• Title/Summary/Keyword: alkali absorption

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Dyeing Properties of CDP Fiber(III) - Dyeing and Solvent Wicking and Physical Properties of Micro CDP Fiber - (CDP 섬유의 염색성(III) -극세 CDP섬유의 염색성, Solvent wicking성 및 물성-)

  • Kim, Young-Hee;Jeong, Dong-Seok;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.17 no.5 s.84
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    • pp.1-12
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    • 2005
  • Polyester fibers can be modified into cationic dyeable polyester fibers(CDP) by the copolymerization of terephthalic acid and 5-sodium sulphoisophthalic acid with ethylene glycol. The advantage of CDP on most cationic dyes is the conspicuous brilliance due to a narrow steep absorption band and the wash fastness and etc. Weight reduction by alkali hydrolysis, dyeing and solvent wicking properties of fabrics with cationic dyes, and change of fine structure were investigated. To obtain optimum splitting process parameters for dyeing and physical properties of micro CDP fiber, splitting method under various conditions was carried out. By means of SEM, it was confirmed that the splitting process of the micro CDP fiber be achieved at the weight reduction. A comparatively greater quantity of dye is necessary to dye microfiber than conventional fiber. The fastness and solvent wicking of regular CDP fiber is higher than that of micro CDP fiber.

Adsorption of lead ion by using biomass of Aspergillus niger (Aspergillus niger의 생물 흡착제를 이용한 납이온의 흡착)

  • 김병하;김장억;문성훈;김희식;오희목;윤병대;권기석
    • Journal of Korea Soil Environment Society
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    • v.1 no.2
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    • pp.43-50
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    • 1996
  • The adsorption charateristics of lead(II) ions on Aspergillus niger and Rhizopus arrhizus were investigated. Adsorption amount of A. niger and R. arrhizus was about 95 mg/g and 25 mg/g, respectively. These biomass was approached to adsorption equilibrium within reaction time of 1hr because of their high reactivity. The uptake of lead ion by A. niger was less sensitivity than it by R. arrhizus on the inhibition effect of alkali metals and the decreasing ratio of uptake of lead ion of A. niger and R. arrhizus by inhibition effect of alkali metals was 37% and 50%, respectively. In pre-treatment on these biomass, NaOH treatment was contributed high adsorption capacity to these biomass. Then, adsorption amount of A. niger and R. allhizus was increased about 25 mg/g and 10 mg/g, respectively. In isotherm for the adsorption of lead ion based on Freundlich equation, 1/n value of A. niger and R. ar고izus was calculated the range of 0.28-0.56 and 0.44-0.67, respectively.

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The Effects of the Cutting Length of Paper Mulberry Bast Fiber on Pulping and Hanji Properties(I) - White bast of Korea grown paper mulberry - (닥나무 인피섬유의 절단장이 펄프화 및 한지의 물성에 미치는 영향(제1보) - 국산 닥 백피의 특성 -)

  • Lim, Gang-Hyouk;Choi, Tae-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.57-64
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    • 2008
  • In general, the entire of paper mulberry bark, which is not cut into pieces with an appropriate length, have been used in the pulping. This kind of pulping method couldn't accomplish the improvement of beating and sheet forming efficiency. For this reason, we investigated the effects of the cutting length of paper mulberry bast fiber on pulping and Hanji (Korean traditional paper) properties, in order to develop high quality Hanji manufacturing process. The cutting length variation of paper mulberry white bast did not great effects on pulp yields. The pulp yields based on pulping methods were sulfomethylated pulping av. 57.4%, alkali-hydrogen peroxide pulping av. 55.4%, and alkaline pulping av. 53.5% respectively. The optical properties such as brightness, opacity, scattering coefficient, and absorption coefficient were slightly improved by the increase of paper mulberry white bast cutting length. The increase of paper mulberry white bast cutting length resulted in poor sheet formation. Physical properties such as breaking length, TEA, tear index, burst index, and folding endurance were slightly improved by the increase of cutting length. The modified pulping processes, which used sulfomethylated method and alkali-hydrogen peroxide method, showed better pulp and sheet properties than conventional alkaline pulping.

Surface Reflectance Reduction of Multicrystalline Silicon Wafers for Solar Cells by Acid Texturing (Acid Texturing에 의한 태양전지용 다결정 실리콘 기판의 표면 반사율 감소)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Soo-Hong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.99-103
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    • 2008
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controlling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400 nm to 1000 nm) reflectance with acid texturing is 4.64 % less than alkali texturing.

Preparation of Red Perylene Fluoroionophore Containing Calix[4]azacrown Ether and Their Ionophoric Properties

  • Jeon, Young-Min;Lim, Tae-Ho;Kim, Jong-Gyu;Kim, Jong-Seung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.5
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    • pp.816-820
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    • 2007
  • Novel new red-light emitting perylene fluoroionophore N,N'-dipropyl-1,7-bis(calix[4]azacrown-5-crown-5)- 3,4,9,10-perylene tetracarboxy diimide (3) was prepared by reacting N,N'-dipropyl-1,7-dibromo-3,4,9,10- perylene tetracarboxy diimide (1) with calix[4]azacrown-5-crown-5. Also the alternating copolymer (4) with similar repeating unit was prepared reacting by calix[4]bisazacrown-5 with 1. Metal ion binding by 3 and 4 leads to a blue-shift of absorption band and emission spectra. When ionophoric characteristics were investigated by binding alkali, alkali earth metal and various metal ions, polymeric ionophores displayed large fluorescence decreasing effects with K+, Ag+ and Ba2+, which was rationalized by photo-induced charge transfer (PCT).

Effect of Alkali Salts Adding on the Cooking Quality in Dried Noodles (면류용 알칼리제 처리가 건면의 조리특성에 미치는 영향)

  • 문태용;이성갑
    • Journal of the Korean Professional Engineers Association
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    • v.33 no.3
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    • pp.71-79
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    • 2000
  • The effects of alkali salts adding on the cooking quality improving in dried noodles were investigated in the good texture maintaining for preventing solid soluble losses ,through chemical analysis and actual manufacturing practice ,the following results were obtained. Experiments were took a special flour of ASW:DNS=70:30, thickening agent(TA) composed of K2CO3 58%, Na2CO3 36% and Na4P2076%, and emulsified oil(EO) mixing of corn oil 44%, polysorbate 23%, emulsifier(ester of glycerin and fatty acids) 21%, soy lecithin 12%. When the mixing ratio of TA and EO to flour, is 0.03 and 1.5%(w/w) or morel than, satisfied the good quality. The water soluble solid matters content of the lowest 3.2% in the treating group that TA and EO is 0.03 and 1.5%(w/w) respectively, comparing to the 7.3% in the control group provides a excellent cooking quality. The research achieves the similar effects at specific gravity, water absorption ratio, weight increasing rate and volume expansion ratio. According to appearance test the more treating of TA turn the noodle into deeper yellow-green color. Turning to the deeper yellow color according to the increasing of EO provides better

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Investigation of Surface Reflectance Reduction for Multicrystalline Silicon Solar Cells with Acid Texturing (Acid Texturing에 의한 다결정 실리콘 태양전지의 표면 반사율 감소에 대한 연구)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Eun-Joo;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.16-17
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    • 2007
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400nm to 1000nm) reflectance with acid texturing is 4.64% less than alkali texturing.

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Studies on the Improvement of Milling, Quality and Storage of Tongil (Indica Type) Rice -Part II. Properties of Tongil Rice Starch- (통일벼의 도정과 품질 및 저장개선 방안에 관한 연구 -제2보 통일쌀 녹말의 특성-)

  • Chung, Dong-Hyo;Lee, Hyun-Yoo
    • Korean Journal of Food Science and Technology
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    • v.8 no.3
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    • pp.179-184
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    • 1976
  • Properties of starch from three rice varieties in Korea, Indica types Tongil, Yusin and a Japonica type Jinheung were investigated. 1) Gelatinization temperatures of Tongil, Yushin and Jinheung rice were $72^{\circ}C,\;70^{\circ}C\;and\;68{\sim}69^{\circ}C$ respectively. Gelatinization temperature of Indica variety was higher than that of Japonica variety. 2) Blue values of Tongil, Yusin and Jinheung rice starch were 0.40, 0.39 and 0.35 respectively, in which differences among rice varieties were small. 3) Color intensity of three varieties of rice starch with iodine gave rise to absorption maxima at $610{\sim}625\;nm$. 4) Amylose contents of Tongil, Yusin and Jinheung rice starch were 23.2%, 21.3% and 20.6% respectively, which were lower than those of other cereals. Amylose content of Indica variety was higher than that of Japonica variety. 5) Alkali numbers of Tongil, Yusin and Jinheung rice starchs were 7.0, 7.0 and 6.8, respectively. The differences were negligible among rice varieties. Those values were higher than that of glutinous rice starch.

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Status and Prospect of Test Methods of Quality Silicone Water Repellent for Protecting Reinforced Concrete

  • Sun, H.Y.;Yuan, Z.Y.;Yang, Z.;Shan, G.L.;Shen, M.X.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.141-150
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    • 2017
  • Impregnating with quality silicone water repellent on the concrete surface is an effective method of protecting concrete. Quality silicone water repellent has been widely used in the engineering profession because of its desirable properties such as hydrophobicity, keeping concrete breathable and preserving the original appearance of the concrete. The companies in China that produce silicone water repellent are listed. Test methods in the specifications or standards about silicone water repellent in China are summed. The test methods relative to durability of concrete impregnated with silicone water repellent (such as resistant to chloride ion penetration, resistant to alkali, resistance to freezing and thawing and weatherability etc.) and the constructive quality (such as water absorption rate, impregnating depth and the dry velocity coefficient etc.) are compared and analyzed. The results indicate that there are differences among test methods relative to different specifications with the same index and therefore, confusion has ensued when selecting test methods. All test methods with the exception of the method of water absorption rate by using a Karsten flask are not non-destructive methods or conducted in a laboratory. Finally, further research on silicone water repellent during application is proposed.

Effects of NaF evaporation rate on the properties of $CuInSe_2$ thin-film solar cells

  • Park, Sun-Yong;Lee, Eun-U;Lee, Sang-Hwan;Park, Sang-Uk;Jeong, U-Jin;Kim, U-Nam;Jeon, Chan-Uk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.36.2-36.2
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    • 2010
  • A small amount of Na incorporated in $CuInSe_2$ (CIS) absorption layer has become widely accepted as a requirement for efficient polycrystalline CIS solar cells. However, there is ongoing argument on the role of sodium incorporated in the absorber. In this paper, CIS absorption layers have been deposited using the three-stage co-evaporation process on Mo coated non-Alkali glass substrates. The NaF was evaporated during the second-stage with various fluxes. This paper is focusing on differences of micro-structure and composition ratio of the absorber realized with different Na contents and the variation of electrical properties of the cells with the corresponding absorbers. The analytical results of x-ray diffraction (XRD) patterns, field emission scanning electron microscope (FE-SEM), energy dispersive spectroscopy (EDS) and current-voltage characteristics will be discussed to investigate the effect of NaF flux on the CIS absorber formation and its cell performance.

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