998
  • The N-unsaturated alkylcarbazole derivatives were synthesized by the nucleophilic unimolucular substitution reaction ($S_N1$) of carbazole with unsaturated alkyl chloride. These reactions between carbazole and unsaturated alkyl chloride were conducted in dimethyl sulfoxide (DMSO) containing alkali (NaOH or KOH) at room temperature for 4 hrs under nitrogen atmosphere. The mole ratios of carbazole, alkali and unsaturated alkyl chloride were 1:6:1, respectively. All of the compounds of starting materials and reaction products were characterized by CHN analysis, $^1H$-NMR and FR-IR spectroscopy.

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