• Title/Summary/Keyword: alkali hydroxide

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A Study on Characteristics of Coated Films on Wood Surface by Nitrocellulose Lacquer, Aminoalkyd, Polyester, and Polyurethan (니트로셀룰로오스락카, 아미노알키드, 폴리에스테르 및 폴리우레탄 도료(塗料)의 도막성능(塗膜性能)에 관(關)한 고찰(考察))

  • Lee, Phil-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.1
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    • pp.12-21
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    • 1989
  • This experiment was executed to investigate the characteristics of gloss and color difference in coated films by N.C. Lacquer, Aminoalkyd, Polyester. and Polyurethan coating after chemical (distilled water, ethyl alcohol. acetic acid, and sodium hydroxide) and heating ($120^{\circ}C$) treatments, cold-check test, and U.V. radiation. The results obtained were summarized as follows 1. The gloss decreasing rate by water resistance test was the least among chemicals treated on coated films. 2. The color difference of coated films chemical treatments highly and similarly increased, except the alkali treatment showing a little increase. 3. In the color difference by U.V. radiation, the polyester coated film showed generally large difference compared with the other coated films.

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Development of NaOH Concentration Control System for a Liquor-Flow Polyester Hydrolysis Machine (액류감량기 가성소다 농도 제어 시스템의 개발)

  • 박정우;변희운;노근필;구자길;황백순;김덕리
    • Textile Coloration and Finishing
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    • v.12 no.4
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    • pp.233-238
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    • 2000
  • In this study, the control system of sodium hydroxide was demonstrated to systemize hydrolysis process in polyester dyeing. We mainly focused on the application method of acid-alkali titration for the polyester hydrolysis machine of liquor-flow type. Industrial pH meter with electrode type was used for identifying equivalence point. Three units which were analogue-to-digital card, microprocessor and digital output card were used to control NaOH concentration in the control part of the system. The yielded data are translated to the microprocessor through analogue-digital interfacing card. After calculating, NaOH concentration in NaOH storage tank was controlled through the digital output card and solenoid valves.

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Kmulsi5ed Transesterification of Soybean Oil into Biodicsal (유화전이에스테르화에 의한 대두유의 Biodiesel화)

  • Kang, Young-Min;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.298-305
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    • 2001
  • Emulsified transesterification of soybean oil into biodiesel was investigated using potassium hydroxide and sodium methoxide catalysts with methyl glucoside oleic polyester as a methanol-in-oil emulsifier. The transesterification reaction conditions were optimized to obtain high yields of fatty acid methyl esters of the quality defined by biodiesel standards. The developed process resulted in $95{\sim}96%$ of overall yield from soybean oil by alkali-catalyzed methanolysis at $45^{\circ}C$ of reaction temperature with 6:1 of methanol-to-oil molar ratio and 1(v/v)% methyl glucoside oleic polyester in the presense of 0.8wt% KOH and 1.2wt% $NaOCH_{3}$.

Studies on the Combustion of Anthracite (II). The Combustion of Sulfide in Anthracite (無燃炭 燃燒에 關한 硏究 (第 2 報). 無煙炭中의 黃化物의 燃燒)

  • Shin Byoung Sik;Shin Sei Kun
    • Journal of the Korean Chemical Society
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    • v.19 no.3
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    • pp.193-197
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    • 1975
  • In the combustion process, it is found that the addition of small amount of hydroxide of alkali and alkaline earth metal to the anthracite is more effective in order to suppress the evolution of $SO_2 gas, since the large portion of sulfur contained in anthracite is remained in the ash with a form of sulfide and sulfate. Under this experimental condition, however, it was observed that the SO_2$ gas corresponding to about 20 % of sulfur content in anthracite was released at $1000^{\circ}C$.

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A Case Report of Liquid-Lye (NaOH) Ingestion Complicated with Gastroesophageal Perforation (양잿물 음독 후 생긴 위${\cdot}$식도 천공으로 사망한 환자 1례)

  • Yang, Hee-Bum;Yang, Young-Mo;Hong, Sung-Youp
    • Journal of The Korean Society of Clinical Toxicology
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    • v.3 no.2
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    • pp.99-102
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    • 2005
  • The caustic drugs are classified into acid and alkali. Oral intake of these drugs cause histological injuries to the surfaces of oral cavity, laryngopharynx, and esophagus. Caustic drugs such as detergents and brilliants are easily contacted at homes. However, until now, the epidemiology and the clinical statistics of caustic drug ingestion in Korea were not carried out. This is a case report of sodium hydroxide - lye, a caustic drug more toxic than the others - ingestion with complication of gastroesophageal perforation, rapidly progressed mediastinitis and prompt death in the course of treatment.

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Effect of Early Compressive Strength Development with Blast Furnace Slag Using Various stimulants Mortar. (각종자극제가 고로슬래그 미분말 혼입 모르타르의 초기재령 압축강도 발현에 미치는 영향)

  • kim, Jin-Hyoung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.57-58
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    • 2011
  • In the experiment, we add to NaOH, Ca(OH)2 and Calcium Hydroxide as the Slag stimulus also mixed the cement stimulus such as NaSCN, TEA and CaCl2 for improving compressive strenth of concrete which added the Blast Furnace Slag Powder at 1 and 3 days. In the result of strength test, It showed that 2percentage of activator 1 and 5percentage Ca(OH)2, 1percentage of activator 3 and 5percentage of Ca(OH)2 are higher than 100 percentage OPC.

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Preparation and Evaluation of Chitin Derivatives and Their Utilization for Waste-water Treatement

  • Aly, Aly Sayed;Jeon, Byeong-Dae;Kim, Young-Jun;Park, Yun-Heum
    • Proceedings of the Korean Fiber Society Conference
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    • 1996.10a
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    • pp.53-58
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    • 1996
  • The Chitin Thiocarbonate-Fe(II)-H2O2 redox initiator system was investigated for the graft copolymerization of acrylonitrile(AN) and acrylic acid(AA) monomers onto chitin powder. The reactions with vinyl monomers onto chitin were carried out under various the graft copolymerization conditions to elucidate the polymerization behavior in terms of graft yield. Reactions of chitin-acrylonitrile graft copolymer with hydroxyl amine hydrochloride and those with sodium hydroxide were conducted in order to obtain chitin-(amidoxime-co-acrylonitrile) and chitin-(acrylate-co-acrylamide) graft copolymers, respectively. The reaction efficiency was observed to depend on the alkali concentration, time, temperature, and the reactant concentrations. The prepared chitin derivatives were evaluated to find potential applications for use in wastewater treatments for adsorption and desorption of heavy metal ions as well as acidic and basic dyes.

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A Study of Cleaning Technology for Zirconium Scrap Recycling in the Nuclear Industry (원자력산업에서 지르코늄 스크랩 재활용을 위한 세정기술에 관한 연구)

  • Lee, Ji-Eun;Cho, Nam-Chan;An, Chang-Mo;Noh, Jae-Soo;Moon, Jong-Han
    • Clean Technology
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    • v.19 no.3
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    • pp.264-271
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    • 2013
  • In this study, we optimized the removal condition of contaminants attached on the scrap surface to recycle the scrap generated from the Zr alloy tube manufacturing process back to the nuclear grade. The main contaminant is remnant of watersoluble cooling lubricant that is used in the pilgering manufacture during the tube production, and it is assumed to be compressed and carbonized on the surface of tube. Zirlo alloy tube of ${\phi}9.50mm$, which has high occurrence frequency of scrap, was selected as the object to be cleaned, and cleaning abilities of reagents were evaluated by measuring the characteristics of contaminants remained and by analyzing the surface of the tube after cleaning process. For evaluation of each cleaning agent, we selected two types of sodium hydroxide series and three types of potassium hydroxide series. Furthermore, to confirm dependence on tempe-rature and ultrasonic intensities, cleaning at the room temperature, $40^{\circ}C$, and $60^{\circ}C$ was conducted, and results showed that higher the cleaning temperature and higher the ultrasonic intensity, better the cleaning effect. As a result of the bare-eye inspection, while the use of sodium hydroxide provided satisfactory condition on the tube surface, the use of potassium hydroxide series provided satisfactory condition on the tube surface only when the ultrasonic intensity was over 120 W. In the cleaning effect analysis using the gravimetric method, cleaning efficiency of sodium hydroxide series was as high as 97.6% ($60^{\circ}C$, 120 W), but since the tube surface condition was poor after the use of potassium hydroxide, the gravimetric method was not appropriate. In the analytical result of surface contaminants on the tube surface, C, O, Ca, and Zr were detected, and mainly C and O dominated the proportion of contaminants. It was also found that the degree of cleaning on the tube affected the componential ratio of C and O; if the degree of cleaning is high, or if cleaning is well-conducted, the proportion of C is decreased, and the proportion of O is increased. Based on these results, optimal cleaning for application in the industry can be expected by categorizing cleaning process into three steps of Alkali cleaning, Rinsing, and Drying and by adjusting cleaning parameters in each step.

Effect of Feeding Chemically Treated Mustard (Brassica campestris) Straw on Rumen Fibre Degrading Enzymes in Sheep

  • Vaithiyanathan, S.;Raghuvanshi, S.K.S.;Mishra, A.S.;Tripathi, M.K.;Misra, A.K.;Prasad, R.;Jakhmola, R.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.11
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    • pp.1610-1613
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    • 2003
  • The aim of the experiment was to study the changes in the activities of various rumen fibre degrading enzymes due to the feeding of chemically treated mustard (Brassica campestris) straw in sheep. Mustard straw (MS) (<5 cm particle size) was treated either with urea (4% (w/w), or with 2% sodium hydroxide (NaOH), or with alkaline hydrogen peroxide (2% NaOH and 1.5% hydrogen peroxide ($H_2O_2$)) and/or supplemented with 2% (w/w) urea. Seven maintenance type rations were prepared using MS (70 parts) with molasses (5 parts) and concentrate (25 parts). They were untreated MS (CMS), urea treated MS (UMS), urea supplemented MS (MSUS), alkali treated MS (AMS), alkali treated and urea supplemented MS (AMS-US), alkali $H_2O_2$ treated MS (AHMS) and alkali $H_2O_2$ treated and urea supplemented MS (AHMS-US). They were then compressed into a complete feed block with the help of block making machine. Forty two male hoggets of Malpura breed sheep were equally distributed into each treatment group and (were) offered feed and water ad libitum. At the end of 21 days of feeding trial, rumen liquor was collected through stomach tube from three animals in each group at 0 h, 4 h, 8 h, 12 h of post feeding. Results showed that the level of enzyme varied from 8.52 to 11.12, 40.85 to 50.37, 3.22 to 3.78, 2.09 to 2.77 and 31.44 to 44.24 units/100 ml SRL respectively for carboxymethyl cellulase (CMCase), $\alpha$-amylase, microcrystalline cellulase (MCCase), filter paper (FP) degrading enzyme and $\alpha$-glucosidase. Processing of MS affected the enzyme activities, in a way, that NaOH and AHP treatment significantly reduced CMCase and FP degrading enzyme. The effect of urea treatment showed an increase in the activity of MCCase and $\alpha$-glucosidase. But the supplementation of urea increased the activity of CMCase, FP degrading enzyme and $\alpha$-glucosidase. The CMCase, $\alpha$-amylase, $\alpha$-glucosidase activities were highest at 4hr whereas MCCase and FP degrading enzyme had maximum activities at 12 h post feeding Results suggested that MS might need longer time in the rumen for its effective degradation.

A Study on Early Age Properties of Alkali Activated Slag Mortar According to Water/Binder Ratio (물-결합재비에 따른 알칼리 활성 슬래그 모르타르의 초기 재령 특성에 관한 연구)

  • Oh, Sang-Hyuk;Kim, Dae-Wang;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.63-69
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    • 2012
  • Recently, the cement industries brought very severe environment problems such as resource depletion and global warming with massive carbon dioxide during its production. The number of cases using industrial by-products such as the ground granulated blast furnace slag (GGBFS) in concrete mixtures is increasing to resolve the environmental issue. GGBFS is mainly used in the range between 20 to 50% to replace cement, but nowadays lots of researches are carried out to develop the alkali-activated slag (AAS) concrete with no cement. In this study, the early age properties of alkali activated slag (AAS) mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The experimental variables were the water-binder ratios of 0.3, 0.4, and 0.5 and NaOH as the alkali activator of 4%, 8%, and 12% by the mass of GGBFS, and compressive strength, flow, setting time, and ultrasonic pulse velocity of AAS mortars were measured and analyzed. It is found from the test results that as the normal concrete the lower W/B, the higher compressive strength. However, superplasticizer has to be used for producing high strength AAS concrete because the workability of AAS mortar are significantly lowered.

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