• 한국환경농학회지
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• 제9권2호
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• pp.105-111
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• 1990

제초제 butachlor의 토양흡착 실험을 수행한 결과 다음과 같은 결론을 얻었다. 1. Freundlich 방정식으로 구한 butachlor의 흡착상수 K 값은 9.78이었고 1/n값은 0.79였다. 이 때 correlation coefficient는 0.992였다. K값으로부터 유기물 함량을 감안하여 계산된 Koc값은 543이었다. 이 수치는 기존 문헌치와 거의 일치하였다. 2. 온도변화에 따른 흡착량은 온도가 증가할수록 흡착량도 증가하는 경향을 보였으며 $15^{\circ}C$ 온도변화에 대한 흡착량의 변화는 5%정도였다. 3. Computer program을 이용하여 토양 흡착계수를 추정한 결과 실험치와 20배 정도의 차이를 보이나 실험을 수행하기전 토양흡착계수를 예측하는데 있어서는 활용 가능성이 있음을 확인하였다. 4. Butachlor는 비교적 토양에 흡착이 잘되는 화합물로 판정되었다.

• 한국환경농학회지
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• 제25권4호
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• pp.365-370
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• 2006

This study was performed to determine the adsorption-desorption characteristics of polyhexame-thyleneguanidine phosphate in three different soil types of textural classification. Adsorption and desorption studies is impotent for prediction their fate and generating essential information on the mobility of chemicals and their distribution in the soil, water and air of our biosphere. The detection limit of the test substance quantified by a spectroscopic method using Eosin indicator was $0.25{\mu}g/mL$. The reproducibility of analytical method was confirmed by the preliminary test. The concentrations of polyhexamethylenequanidine phosphate in aqueous solution were $1.36{\pm}0.09,\;2.45{\pm}0.01,\;and\;$4.25{\pm}0.05{\mu}g/mL$ by a spectroscopic method using Eosin indicator. The adsorption percents of polyhexamethylenequanidine phosphate in soil were greater than 95.2% for all three test soils. The desorption percents from the adsorbed soil were less than 4.5, 4.7 and 4.7%. Therefore, the adsorption coefficient (K) were greater than 110, 111 and 116. The adsorption coefficient calculated as a function of the organic carbon content (Koc) of the test soils were greater than 9,181, 11,100, and 8,942, respectively. Therefore, the test substance, polyhexamethylenequanidine phosphate could be concluded as medium or high adsorption (>25%) and poorly desorption (<75%) in soil media. Therefore, this chemical is likely to be retained in soil media and may not pose a risk in the aquatic environment.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1997년도 총회 및 춘계 학술발표회 논문집
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• pp.79-82
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• 1997

토양내에서 오염유기물질이 불포화토양내에 유입될 때의 dispersion coefficient를 adsorption과 desorption과정에 대해 알아보았다. apparent dispersion coefficient를 측정하기 위해 일상적인 상대습도(46%)조건에서 parametric analysis를 행하였다. 실험에 사용된 토양은 fine sand와 silt-clay혼합시료였고, 흐름방향은 상향과 하향으로 하였다. 그리고, Freon gas를adsorbing solute로 사용하였다. 오염물질로는 DCM, TCE, DCB를 사용하였다. 분석을 위해서 linear와 probability scale의 breakthrough curve를 사용하였다. 공기에서의 diffusion coefficient의 예측을 위하여 Graham's law를 계산에 사용하였고, DCM diffusion coefficient는 0.098$\textrm{cm}^2$/s로 계산되었다. 연구결과, adsorption과 desorption의 속도는 차이가 있는 것으로 나타났으며, diffusion이 flow regime을 좌우하는 것으로 나타났다. 그리고, desorption에서의 D$^{a}$ D$^{o}$ 는 1보다 클수도 있다. 또한, dispersion은 silt-clay혼합시료에서의 속도와 함께 증가한다. dispersion은 Freon의 sorption방향에 크게 의존한다.

• 한국환경과학회지
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• 제5권2호
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• pp.243-252
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• 1996

미국 New Jersey주에서 채취한 4종류의 토양사료를 이용하여 토양에서 카드뮴 흡착과 치환성양이온의 탈착에 미치는 pH와 유기뮬함령의 영향을 조사하였다. 카드뮴용액으로는 $1\times10^{-5}$M,$1\times10^{-4}$M, $2\times10^{-4}$M, $3\times10^{-4}$M ${Cd(NO_3)}_2$ 용액을 사용하였고, 흡착평형시의 토양용액의 pH는 4.0,5.5, 7.0, 8.5로 맞추었다. 카드뮴흡착등온선의 기울기는 토양용액의 pH가 증가하였으며, partition coefficient($K_4$)도 용액의 pH가 증가할수록 크게 증가하였다. 또한 Langmuir흡착방정식에 의하여 구한 카드뮴대흡착량도 용액의 pH가 높은 경구가 낮은 경우보다 훨씬 많았다. $1\times10^{-4}$M ${Cd(NO_3)}_2$ 용액을 사용한 실험에서 유기물함량과 partition coefficient사이의 correltion coefficient($r^2$)는 용액의 pH가 4.0인 경우의 0.3027에서 pH가 8.5인 경우의 0.9964로 증가하였으며, $2\times10^{-4}$M ${Cd(NO_3)}_2$ 용액을 사용한 실험에서는 pH가 4.0인 경우의 0.2093에서 pH가 8.5인 경우의 0.9657로 증가하였다. 칼슘과 마그네슘의 탈착량은 토양용액의 pH가 증가할수롱, 흡착된 카드뮴의 양이 증가할수록 감소하였다.

• 한국세라믹학회지
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• 제45권12호
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• pp.832-838
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• 2008

Diatomite, bentonite and zeolite were used as porous materials for fabricating hygroscopic panels. Moisture adsorption and desorption of porous materials were investigated and hydrothermal method was applied to fabricate panels. Cheolwon diatomite and Pohang zeolite showed excellent characteristics of moisture adsorption and desorption. These characteristics were caused by higher surface area and pore volume of porous materials. Correlation coefficient between surface area and moisture adsorption content of porous materials was 0.93. Moisture adsorption contents were influenced by surface area and pore volume of panels, and surface area more effected on moisture adsorption. Correlation coefficient between surface area and moisture adsorption content of panels was 0.86. Moisture adsorption content of panel with 10% Pohang zeolite was $180\;g/m^2$ and that of 10% Cheolwon diatomite was $170\;g/m^2$. Moisture desorption content of panel with 10% Pohang zeolite was $105\;g/m^2$. Moisture adsorption contents of panel with porous materials were higher than that of panel without porous materials.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1997년도 봄 학술발표회 논문집
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• pp.179-186
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• 1997

• 한국산업융합학회 논문집
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• 제27권4_2호
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• pp.981-989
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• 2024

In recent years, there has been a growing focus on preserving the global environment and utilizing resources efficiently. The significance of energy conservation has led to the development of systems that recycle waste heat from factories and use eco-friendly refrigerants. This study aims to enhance the performance of adsorption-desorption systems using thermoelectric devices, which are known for their ability to convert temperature differences into electrical energy. The research focuses on improving the efficiency of these systems by integrating thermoelectric modules to cool the adsorption side and heat the desorption side, thus enhancing overall system performance. The experiments utilized a typical thermoelectric device and silica gel as the adsorbent. Key experimental parameters included varying the inlet air temperature and relative humidity on the desorption side. The results indicated that increasing the relative humidity of the inlet air on the desorption side significantly enhanced the overall mass transfer coefficient while reducing the completion time of the process. Similarly, higher inlet air temperatures led to an increase in the mass transfer coefficient and a decrease in process completion time. These findings suggest that optimizing the operational conditions of thermoelectric devices can substantially improve the performance of adsorption-desorption systems, offering potential benefits for applications in ventilation systems and other related fields.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.15-20
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• 1994

The adsorption model in reversed phase liquid chromatography has been critically examined. It has been found that use of the Everett type surface activity coefficient for the solute in the stationary phase is not useful to study the retention characteristics of a nonpolar solute. We suggest a modified model. In this model it is assumed that the displaced modifier molecules from the surface monolayer do not transfer into the bulk mobile phase but stick to the nonpolar solute which has displaced them. In addition, we prefer to use an apparent stationary phase activity coefficient of the soluie instead of the Everett type activity coefficient. This modified adsorption model well explains the mobile and stationary phase effects on the solute retention upon variation of mobile phase composition.

• 청정기술
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• 제14권1호
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• pp.47-52
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• 2008

흡착공정의 흡착속도를 표현하는 여러 가지 물질전달 모델들 가운데, 식의 형태가 비교적 간단한 선형추진력(Linear Driving Force, LDF) 모델이 많이 사용된다. 본 연구에서는 벤젠을 분리 및 제거하기 위한 실제 흡착공정에서 이 물질전달모델의 적용가능성을 알아보고자 하였다. LDF모델에 의한 전산모사 결과와 동적실험에서 구한 실험 값을 비교함으로써 흡착공정의 물질전달 계수를 구하였다. 여러 다른 값의 온도 및 압력에서 얻은 파과곡선을 이용하여 물질전달계수의 온도 및 압력에 대한 의존관계를 알아보았다. 물질전달계수의 온도와 압력에 대한 의존성은 각각, 아레니우스함수와 지수함수 형태의 경험식으로 표현할 수 있었다.

• Environmental Engineering Research
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• 제25권1호
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• pp.96-103
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• 2020

The aim of this study is to investigate the effect of five different combinations including: sand 70%, bentonite 30% (S₇₀B₃₀)- sand 80%, bentonite 20% (S₈₀B₂₀)- sand 80%, organophilic 20% (S₈₀M₂₀)- sand 60%, bentonite 20%, organophilic 20% (S₆₀B₃₀M₂₀) and sand 75% - bentonite 15% - organophilic 10% (S₇₅B₁₅M₁₀) on landfill linear structure in order to decrease phenol leaching. Hydraulic conductivity and adsorption behavior of the samples were investigated. The results demonstrated that the lowest hydraulic conductivity coefficient ($1.16{\times}10^{-11}{\frac{m}{s}}$) was obtained for S₇₀B₃₀. Furthermore, adding more than 20% of bentonite had no significant effect on reducing permeability. Moreover, Freundlich isotherm was introduced as the best model explaining adsorption behaviour due to its highest determination coefficient (0.945). The best samples for adsorption capacity of phenol and for both permeability and adsorption are S₈₀M₂₀ and S₆₀B₃₀M₂₀, respectively. Although the presence of bentonite was effective in reducing hydraulic conductivity, organic clay had no considerable impact on reducing permeability. Though, it's an exceptional role in adsorbing organic contaminants including phenol cannot be ignored. To meet all regulatory constraints, the optimal compound is made up of 10.2% of bentonite and 2.8% of organophilic clays with a minimized cost of 13.64 ($/ton).