• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.425-431
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• 2019

As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

• Advances in concrete construction
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• v.7 no.3
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• pp.151-166
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• 2019

This paper introduces a new efficient analytical method, based on shear deformations obtained with 2D elasticity theory approach, to perform an explicit closed-form solution for calculation the interfacial shear and normal stresses in plated RC beam. The materials of plate, necessary for the reinforcement of the beam, are in general made with fiber reinforced polymers (Carbon or Glass) or steel. The experimental tests showed that at the ends of the plate, high shear and normal stresses are developed, consequently a debonding phenomenon at this position produce a sudden failure of the soffit plate. The interfacial stresses play a significant role in understanding this premature debonding failure of such repaired structures. In order to efficiently model the calculation of the interfacial stresses we have integrated the effect of shear deformations using the equilibrium equations of the elasticity. The approach of this method includes stress-strain and strain-displacement relationships for the adhesive and adherends. The use of the stresses continuity conditions at interfaces between the adhesive and adherents, results pair of second-order and fourth-order coupled ordinary differential equations. The analytical solution for this coupled differential equations give new explicit closed-form solution including shear deformations effects. This new solution is indented for applications of all plated beam. Finally, numerical results obtained with this method are in agreement of the existing solutions and the experimental results.

• Journal of Advanced Navigation Technology
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• v.24 no.6
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• pp.465-470
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• 2020

Complex materials are widely used in aviation industries where lightweighting is essential because they have lighter properties than metals. However, composite materials can cause defects such as internal void formation, poor adhesive mixing, and non-adhesive parts during the production process, and there is a risk of micro-cracking and interlayer separation due to low energy impact. Therefore, a structural damage test is essential. As a result, structural integrity monitoring using FBG is drawing attention. Compared to conventional electrical sensors, FBG has the advantage of being more corrosion-resistant and multiplexed without being affected by electrical noise. However, interloggers measuring FBG are expensive and have a large disadvantage because they are made on the premise of measuring large structures. In this paper, low-cost interloggers were designed for use in unmanned or small aircraft using optical switche, WDM filter, and LTFs, and compared to conventional high-priced interrogator.

• Composites Research
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• v.34 no.3
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• pp.174-179
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• 2021

Currently, fluid transfer steel pipes take a lot of time and expense to maintain all facilities due to new construction and painting or corrosion and aging. Therefore, this study was conducted for designing a CFRP pipe structure with high corrosion resistance and chemical resistance as a substitute for steel pipes. The helical/hoop pattern was cross-laminated to improve durability, and HNT was added to suppress the moisture absorption phenomenon of the epoxy. The HNT/CFRP pipe was manufactured by a filament winding process, and performed a mechanical property test, and a moisture absorption test in distilled water at 70℃. As a result, the highest bending strength was obtained when the hoop pattern was laminated with a thickness equivalent to 0.6% of the pipe. The 0.5 wt% HNT specimen had the highest moisture absorption resistance. Also, the delamination phenomenon at the interlayer interface was delayed, resulting in the lowest strength reduction rate.

• Journal of Advanced Navigation Technology
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• v.26 no.1
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• pp.22-28
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• 2022

In order to install ultra wide band and ultra long-haul transmission link based on standard single mode fiber, optical signal distortion due to chromatic dispersion and nonlinear Kerr effect must to be compensated. In this paper, optical link consisted of dispersion management and optical phase conjugation is proposed for compensation of the distorted wavelength division multiplexed (WDM) channels. Dispersion map profile in the proposed dispersion-managed link is configured by periodic repetitive shape, and optical phase conjugator is placed at various position including the midway of total transmission length. It is confirmed from simulation results that when the residual dispersion per span (RDPS) selected in the proposed dispersion-managed link to be large, the compensation of distorted WDM channels in the non-midway OPC system is more improved than the conventional dispersion-managed link.

• Steel and Composite Structures
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• v.43 no.4
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• pp.447-456
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• 2022

Recent experimental studies showed that deep steel I-shaped profiles classified as high ductility class sections in seismic design international codes exhibit low deformation capacity when subjected to cyclic loading. This paper presents an innovative retrofit solution to increase the rotation capacity of beams using bonded carbon fiber reinforced polymers (CFRP) patches validated with advanced finite element analysis. This investigation focuses on the flexural cyclic behaviour of I-shaped hot rolled steel deep section used as beams in moment-resisting frames (MRF) retrofitted with CFRP patches on the web. The main goal of this CFRP reinforcement is to increase the rotation capacity of the member without increasing the overstrength in order to avoid compromising the strong column-weak beam condition in MRF. A finite element model that simulates the cyclic plasticity behavior of the steel and the damage in the adhesive layer is developed. The damage is modelled using the cohesive zone modelling (CZM) technique that is able to capture the crack initiation and propagation. Details on the modelling techniques including the mesh sensitivity near the fracture zone are presented. The effectiveness of the retrofit solution depends strongly on the selection of the appropriate adhesive. Different adhesive types are investigated where the CZM parameters are calibrated from high fidelity fracture mechanics tests that are thoroughly validated in the literature. This includes a rigid adhesive commonly found in the construction industry and two tough adhesives used in the automotive industry. The results revealed that the CFRP patch can increase the rotation capacity of a steel member considerably when using tough adhesives.

• Structural Engineering and Mechanics
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• v.83 no.4
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• pp.515-535
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• 2022

The strength models for fiber-reinforced polymer (FRP)-confined normal strength concrete (NC) cylinders available in the literature have been suggested based on small databases using limited variables of such structural members portraying less accuracy. The artificial neural network (ANN) is an advanced technique for precisely predicting the response of composite structures by considering a large number of parameters. The main objective of the present investigation is to develop an ANN model for the axial strength of FRP-confined NC cylinders using various parameters to give the highest accuracy of the predictions. To secure this aim, a large experimental database of 313 FRP-confined NC cylinders has been constructed from previous research investigations. An evaluation of 33 different empirical strength models has been performed using various statistical parameters (root mean squared error RMSE, mean absolute error MAE, and coefficient of determination R²) over the developed database. Then, a new ANN model using the Group Method of Data Handling (GMDH) has been proposed based on the experimental database that portrayed the highest performance as compared with the previous models with R²=0.92, RMSE=0.27, and MAE=0.33. Therefore, the suggested ANN model can accurately capture the axial strength of FRP-confined NC cylinders that can be used for the further analysis and design of such members in the construction industry.

• Clinical and Experimental Reproductive Medicine
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• v.49 no.4
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• pp.259-269
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• 2022

Objective: Animal-free scaffolds have emerged as a potential foundation for consistent, chemically defined, and low-cost materials. Because of its good potential for high biocompatibility with reproductive tissues and well-characterized scaffold design, we investigated whether polyglycolic acid (PGA) could be used as an animal-free scaffold instead of natural fibrin-agarose, which has been used successfully for three-dimensional human endometrial cell culture. Methods: Isolated primary endometrial cells was cultured on fibrin-agarose and PGA polymers and evaluated various design parameters, such as scaffold porosity and mean fiber diameter. Cytotoxicity, scanning electron microscopy (SEM), and immunostaining experiments were conducted to examine cell activity on fabricated scaffolds. Results: The MTT (3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyl tetrazolium bromide) assay and SEM results showed that endometrial cells grew and proliferated on both scaffolds. Immunostaining showed cytokeratin and vimentin expression in seeded cells after 7 days of culture. On both scaffolds, an epithelial arrangement of cultured cells was found on the top layer and stromal arrangement matrix on the bottom layer of the scaffolds. Therefore, fibrin-agarose and PGA scaffolds successfully mimicked the human endometrium in a way suitable for in vitro analysis. Conclusion: Both fibrin-agarose and PGA scaffolds could be used to simulate endometrial structures. However, because of environmental and ethical concerns and the low cost of synthetic polymers, we recommend using PGA as a synthetic polymer for scaffolding in research instead of natural biomaterials.

• Journal of Advanced Navigation Technology
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• v.26 no.6
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• pp.474-480
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• 2022

Optical phase conjugation is one of techniques capable of compensating for distortion due to chromatic dispersion and nonlinearity, which are essential for long-distance transmission of wavelength division multiplexed (WDM) signal. We proposed and analyzed a way to solve the limitations of this technology through dispersion map with periodic dispersion profile. In the proposed system, optical phase conjugator (OPC) is placed at the position of 1:2 or 2:1 of the entire link, and the dispersion profile of dispersion map has periodic shape in the form of a sine wave or an inverse-sine wave. It was confirmed that the effective compensation of the distorted 960 Gb/s WDM signal was further improved through the proposed periodic dispersion map when the OPC was located at the 1:2 point instead of the 2:1 point of the entire link. In addition, it was found that the maximum RDPS allocated to fiber span should be 1,800 ps/nm or more in order to increase the design flexibility of dispersion-managed link with the proposed periodic dispersion map.

• Current Optics and Photonics
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• v.8 no.4
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• pp.406-415
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• 2024

The major error factors that degrade the efficiency of coherent beam combining (CBC) are numerically studied in a comprehensive manner, paying particular attention to phase, tip-tilt, polarization angle, and beam quality. The power in the bucket (PIB), normalized to the zero-error PIB, is used as a figure of merit to quantify the effect of each error factor. To maintain a normalized PIB greater than or equal to 95% in a 3-channel CBC configuration, the errors in phase, tip-tilt, and polarization angle should be less than 1.06 radians, 1.25 ㎛, and 1.06 radians respectively, when each of the three parameters is calculated independently with the other two set to zero. In a worst-case scenario of the composite errors within the parameter range for the independent-95%-normalized-PIB condition, the aggregate effect would reduce the normalized PIB to 83.8%. It is noteworthy that the PIB performances of a CBC system, depending on phase and polarization-angle errors, share the same characteristic feature. A statistical approach for each error factor is also introduced, to assess a CBC system with an extended number of channels. The impact of the laser's beam-quality factor M² on the combining efficiency is also analyzed, based on a super-Gaussian beam. When M² increases from 1 to 1.3, the normalized PIB is reduced by 2.6%, 11.8%, 12.8%, and 13.2% for a single-channel configuration and 3-, 7-, and 19-channel CBC configurations respectively. This comprehensive numerical study is expected to pave the way for advances in the evaluation and design of multichannel CBC systems and other related applications.