• 한국식품과학회지
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• 제30권2호
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• pp.341-347
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• 1998

본 연구에서는 서로 다른 동결조건 및 방법에 따른 우육 및 tylose의 단순하며 간편한 동결시간을 예측할 수 있는 모델을 모색하기 위하여 23개의 실험데이터를 이용하여 시료의 초기온도$(X_1)$, 시료의 두께$(X_2)$와 시료의 초기빙결점에서 동결매체 온도사이의 차의 역수$(X_3)$ 및 표면열전달계수의 역수$(X_4)$를 독립변수로 하고 동결시간(Y)을 종속변수로 설정하여 다중회귀 분석을 실시한 결과, $Y_{tylose}=3.45X_1+7642.84X_2+4642.67X_3+2946.89X_4-431.33\;(R^2=0.9568)$ 및 $Y_{beef}=0.68X_1+7568.98X_2+2430.78X_3+3293.26X_4-299.00\;(R^2=0.9897)$의 방정식을 구하였다. 본 모델은 Cleland & Earle와 Hung & Thompson의 모델과 마찬가지로 평균절대오차는 10% 수준으로, Plank, Nagaoka 및 Pham의 모델보다 정확함과 아울러 매우 간편함을 보여 주었다. 또한, 우육 및 tylose의 $6{\sim}7^{\circ}C$ 범위에서의 열확산율은 $4.43{\times}10^{-4}m^2/hr$ 및 $4.39{\times}10^{-4}m^2/hr,\;-10{\sim}-12^{\circ}C$에서의 열확산율은 $2.42{\times}10^{-3}m^2/hr$ 및 $3.32{\times}10^{-3}m^2/hr$로 측정되었고, tylose 및 우육의 빙결점은 각각 $-0.6^{\circ}C$ 및 $-1.2^{\circ}C$로 나타났다. 그리고 표면열전달계수는 송풍식에서 무포장시 $20.57\;W/m^2^{\circ}C$, wrap 포장시는 $16.11\;W/m^2^{\circ}C$, wrap 과 Al-foil로 포장한 경우에는 $13.07\;W/m^2^{\circ}C$로 계산되었으며, 침지식은 송풍식보다 냉각속도가 약 10배 이상 빠르게 나타났다.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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• pp.5-6
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• 2002

The new spectrometer for X-ray Induced Electron Emission Spectroscopy (XIEES) .has been recently developed in KRISS in collaboration with PTI (Russia). The spectrometer allows to perform research using the XAFS, SXAFS, XANES techniques (D.C.Koningsberger and R.Prins, 1988) as well as the number of techniques from XIEES field(L.A.Bakaleinikov et all, 1992). The experiments may be carried out with registration of transmitted through the sample x-rays (to investigate bulk samples) or/and total electron yield (TEY) from the sample surface that gives the high (down to several atomic mono-layers in soft x-ray region) near surface sensitivity. The combination of these methods together give the possibility to obtain a quantitative information on elemental composition, chemical state, atomic structure for powder samples and solids, including non-crystalline materials (the long range order is not required). The optical design of spectrometer is made according to Johannesson true focusing schematics and presented on the Fig.1. Five stepping motors are used to maintain the focusing condition during the photon energy scan (crystal angle, crystal position along rail, sample goniometer rail angle, sample goniometer position along rail and sample goniometer angle relatively of rail). All movements can be done independently and simultaneously that speeds up the setting of photon energy and allows the using of crystals with different Rowland radil. At present six curved crystals with different d-values and one flat synthetic multilayer are installed on revolver-type monochromator. This arrangement allows the wide range of x-rays from 100 eV up to 25 keV to be obtained. Another 4 stepping motors set exit slit width, sample angle, channeltron position and x-ray detector position. The differential pumping allows to unite vacuum chambers of spectrometer and x-ray generator avoiding the absorption of soft x-rays on Be foil of a window and in atmosphere. Another feature of vacuum system is separation of walls of vacuum chamber (which are deformed by the atmospheric pressure) from optical elements of spectrometer. This warrantees that the optical elements are precisely positioned. The detecting system of the spectrometer consists of two proportional counters, one scintillating detector and one channeltron detector. First proportional counter can be used as I/sub 0/-detector in transmission mode or by measuring the fluorescence from exit slit edge. The last installation can be used to measure the reference data (that is necessary in XANES measurements), in this case the reference sample is installed on slit knife edge. The second proportional counter measures the intensity of x-rays transmitted through the sample. The scintillating detector is used in the same way but on the air for the hard x-rays and for alignment purposes. Total electron yield from the sample is measured by channeltron. The spectrometer is fully controlled by special software that gives the high flexibility and reliability in carrying out of the experiments. Fig.2 and fig.3 present the typical XAFS spectra measured with spectrometer.

• Restorative Dentistry and Endodontics
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• 제20권2호
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• pp.399-422
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• 1995

The purpose of this study was to investigate a fragment of possibility of pulpotomy with the Nd-YAG laser by the observation of pulpal healing process and the fine structural changes of the fibroblasts of the remaining pulpal tissues. Class V cavities on !55 teeth from 4 adult dogs were prepared and the pulp chambers were opened with a sterilized round bur. In the control group(19 teeth), the exposed coronal pulps were excised by a sharp excarvator. After bleeding was controlled with the sterilized cotton pellets, calcium hydroxide powder was applied on the remaining pulpal tissues and the cavities were sealed with Z.O.E. In the experimental group 1 : the pulpotomy with laser-calcium hydroxide powder application group(l9 teeth), the exposed coronal pulps were excised by Nd-YAG laser(10 watts power, 2 psi water, 20 psi air) for 2 or 3 seconds and calcium hydroxide powder was applied on the remaining pulpal tissues and the cavities were sealed with Z.O.E. In the experimental group 2 : the pulpotomy with laser-no calcium hydroxide powder application group(17 teeth), after amputating the coronal pulps with Nd-YAG laser as the experimental group 1, the remaining pulpal tissues were covered with stenilized aluminum foil and the cavities were filled with Z.O.E. The animals were sacrificed at the intervals of 1, 2, 3 and 4 weeks. All the teeth were rouutinely processed and the remaining pulpal tissues were observed by the light microscope and electron microscope. The results were as follows : 1. In light microscopic findings, there was no significant difference of the inflammatory response in the remaining pulpal tissues between the control group and the experimental groups. In both of the experimental group 1 : pulpotomy with laser-calcium hydroxide powder application group and the control group, the dentin bridges were observed after 2 weeks and the structure of the dentin bridge was almost same. In the experimental group 2 : pulpotomy with laser-no calcium hydroxide powder application group, the fibrous layers instead of dentin bridge were observed on the superficial portion of the remaining pulpal tissues after 2 weeks and they were consisted with densely crowded active fibroblasts. 2. In the electronmicroscopic findings, the active fibroblasts in the experimental groups were more frequently observed than in the control group at 1 week. But active fibroblasts were found with same frequency after 2 weeks in all of the control group and the experimental groups. 3. General distortions of the cell such as loss of the cell membrane, vaculoization of the cell etc. were observed at the suberficial layer of the remaining pulpal tissues and the carbonization was found in the dentinal wall in 1 week of the experimental groups. 4. In the experimental group 2 : pulpotomy with laser-no calcium hydroxide powder application group, the activity and the density of the fibroblasts in the fibrous layer were more than those in the deep portion of the remaining pulpal tissues after 2 weeks. 5. In the control group, bacteria such as cocci and bacilli were observed frequently, but in the experimntal groups, they could not be observed.

• 한국수산과학회지
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• 제20권1호
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• pp.41-51
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• 1987

다획성적색육어류인 고등어를 원료로하여 우리나라 사람의 기호에 맞고 즉석(卽席)수우프의 원료로 이용할 수 있는 고등어분말수우프를 제조하기 위한 가공조건 및 이의 효율적인 저장방법과 제품의 맛성분에 대하여 검토하였다. 가공조건은 고등어를 필레로 만들어 $95^{\circ}C$의 열수 중에서 10분간 자숙한 다음 압착하여 가다랑어자숙 엑스분 중에서 5분간 침지하였다. 이것을 $80^{\circ}C$에서 8시간의 훈건 및 엄증을 3차례 반복하여 수분함량이 약 $10\~12\%$되도록 하여 50 mesh 크기로 분쇄한후 $(PET/Al\;foil/CPP:\;5{\mu}m/15{\mu}m/70{\mu}m,\;15\times17cm)$ 적층필름주머니에 일정량 충전하여 포장용기내의 공기를 질소치환 혹은 탈산소제를 봉입포장하여 저장함으로서 제품의 품질변화를 최대한 억제시킬 수 있었다. 한편 제품제조시 가다랑어자숙엑스분중에 침지처리함으로서 제조중 지방산화의 억제 및 제품의 풍미를 향상시킬 수 있었다. 고등어분말수우프의 수분함량은 $11.3\~12.3\%$, 조지방 $12.0\%$, 조단백질 $73.0\%$, 회분 $3.2\%$ 및 구분활성은 $0.52\~0.56$의 범위로서 저장중 거의 변화가 없었고, 제품의 pH, 휘발성염기질소 및 아미노질소는 저장기간이 경과함에 따라 약간씩 증가하는 경향이었다. 저장중 제품의 수용성 및 지용성 갈변도는 함기포장제품(C)의 경우 증가하는 경향을 나타내나 질소치환포장제품(N)이 나 탈산소제 봉입 포장제 품(O)은 거의 변화가 없었고, 과산화물값, 카르보닐값 및 TBA값을 측정한 결과 제품(N) 및 (O)는 저장중 지방산화를 효율적으로 억제 할 수 있었다. 제품의 주요구성지방산은 16:0, 18:1, 22:6, 18:0 및 20:5 등이었으며 제품제조 및 저장중 폴리엔산은 다소 감소한 반면, 포화산 및 모노엔산의 조성비는 증가하였다. 고등어분말수우프제품의 주요한 맛성분이라고 추정되는 IMP의 함량은 $420.2\~454.2mg/100g$으로서 저장중 약간씩 감소하는 경향이었고, 주요불휘발성 유기산은 lactic acid, succinic acid, $\alpha-ketoglutaric\;acid$ 등으로 함량은 각각 902.2 mg/100 g, 28.3 mg/100g 및 8.6mg/100g이었다. 이외에 malic acid 등 6종의 유기산이 미량 함유되어 있었다. 제품의 유리아미노산 및 관련화합물의 조성은 histidine이 641.8 mg/100g으로 가장 많았고, alanine 214.7 mg/100g, hydroxyproline이 48.9mg/100g, 이외에 lysine, glutamic acid 및 anserine 등이 전체의 $80.8\%$를 차지하였다. 고등어분말수우프의 맛성분은 건물량 기준으로 유리아미노산 및 관련화합물이 1,279.4 mg/100g, 불휘발성유기산이 948.1mg/100g, 핵산 관련물질 672.8 mg/100g, 총 creatinine이 430.4 mg/100g, betaine 86.6mg/100g 및 미량의 TMAO로 이루어져 있었고 국물로 우려낼때 맛성분의 추출조건은 $100^{\circ}C$에서 1분간의 고온단시간 추출이 적합하였다.