• 한국산업보건학회지
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• 제20권1호
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• pp.10-18
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• 2010

To provide necessary information for future environmental monitoring of smelting and litharge making industries in Korea, environmental monitoring dataset of air lead concentration of 4 lead industries(1 primary smelting, 2 secondary smelting and 1 litharge making industry) were analyzed from 1994 to 2007. Data were compared using geometric mean and standard deviation with minimum and maximum values according to year of measurement, type of lead industries and type of operation of lead industries. The geometric mean and standard deviation of air concentration for a total of 1140 samples in all lead industries for overall 14 years were 70.7${\mu}g/m^3$ and 5.51 with minimum of 1${\mu}g/m^3$ and maximum of 9,185 ${\mu}g/m^3$. The overall geometric means of air concentration were above the permissible exposure levels(PEL) until year of 2001 and thereafter they were remained at the level of half of PEL. The geometric means of primary smelting, secondary smelting and litharge making industry for overall 14 years were 21.7${\mu}g/m^3$(number of samples: 353), 82.5${\mu}g/m^3$(number of samples: 357) and 164.2 ${\mu}g/m^3$(number of samples: 430) respectively. In primary smelting industry, the highest geometric mean air concentration was 35.4 ${\mu}g/m^3$ in the secondary smelting operation; followed by casting operation (24.9 ${\mu}g/m^3$) and melting operation (14.9 ${\mu}g/m^3$), respectively. On the other hand, in secondary smelting industries, the highest geometric mean air concentration was 125.4${\mu}g/m^3$ in melting operation; followed by casting operation (90.5${\mu}g/m^3$) and pre-treatment operation (43.4${\mu}g/m^3$), respectively. However, in litharge making industries, there were no significant differences of geometric mean air concentrations between litharge operation and stabilizer operation. The proportion of over PEL (50${\mu}g/m^3$) was highest in litharge industry and followed by secondary smelting industries. However The proportions of over PEL(${\mu}g./m^3.$) were decreased by the years of environmental monitoring. The significant reduction of mean air lead concentration since year of 2000 was observed due to more active environmental engineering control and new introduction of new operation in manufacturing process, but may be also influenced by non-engineering method such as reduction of operation hours or reduction of exposure time during actual environmental measurement by industrial hygienist according to more strict enforcement of occupational and safety law by the government.

• Journal of Preventive Medicine and Public Health
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• 제26권1호
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• pp.65-73
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• 1993

This study was carried out to evaluate the relationship between the biological lead exposure indices and air lead concentrations measured by personal air samplers. The 72 occupationally lead exposed workers were observed and the bioiogical lead Exposure indices chosen for this study were blood lead(PbB), urine lead(PbU), zinc protoporphyrin in whole blood(ZPP), $\delta$-aminolevulinic acid in urine(ALAU), $\delta$-aminolevulinic acid dehydratase activity (ALAD), coproporphyrin in urine(CPU) and hemoglobin(Hb). The workers were divided into four groups by air lead concentrations: Group I; under $0.05mg/m^3$, Group II; $0.05-0.10mg/m^3$, Group III; $0.10-0.15mg/m^3$ and Group IV; and over $0.15mg/m^3$. For evaluation the relationship between the biological lead exposure indices and air lead concentrations was used as correlation coefficients. The results obtained were as follows: 1. In Group I, II, III and IV, the mean value of PbB were $25.45{\pm}1.84{\mu}g/dl,\;27.87{\pm}3.53{\mu}g/dl,\;31.21{\pm}1.76{\mu}g/dl\;and\;47.02{\pm}13.96{\mu}g/dl$. Between Group IV and other groups showed statistically significant difference(p<0.05). 2. There was an increasing tendency of PbB, PbU, ALAU and ZPP according to the increase the mean air lead concentration, while ALAD has decreasing tendency. CPU and Hb did not show any constant tendency. 3. Correlation coefficients between PbB, PbU, ZPP, ALAU, ALAD, CPU, Hb and air lead concentration were 0.95, 0.83, 0.89, 0.72, -0.83, 0.51 and -0.45 respectively, and regression coefficient between PbB(Y) and PbA(X) was Y=126.8746X+16.9996(p<0.01).

• Journal of Preventive Medicine and Public Health
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• 제29권3호
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• pp.693-700
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• 1996

부산 시내 모 공단에 위치한 폐밧데리로 연을 재생하는 산업장에 인접한 산업장에 근무하는 근로자들의 연 폭로 정도를 알기 위하여 연 폭로원에 인접한 작업장 A의 39명과 연 폭로원에서 8.5km 떨어진 곳에 위치한 동일한 원료, 공정, 자동차 부품을 생산하는 작업장 B의 62명을 연구대상자로 선정하고 표준화된 설문지 조사와 혈중 연 농도를 분석, 비교하였다. 또한 두 산업장의 세 작업장 기중 연 농도를 분석, 비교하였다. 그 결과는 다음과 같다. 1. 산업장 A의 평균연령 (38.7세)이 산업장 B(29.5세) 보다 유의하게 높았고, 근무연수의 차이는 없었다. 2. 평균 기중 연 농도는 산업장 A $2.6{\mu}g/m^3$, 산업장 B $1.2{\mu}g/m^3$로 산업장 A가 유의하게 높았다(P<0.05). 또한 산업장 A의 평균 기중 연 농도는 실내작업장, 실외작업장, 사무실 순으로 연 폭로원과 거리가 가까울수록 높았고 세 작업장 사이에 유의한 농도차가 있었다(P<0.05). 3. 평균 혈중 연 농도는 산업장 A $14.9{\mu}g/dl$, 산업장 B $12.2{\mu}g/dl$로 산업장 A가 유의하게 높았다(P<0.001). 또한 작업장 A의 세 작업 분야별 평균 혈중 연 농도 사이에는 유의한 통계적 차이(P<0.05)가 있었지만 작업장 B는 없었고 작업장 A의 평균 혈중 연 농도 순은 기중 연 농도 순과 연 폭로원과 떨어진 거리 순과 일치하였다. 4. 혈중 연 농도와 연령, 근무연수 사이의 상관관계는 산업장 A의 경우 상관이 낮았고, 산업장 B에서는 연령과 유의한 상관(r=0.382, P=0.0023)을 보였고, 연령을 보정하여도 두 산업장간 평균 혈중 연 농도 차는 유지되었다(P<0.001). 산업장 A에서 보인 작업장소간, Part간 농도의 차이는 연 폭로원에 인접한 산업장의 경우 연 폭로원의 작업환경과 밀접한 관계가 있음을 시사한다. 따라서 유해산업장의 작업환경으로 인하여 발생하는 인접산업장 근로자들의 유해물질에 대한 환경적 폭로는 해당 유해산업장의 환경개선 노력에 의하여 적절히 예방될 수 있을 것이므로 유해산업장의 작업환경에 대한 보다 체계적이고 철저한 감시가 필요할 것으로 생각된다.

• 한국산업보건학회지
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• 제17권4호
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• pp.261-271
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• 2007

To provide necessary information for future environmental monitoring of storage batteries in Korea, authors analyzed environmental monitoring dataset of air lead concentration of 12 storage battery industries measured during 1989-2006. We calculated geometric mean and standard deviation with minimum and maximum value of each year dataset. Air lead concentration data were analyzed according to year of measurement, type of grid manufacturing method (grid casting type or expander type), size of industries and type of operation (casting, lead powder & pasting, assembly and others). The geometric mean and standard deviation of all lead industries for overall 18 years were $72{\mu}g/m^3$ and 3.65 with minimum of $6{\mu}g/m^3$ and maximum of $7,956{\mu}g/m^3$. The geometric mean air lead concentrations of years between 1989-1999 were above the Korean PEL($50{\mu}g/m^3$), whereas those of years after year 2000 were below the Korean PEL showing 50% of it. The geometric mean concentration of air lead was significantly lower in expander method battery industries than that of grid method battery industries and was lower in large sized battery industries than small & medium sized ones throughout the whole 18 years period. The distributions of over PEL($50{\mu}g/m^3$) were decreased by the years of environmental monitoring and those were lower in expander method battery industries than grid method battery industries. The significant reduction of mean air lead concentration during last 10 years may be induced partly due to more active environmental engineering control and new introduction of new operation in grid method battery industries, but may be also influenced by non-engineering method such as reduction of operation hours or reduction of exposure time during actual environmental measurement by industrial hygienist which is not concrete evidence, but just circumstantial evidence.

• Journal of Preventive Medicine and Public Health
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• 제29권4호
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• pp.747-764
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• 1996

This study intended to obtain an useful information for health management of lead exposed workers and determine biological monitoring interval in early period of exposure by measuring the lead exposure indices and work duration in all male workers (n=433 persons) exposed less than 1 year in 6 storage battery industries and in 49 males who are not exposed to lead as control. The examined variables were blood lead concentration (PBB), Zinc-protoporphyrin concentration (ZPP), Hemoglobin (HB) and personal history; also measured lead concentration in air (PBA) in the workplace. According to the geometric mean of lead concentration in the air, the factories were grouped into three categories: A; When it is below $0.05mg/m^3$, B; When it is between 0.05 and $0.10mg/m^3$, and C; When it is above $0.10mg/m^3$. The results obtained were as follows: 1. The means of blood lead concentration (PBB), ZPP concentration and hemoglobin(HB) in all male workers exposed to lead less than 1 year in storage battery industries were $29.5{\pm}12.4{\mu}g/100ml,\;52.9{\pm}30.0{\mu}g/100ml\;and\;15.2{\pm}1.1\;gm/100ml$. 2. The means of blood lead concentration (PBB), ZPP concentration and hemoglobin(HB) in control group were $5.8{\pm}1.6{\mu}g/100ml,\;30.8{\pm}12.7{\mu}g/100ml\;and\;15.7{\pm}1.6{\mu}g/100ml$, being much lower than that of study group exposed to lead. 3. The means of blood lead concentration and ZPP concentration among group A were $21.9{\pm}7.6{\mu}g/100,\;41.4{\pm}12.6{\mu}g/100ml$ ; those of group B were $29.8{\pm}11.6{\mu}g/100,\;52.6{\pm}27.9{\mu}g/100ml$ ; those of group C were $37.2{\pm}13.5{\mu}g/100,\;66.3{\pm}40.7{\mu}g/100ml$. Significant differences were found among three factory group(P<0.01) that was classified by the geometric mean of lead concentration in the air, group A being the lowest. 4. The mean of blood lead concentration of workers who have different work duration (month) was as follows ; When the work duration was $1\sim2$ month, it was $24.1{\pm}12.4{\mu}g/100ml$, ; When the work duration was $3\sim4$ month, it was $29.2{\pm}13.4{\mu}g/100ml$ ; and it was $28.9\sim34.5{\mu}g/100ml$ for the workers who had longer work duration than other. Significant differences were found among work duration group(P<0.05). 5. The mean of ZPP concentration of workers who have different work duration (month) was as follows ; When the work duration was $1\sim2$ month, it was $40.6{\pm}18.0{\mu}g/100ml$, ; When the work duration was $3\sim4$ month, it was $53.4{\pm}38.4{\mu}g/100ml$ ; and it was $51.5\sim60.4{\mu}g/100ml$ for the workers who had longer work duration than other. Significant differences were found among work duration group(P<0.05). 6. Among total workers(433 person), 18.2% had PBB concentration higher than $40{\mu}g/100ml$ and 7.1% had ZPP concentration higher than $100{\mu}g/100ml$ ; In workers of factory group A, those were 0.9% and 0.0% ; In workers of factory group B, those were 17.1% and 6.9% ; In workers of factory group C, those were 39.4% and 15.4%. 7. The proportions of total workers(433 person) with blood lead concentration lower than $25{\mu}g/100ml$ and ZPP concentration lower than $50{\mu}g/100ml$ were 39.7% and 61.9%, respectively ; In workers of factory group A, those were 65.5% and 82.3% : In workers of factory group B, those were 36.1% and 60.2% ; In workers of factory group C, those were 19.2% and 43.3%. 8. Blood lead concentration (r=0.177, P<0.01), ZPP concentration (r=0.135, P<0.01), log ZPP (r=0.170, P<0.01) and hemoglobin (r=0.096, P<0.05) showed statistically significant correlation with work duration (month). ZPP concentration (r=0.612, P<0.01) and log ZPP (r=0.614, P<0.01) showed statistically significant correlation with blood lead concentration 9. The slopes of simple linear regression between work duration(month, independent variable) and blood lead concentration (dependent variable) in workplace with low air concentration of lead was less steeper than that of poor working condition with high geometric mean air concentration of lead. The study result indicates that new employees should be provided with biological monitoring including blood lead concentration test and education about personal hygiene and work place management within $3\sim4$ month.

• 한국환경과학회지
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• 제4권5호
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• pp.535-542
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• 1995

Monitoring of lead concentration in the ambient alt was performed in Kyung Hee University-Suwon Campus over a period of 5 year from November 1989 to September 1994 using a cascade impactor having 9 size stages. Lead level was analyzed by x-ray fluorescence. The lead levels have been extensively examined to identify annual trends, seasonal variations, and size distribution of lead concentration. Even though consumption of leaded gasoline has been decreased, the levels have not significantly changed during the sampling period. Probably other sources like fossil fuel emission and refuse incinerator will be potential contributors. The seasonal variation showed that Pb concentration significantly increased in the winter season and decreased in the summer season. The size distributions of Pb were observed to be unimodal distribution of the 1.1~2.1 $mu extrm{m}$ sixte ranges in the winter and 0.65~1.1 ${\mu}{\textrm}{m}$ in the summer.

• 한국환경과학회지
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• 제4권5호
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• pp.149-149
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• 1995

Monitoring of lead concentration in the ambient alt was performed in Kyung Hee University-Suwon Campus over a period of 5 year from November 1989 to September 1994 using a cascade impactor having 9 size stages. Lead level was analyzed by x-ray fluorescence. The lead levels have been extensively examined to identify annual trends, seasonal variations, and size distribution of lead concentration. Even though consumption of leaded gasoline has been decreased, the levels have not significantly changed during the sampling period. Probably other sources like fossil fuel emission and refuse incinerator will be potential contributors. The seasonal variation showed that Pb concentration significantly increased in the winter season and decreased in the summer season. The size distributions of Pb were observed to be unimodal distribution of the 1.1∼2.1 $mu extrm{m}$ sixte ranges in the winter and 0.65∼1.1 ㎛ in the summer.

• 한국산업보건학회지
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• 제30권2호
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• pp.163-173
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• 2020

Objectives: The study was evaluated exposure variation and daily absorption level of cadmium, lead concentration of ambient air of monthly data from 1999 to 2017 for main exposure factor in outdoor workers. Methods: Based on the monthly data from 'The annual report of air quality in Korea from 1999 to 2018' in 'Air Korea' website in the Korean Ministry of Environment. The monthly data of PM_2.5, PM₁₀, cadmium, lead concentration of ambient air were recalculated to average, minimum, and maximum. And these data were combined to Asian-dust exposure data from 'The annual report of Asian-dust·smog in 2017' of National Institute of Meteorological Sciences in Korea. Results: Geometric mean(minimum-maximum) concentration in ambient air of monthly data were 0.0017 (ND-0.2015) mg/㎥ in cadmium and 0.0467(ND-0.8554) mg/㎥ in Pb from 1999 to 2017. Both of Cd and Pb concentration in ambient air showed the highest concentration in January and the lowest in August among annual variation from 1999 to 2017. PM₁₀ and PM_2.5 level showed the highest in March(PM₁₀) and February (PM_2.5) the lowest in August both of PM₁₀ and PM_2.5. Discussion: Based on exposure data and prior reports, daily Cd absorption was estimated to 0.013(ND-1.511) mg/day from respiration and 1.89 mg/day from daily food(25.2 mg/day of daily Cd intake). In case of Pb, daily absorption was estimated to 0.350(ND-6.416) mg/day from respiration and 1.38-1.71 mg/day from daily food intake. Conclusion: Cd and Pb with Asian-dust have high influential factor to increase the Cd and Pb exposure at Winter and Spring season in outdoor workers.

• Journal of Preventive Medicine and Public Health
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• 제24권2호
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• pp.181-194
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• 1991

This study intended to obtain an useful information on the prevalence of subjective symptoms, and to clarify the interrelationships between blood lead and lead related symptoms in low level lead exposure. The 93 male workers exposed to lead and 56 male nonexposed workers were examined for their blood lead(PBB), Zinc-protoporphy(ZPP), hemoglobin(HB) and personnal history, and completed 15 questionnaires related to symptoms of lead absorption : also measured lead concentration in air (PBA) in the workplace. The results obtained were as follows ; 1. The means of blood lead (PBB), blood ZPP and hemoglobin (HB) among workers exposed to lead were $26.1{\pm}8.8{\mu}g/dl,\;28.3{\pm}26.0{\mu}g/dl$ and $16.2{\pm}1.2g/dl$ : whereas those of nonexposed workers were $18.7{\pm}5.1{\mu}g/dl,\;20.6{\pm}8.7{\mu}g/dl$ and $17.3{\pm}1.1g/dl$. The means of above three indicies between two groups showed significant difference statistically (p<0.05). 2. The means of blood lead (PBB), blood ZPP and hemoglobin of workers exposed .to different lead concentration in air were as follows : When it was below $25{\mu}g/m^3$, the indices were $24.7{\pm}79,\;26.1{\pm}26.8{\mu}g/dl\;and\;16.4{\pm}1.1g/dl$ respectively : These indices were $27.1{\pm}8.5,\;23.9{\pm}10.92{\mu}g/dl\;and\;16.2{\pm}1.3g/dl$ when the lead concentration in air was $25{\sim}50{\mu}g/m^3$ : and they were $3.4{\pm}9.3,\;42.3{\pm}31.3{\mu}g/dl\;and\;15.5{\pm}1.2g/dl$ when the concentration of lead was above $50{\mu}g/m^3$. Although there were statistical difference in blood lead and hemoglobin among three different lead concentration in air, there was no statistical difference of blood ZPP among the three groups with different exposure levels (p>0.05). 3. The most frequent by complained symptom was 'Generalized weakness and fatigue', and fewest symptom was 'Intermittent pains in abdomen' 4. Only two symptoms out of fifteen symptoms checked by themselves revealed significant difference between exposed and nonexposed groups. These were 'Intermittent pains of abdomen' and 'Joint pain or arthralgia' (p<0.05), No positive correlation was found between the levels of blood lead and symptom groups categorized as gastrointestinal, neuromuscular and constitutional symptoms, 5. Blood lead (r=0.3995) and ZPP (r=0.2837) showed statistically significant correlation with mean lead concentration in air, whereas correlations were not demonstrated between blood lead and lead related symptoms or blood ZPP and lead related symptoms. 6. Blood lead (PBB) and ZPP showed association (r=0.2466) and the equation PBB=23.75+0.0842 ZPP was derived. 7. On stepwise multiple regression, using blood lead level as a dependent variable and ZPP, hemoglobin (HB), age, work duration (WD) and symptom prevalence as a independent variables, only ZPP significantly contributed a lot to blood lead level. 8. While the ZPP measurement was found to be a good indicator in evaluating health effect of lead absorption in low level lead exposure, lead related symptoms were not sensitive enough to evaluate of lead absorption in low level exposure.

• 한국대기환경학회지
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• 제2권3호
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• pp.11-18
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• 1986

In order to evaluate the state of the environmental pollution by vehicle exhaust in Seoul area the correlation between lead in air and leaves of roadside trees has been investigated during August in 1985. The dust in the atmosphere was collected by high volume air sampler to measure the concentration of lead. On the other hand, lead as a pollution indicator was extracted from the leaves of roadside trees (Ginkgo biloba, Salix pseudo/lasiogyne, platanus occidentalis) by conventional method and their concentrations were determined. The following results were obtained : 1. Lead concentrations in the leaves of roadside trees varied with trees, for example, the average concentrations of lead in each of the leaves of Ginkgo biloba, Salix pseudo/lasiogyne and Platanus occidentalis were 20.66 ppm, 9.37 ppm, and 10.58 ppm, respectively. 2. The dust sampled along heavily traveled highways showed that lead content tended to increase with traffic volume. 3. The correlation coefficients between lead correlation in air and leaves of Gingo biloba, Salix pseudo/lasiogyne, and Platanus orientalis were 0.80, 0.85, and 0.87, respectively.