• Title/Summary/Keyword: alkali content

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Effect of Sodium Hydroxide plus Hydrogen Peroxide Treated Mustard (Brassica campestris) Straw Based Diets on Rumen Degradation Kinetics (In sacco), Fermentation Pattern and Nutrient Utilization in Sheep

  • Mishra, A.S.;Misra, A.K.;Tripathi, M.K.;Santra, A.;Prasad, R.;Jakhmola, R.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.3
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    • pp.355-365
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    • 2004
  • Two experiments were conducted to determine the effect of alkaline hydrogen peroxide (AHP) treatment (1% NaOH+1.5% $H_2O_2$; 1 AHPMS, 2% NaOH+1.5% $H_2O_2$; 2AHPMS) on rate and extent of degradation of mustard straw (MS) in sacco in sheep, and its in vivo digestion and ruminal fermentation characteristics when fed to sheep with concentrate (200 g per sheep daily). The treatment of straw with 1 and 2% AHP increased its sodium content by 148 and 296% to that of untreated straw (UMS). There was significant decrease in NDF and hemicellulose contents of AHP treated straw and increase in cellulose and lignin contents. Phenolic acids like ferrulic, $\rho$-coumaric and o-coumaric significantly (p<0.001) reduced by AHP treatment of mustard straw. In first experiment the in sacco degradation of DM, OM and NDF was significantly (p<0.01) greater for 2 AHPMS than for UMS at all incubation periods. The disappearance of nutrient from 1 AHPMS and 2 AHPMS treated straws continue to increase up to 96 h whereas in UMS the peak disappearance was found at 48 h. By using the equation {(y=a+b) ($1-e^{-ct}$)} the degradation rates (c) for DM, OM, and NDF were significantly higher for UMS than AHP treated straws. Level of alkali (1 and 2%) had significant effect on degradation characteristics (a, b, c and $P_{0.05}$) of DM and NDF fraction of MS. However, the effect was not pronounced on OM fraction of MS. In feeding experiment, the intake of nutrients for DM, OM, cell wall constituents and energy was higher on 2 AHPMS, whereas no effect on the digestibility of these nutrients was observed. The apparent nitrogen retention was higher (p<0.05) both in 1 and 2 AHPMS groups. Water intake by animals was significantly increased due to AHP treated mustard straw feeding. Rumen liquor pH was higher in 2 AHPMS fed animals. The $NH_3-N$ of rumen liquor was not affected by feeding of AHP treated MS based diets. Total VFA concentration was significantly (p<0.01) higher in UMS fed group. The fractional out flow rate of DM was higher (p<0.05) in animals fed on 2 AHPMS diets compared to UMS and lAHPMS fed groups. The population of large holotrichs was higher (p<0.05) on AHP treated MS fed diets compared to UMS. The study indicated that treatment of mustard straw with AHP changed its chemical composition towards a better feed. The nutritive value of 2% AHP treated mustard straw was better in terms of dry matter intake and apparent nitrogen retention. The higher in sacco DM, OM and NDF disappearance however, was not confirmed by in vivo data in this study.

Studies on the Ripening Characteristics, Germination Speed and Quality among Different Floret of Japonica and Tongil Type of Rice under Different Growing Season (수도재배시기별 Japonica 및 Tongil형 품종의 영화간 등숙특성 발아세 및 미질연구)

  • 권규칠;박성규
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.3
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    • pp.310-323
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    • 1989
  • This study was carried out to find out the difference of ripening and growth characteristics among the different florets in same panicle. There were 2 different transplanting date (May 25 and June 10) and 6 varieties were used. Physiological ripening period, ripening speed, 1000 grain weight, germination speed and grain quality were studied among the different florets (1, 5 and 8 days after heading) in same panicle. Physiological ripening period was long in late transplanting, late flowering floret, and late varieties by 3-9 days in Japonica. Ripening speed and 1000 grain weight were high in early transplanting and early flowering florets. There was positive correlation among the ripening speed, 1000 grain weight and a average temperature but negative correlation between the ripening and physiological ripening period. Germination speed was excellent in early flowering floret after heading. There was difference in amylose content within varieties and different flowering grains and there was significant correlation between grain quality and meteorological factors in some varieties.

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An Influence of Additional Metals over Ni/SiO2 or Ni/Al2O3 on the Formation of CFC-1113 from CFC-113 (CFC-113로부터 CFC-1113의 합성시 Ni/SiO2(또는 Al2O3) 촉매상에서 다른 금속의 첨가효과)

  • Kim, JinHo;Park, Kun-You;Ha, Baik-Hyon
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.237-241
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    • 1999
  • Nickel was impregnated on the $SiO_2$ and $Al_2O_3$ supports and applied to the reduction reaction of CFC-113 ($CF_2Cl$-$CFCl_2$) with hydrogen to 3FCl ($CF_2$=CFCl, CFC-1113). The conversion was rapidly declined on the Ni/$SiO_2$(or $Al_2O_3$) and the deactivation accelerated as the increase of Ni content. However, the selectivity of 3FCl was maintained at around 80% level. The simultaneous coprecipitation of copper and lithium on Ni/$Al_2O_3$ improved both the conversion and selectivity to 3FCl, but an excessive amount of lithium reduced the conversion as well as the selectivity of 3FCl. However, in the case of Ni/$SiO_2$, the conversion was greatly reduced possibly due to a loss of silica support with high surface area by the reaction of $SiO_2$ with HF. Such a reduction in conversion also can be ascribed to the decrease in active sites, caused by the addition of alkali metal compound, LiOH.

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The effects of some additives on Methane Fermentation of Paper Mill Sludge treated with Alkali (알칼리 처리된 제지슬러지의 메탄발효에 미치는 몇몇 첨가제의 효과)

  • Choi, Jong-Woo;Lee, Kyu-Seung;Park, Seung-Heui
    • Korean Journal of Agricultural Science
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    • v.22 no.2
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    • pp.134-142
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    • 1995
  • In order to elevate the efficiency of methane fermentation using the paper mill sludge, this experiment was conducted at two temperature conditions($35^{\circ}C$ and $60^{\circ}C$), and overlooked the addition effects of ethyl acetate as a substrate, nickel as a constituent of $F_430$, and sulfur as a cell growth factor and reductant. The cellulose of paper mill sludge was degraded to lower molecular materials by heating at $60^{\circ}C$ and NaOH treatment. Methane forming rates were 4.8% from NaOH-treated paper mill sludge added with ethyl acetate, 16.5% with sodium sulfide, 19.8% with nickel trioxide, 31.9% with mixture, and 9.6% with control at $60^{\circ}C$, but 0.21% with ethyl acetate, 2.14% with nickel acetate, 3.02% with nickel sulfate, 3.34% with nickel trioxide and 0.62% with control at $35^{\circ}C$. Therefore, methane yield was increased by approximately 10-fold at $60^{\circ}C$ than $35^{\circ}C$, and fermentation liquid added with mixture(nickel trioxide+ethyl acetate+sodium sulfide) at $60^{\circ}C$ showed the medium pH(7.0), higher COD value and lower nitrogen content.

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Characteristics of the Small Scale Leucocratic Granites in the Eastern Parts of the Taebaegsan Region, Korea (태백산 지역 동부에 분포하는 소규모 우백질 화강암체의 특징)

  • Yoo, Jang-Han;Ryoo, Chung-Ryul
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.375-383
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    • 2014
  • Precambrian granitic gneisses and Cambrian meta-sedimentary rocks are prevalently distributed in the eastern part of the Taebaegsan region, and biotite granitic batholith of the Jurassic period (?) is found in the southern part of Uljin-si. But small scale leucocratic granitic stocks which commonly found here and there have been rather neglected in the previous studies. The presence of leucocratic granites could be differentiated from the older granitic rocks and biotite granite through the outcrop characteristics, mineral species and geochemical compositions. For the effective comparison between the older granitic rocks and leucocratic ones, pale gray to gray coloured Hongjesa granitic gneiss with granular texture was selectively chosen. The Hongjesa granitic gneiss and biotite granite usually have rather plenty of coloured minerals such as biotite and chlorites. But the leucocratic granites often show sericitic alteration due to the albitization and greisenisation during the post-magmatic alteration, and shows rather bright appearance because of poor amount of coloured minerals. Since all of granitic rocks passed rather high degrees of magmatic differentiation, they belong to calc-alkalic and peraluminous in their characters. Among the alkali elements of the leucocratic rocks $K_2O$ shows higher increase than those of the other granitic rocks, and $Na_2O$ only represents slight decrease than those of the Hongjesa granitic gneiss and Uljin granite. On the other hand, CaO and total Fe content are clearly decreased than those of the Hongjesa granitic gneiss and Uljin granite.

Changes in Antioxidative Activity and Total Polyphenols of Crude and Defatted Grape Seed Extract by Extraction Condition and Storage (포도종자의 처리별 추출조건 및 저장에 따른 항산화활성 및 총페놀함량의 변화)

  • Kim Young-Kuk;Lee Hyeon-Yong;Oh Deog-Hwan
    • Food Science and Preservation
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    • v.11 no.4
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    • pp.455-460
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    • 2004
  • This study was conducted to determine the yield, free radical scavengering effect and total phenol contents of various solvent fractions on the crude and defatted grape seed extract during storage. The optimal condition for the extraction yield, free radical scavengering effect and total phenol contents was $90\%$ ethanol for 6 hour at $70^{\circ}C$. The extraction yield for crude and defatted grape seed at optimal condition was $8.9\%\;and\;9.16\%$, respectively. Also, the strongest free radical scavengering effect with $41.52\;{\mu}g/mL$ was observed in $95\%$ ethanol of defatted grape seed extracted for 6 hour at $70^{\circ}C$. Similar result was observed in total phenol contents of defatted grape seed. The ethyl acetate fraction obtained from ethanol extract of defatted grape seed showed the strongest RC50($12.35\;{\mu}g/mL$) compared to other organic fractions. Free radical scavengering effect of crude and defatted grape seed extracts treated with alkali condition(pH 10) was reduced compared to that of acidic condition(pH 2) during storage far 1 month at $50^{\circ}C$. Overall, more stronger free radical scavengering effect and higher total phenol contents in defatted grape seed extracts was observed than that of crude grape seed.

Weathering and Deterioration Diagnosis for Conservation Sciences of Stone Pagoda in the Bunhwangsa Temple,Gyeongju, Korea (경주 분황사 모전석탁의 암석학적 풍화와 보존과학적 훼손도 진단)

  • Yi, Jeong-Eun;Lee, Chan-Hee;Lee, Myeong-Seong;Kim, Young-Taek
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.92-100
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    • 2004
  • The host rocks of brick-shaped stone pagoda in the Bunhwangsa temple are lots of kinds andesitic rocks, which has gone through mechanical and chemical weathering. As the overall observation, the pagoda is serious damages by air pollutants, and the northeast parts show the much advanced state of turning white, while the southeast parts are heavily cracked in the materials. The rocks of brick-shaped pagoda body are in a relatively stable condition of weathering and damage except for the abrasion and cracks of the corners. The rocks of the pagoda roof suffer from more symptoms including multiple peel-offs, exfoliation, cracks forming round lines, and falling off stone pieces. The pagoda roof rocks are dominated by the thriving leafy lichens and mosses, especially, there are higher plants (selaginella involvens, dandelions) taking root actively between the brick stones and content mortar. There are even light gray precipitates like stalactites between the rocks of the body, In particular, the 1st and 2nd floor in the east side and the body parts in the north side are the most serious. Their major minerals are calcite, gypsum and clay minerals. The rocks of the stylobate and the tabernacle in all the four directions are composed mainly of granitic rocks. The materials consisting of the tabernacles show the severe splits and distortion, which causes the structural instability. The stylobate rocks are heavily contaminated by some weeds with the often marks of inorganic contamination by secondary hydroxides. The central part of the east stylobate has been sinking, while that of the 1st floor west stylobate is protruded nesting a line of cracks. Accordingly, the inside of the tabernacle is always humid with the constant introduction of rainwater. The stone lion standing in the southeast and northeast side are alkali granite, while that in the southwest and northwest lithic tuff. Each of the stone lion also coated with various colored lichens, mosses, algae, bacteria and bryophyte. The external materials of the pagoda have deteriorated the functions of the rocks and made the loss, falling off, and biological contamination even worse due to the surface weathering. Thus it's urgent to come up with scientific restoration and conservation measures through clinical tests.

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Studies on the suitable temperature for rice drying (미곡의 건조 적정 온도에 관한 연구)

  • Lee, B.Y.;Son, J.R.;Kim, Y.B.;Yoon, I.H.
    • Applied Biological Chemistry
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    • v.34 no.3
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    • pp.258-261
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    • 1991
  • In order to establish the optimum drying temperature of the heated air blast-grain circulation dryer, a 2 ton scale of paddy was used in this experiment. The temperatures of heated air used were 45, 50, 55, 60, 65 and $70^{\circ}C$. Moisture content of the paddy was reduced to 15% from 24% by drying. The higher air temperature, the shorter drying time and the less fuel consumed. The portion of cracked kernels was found to be low as $3{\sim}10%\;at\;40{\sim}55^{\circ}C$, but was very high to $28{\sim}30%\;at\;60{\sim}70^{\circ}C$. The germination percent was very high as 98 and 93% at 40 and $45^{\circ}C$, but it was decreased to 86 and 30% at 50 and $70^{\circ}C$, respectively. The recovery yield of milled rice from paddy was decreased by 1.76, 2.63 and 7.52% at 60, 65 and $70^{\circ}C$, respectively, compared with 75.86% as drying at $40^{\circ}C$. The higher heated air temperature, the less head rice of milled rice was recovered, and the decreased ratio was increased $60^{\circ}C$. The higher heated air temperature, the less alkali disintergation value and gel consistency of milled rice and the more water up take, expanded vlume, total solid in residual liquid and intensity of starch iodine blue value of residual liquid, and those tendency was found clear from $60^{\circ}C$ temperature of heated air.

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A Study on the Field Application of Ground Stabilizer using Circulating Resource for Improvement of Soft Ground in Saemangeum Area (새만금 지역의 연약지반 개량을 위한 순환자원 활용 지반안정재의 현장적용에 관한 연구)

  • Seo, Se-Gwan;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.103-110
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    • 2020
  • The DMM (Deep mixing method) is a construction method in which an improved pile is installed in the soft ground by excavation ground using an auger and then mixing ground stabilizer with soil. Improved pile installed in the soft ground by the DMM may have different compressive strength depending on the properties and characteristics of the soil. In the previous study, laboratory tests were performed on the ground stabilizer for the DMM developed by using the ash of the circulating fluidized bed boiler as a stimulator for alkali activation of the blast furnace slag. And the test results were analyzed to derive the correlation between the unit weight of binder (γB) and the uniaxial compressive strength (qu). In this study, comparative reviews were conducted on the correlations derived from the same laboratory tests on soil material collected from the Saemangeum area and the stability of the site was evaluated by analyzing the test results performed at the site. As a result, the clay collected from the Saemangeum area satisfies the correlation between the unit weight of binder (γB) and the uniaxial compressive strength (qu) derived from the previous study. And the result of the test at the field showed a higher uniaxial compressive strength than the standard strength at the field, indicating excellent stability.

Synthesis of Mesoporous Silica Using Municipal Solid Waste Incinerator Ash Slag : Influence of NaOH Concentration (생활(生活) 폐기물(廢棄物) 소각재(燒却材) 슬래그를 이용(利用)한 메조포러스 실리카 합성(合成) : NaOH 농도(濃度)의 영향(影響))

  • Han, Yo-Sep;Jung, Jong-Hoon;Park, Jai-Koo
    • Resources Recycling
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    • v.19 no.1
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    • pp.40-48
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    • 2010
  • It was investigated that effects of NaOH concentration on synthesis of mesoporous materials using municipal solid waste incinerator ash slag (MSWI-ash slag). In order to increase the purity and maximize the amount of extracted Si content the raw MSWI-ash slag was mechanically activated. Extraction of Si from the MSWI-ash slag was carried out by alkali treatment using concentrated NaOH solution, which varied from 1M to 4M. Physical properties (i.e., pore size, specific surface area and total pore volume) of the synthesized mesoporous silica were also evaluated as a function of NaOH concentration via BET, SEM, TEM and small-angle X-ray scattering analyses. Over the entire range of NaOH concentration investigated (i.e., 1-4M), the synthesized mesoporous materials were determined to be SBA-15, which exhibited a hexagonal structure with the pore size of approximately 7 nm. On the other hand, specific surface area and total pore volume increased with NaOH concentration up to 3M while the values decreased at 4M, indicating that the optimal NaOH concentration for the synthesized mesoporous silica was approximately 3M. Further comparison analysis between two conditions (3M versus 4M) showed that the decrease in two physical properties at 4M NaOH concentration was likely due to the potential inhibition by excess Na ions on the formation of mesophase and the consequent increase of pore wall thickness by remaining Si ions.