• Analytical Science and Technology
• /
• v.12 no.6
• /
• pp.465-471
• /
• 1999

Chloromethylated polystyrene resins supported diethylenetriamine of linear and claw types have been prepared by the reaction of diethylenetriamine with chloromethylated polystyrene. The kinetics of adsorption of transition metal ions on polystyrene resins were measured by the limited-bath technique. This paper reports the results of the diffusion coefficients, entropies of activation, and free energies of activation. The ratedetermining step of the adsorption of transition metals on the resins is a process of diffusion through the particles.

• Korean Journal of Food Science and Technology
• /
• v.22 no.2
• /
• pp.227-228
• /
• 1990

The cooking properties of waxy rice, Olchal (Japonica type) and Hangang-chalbyeo $(J{\times}\;Indica\;type)$, were studied. The values of cooking rate constant of Hanganchalbyeo were higher than those of Olchal. However, the activation energies were essentially the same. The activation energy for cooking at $80-100^{\circ}C$ was about 1.6 times greater than at $100-120^{\circ}C$. The Z-value and $Q_{10}$ calculated from the terminal point of cooking were also similar between waxy rices.

• Journal of Powder Materials
• /
• v.6 no.3
• /
• pp.209-214
• /
• 1999

The oxidation behavior of the simulated spent fuel of burn up 33 MWD/kgU was investigated to predict that of the spent fuel in the temperature ranges of 400 to $700^{\circ}C$ and was compared with those of $UO_2$. The forms of uranium oxides after the oxidation were conformed by XRD analyses. The oxidation rate at each the temperature and the activation energy were obtained. After complete oxidation, the simulated spent fuel was converted to $U_3O_8$ and pulverized to powder due to the density difference between the simulated spent fuel and uranium oxides. The activation energies were 85.35 and 30.77kJ/mol in the temperature ranges of 400$\leq$T($^{\circ}C$)$\leq$500 and 500$\leq$T($^{\circ}C$)$\leq$700, respectively.

• Journal of Powder Materials
• /
• v.16 no.3
• /
• pp.167-172
• /
• 2009

This study has been carried out to investigate the non-isothermal behaviors and kinetic parameter of calcium carbonate by different thermal analysis methods. At the heating rate of $10^{\circ}C$/min, the onset calcination temperature, the peak and final temperatures of calcium carbonate were $612^{\circ}C$, $748^{\circ}C$, and $890^{\circ}C$ respectively. As the heating rate of the calcium carbonate increased from $5^{\circ}C$/min to $20^{\circ}C$/min, the peak temperature increased from $719^{\circ}C$ to $782^{\circ}C$. The activation energies of the calcium carbonate calculated by the methods of Kissinger and Freeman-Carroll were 40.15 kcal/mol and 43.47 kcal/mol, respectively.

• Journal of radiological science and technology
• /
• v.21 no.2
• /
• pp.47-52
• /
• 1998

Tissue-equivalent $MgB_4O_7$ TL phosphors were prepared and the effects of Lantanides series activators on TLD properties of the phosphors were studied. The glow curve of TLD increased TL intensity and the peak temperature is low that is, the heating rate is $10^{\circ}C/sec$. The activation energy of the main peak estimated by the peak shape method. By these methods, the estimated activation energies were $0.76{\sim}1.55eV$ respectively. The TL phosphors prepared in this work may be utilized to radiation sensor elements because of this high sensitivity to X-ray.

• Nuclear Engineering and Technology
• /
• v.41 no.8
• /
• pp.1073-1078
• /
• 2009

A kinetic model for the oxidation of a $UO_2$ pellet to $U_3O_8$ powder has been suggested by considering the mass transfer and the diffusion of oxygen molecules. The kinetic parameters were estimated by a fitting of the experimental data. The activation energies for the chemical reaction and the product layer diffusion were calculated from the kinetic model. The oxidation conversion of a $UO_2$ pellet was simulated at various operating conditions. The suggested model explains the oxidation behavior of $UO_2$ well.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2001.04a
• /
• pp.53-56
• /
• 2001

The degradation of tetrachloroethene (PCE) and trichloroethene (TCE) by vitamin B$_{12}$, an electron mediator was examined when zero valent metals (ZVMs) were used as built electron donors. Dechlorination of PCE and TCE by iron and zinc in the presence of vitamin B$_{12}$ showed that the zinc and vitamin B$_{12}$ combination greatly enhances the reaction rates for both PCE and TCE, but iron and vitamin B$_{12}$ result in an increase in reactivity only for PCE degradation, not for TCE degradation in comparing with meta]s only. This result indicates vitamin B$_{12}$(I) Is active towards both PCE and TCE degradation while vitamin B$_{12}$(II) is active towards both PCE. Calculated activation energies for the dechlorination of PCE in the presence of Vitamin B$_{12}$ showed that vitamin B$_{12}$ lowered the activation energy about 40-60 kJ/㏖ for the both metals.the both metals.

• Journal of the Korean Ceramic Society
• /
• v.31 no.12
• /
• pp.1545-1551
• /
• 1994

Various kinetic parameters of the nucleation and crystallization in anorthite glass (CaO.Al2O3.2SiO2) were calculated by nonisothermal differential thermal analysis. Base glass and glass with TiO2 were prepared by melting. In base glass, the temperature where nucleation can occur ranges from 85$0^{\circ}C$ to 9$25^{\circ}C$ and the temperature for maximum nucleation was 900$\pm$5$^{\circ}C$. In glass with TiO2, the nucleation temperature range was 800~875$^{\circ}C$ and the maximum nucleation temperature was 850$\pm$5$^{\circ}C$. Kissinger equation, Bansal equation, and modified Ozawa equation were used for calculating activation energy for crystallization, Ec. The results showed the same activation energies for both glasses with and without TiO2 in the different equations. The shape of maximum exotherm peak and Ozawa equation were used for Avrami exponent, n. The n value for each glass was 2, indicating that each glass crystallized primarily by bulk crystallization.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2002.10a
• /
• pp.273-275
• /
• 2002

In this studies, curing behavior and mechanical properties of tetrafunctional epoxy resin (4EP)/ fluorine-containing epoxy resin (FEP) blend systems was investigated with 4, 4'-diaminodiphenol methane (DDM) as a curing agent. The cure activation energies $(E_a)$) were studied by Flynn-Wall-Ozawa's equation with dynamic DSC method. For the fracture toughness of the casting specimens, the critical stress intensity factor ($K_{IC}$) and the specific fracture energy ($G_{IC}$) were determined by fracture toughness test.

• Journal of the Korean Chemical Society
• /
• v.16 no.5
• /
• pp.284-289
• /
• 1972

Rates of the reactions of m-and p-ring-substituted thiobenzamides with benzyl bromide in acetone have been determined by an electric conductivity method. The Hammett rule has been adopted for these reactions. It has been observed that an electron-attracting substituent accelerates the reaction while an electron-donating substituent retards the reaction, and a mechanism which accounts for the observed kinetics has been postulated. The activation energies and entropies of activation for these reactions have also been calculated.