• 소성∙가공
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• 제21권2호
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• pp.101-106
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• 2012

Generally, rapid cure reaction of LED encapsulation silicone resin causes serious defects in cured resin products such as warpage, residual bubbles, and reduced wettablility. In order to prevent residual bubbles in silicone resin, the step cure process was examined in the present paper. Three kinds of step cure processes were applied, and bubble-free phenomenon was observed. Most of the bubbles were removed under $70^{\circ}C$, the minimum temperature for activating cure reaction. In addition, degree of cure(DOC) and temperature distribution were predicted by using FEM analysis of heat transfer. It was concluded that maintaining cure temperature which provide a DOC under 0.5~0.6 effectively reduces residual bubbles.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.113-114
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• 2008

Conventional furnace annealing (CFA) for activating Mg-doped p-type GaN films had been performed in pure $N_2$ ambient. All sample activated the same gas ambient. The annealing process change temperature: the first process is performed at $550^{\circ}C$ for 10 min. but, the first process is the same bulk. From second to five process increase activation temperature to change $50^{\circ}C$ and annealing time keeping for 10 min. It is found that the samples characteristic measure hall measurement. Similar results were also evidenced by photoluminescence (PL) measurement.

• Carbon letters
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• 제2권2호
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• pp.105-108
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• 2001

In this work, the activated carbons (ACs) with high micropores were synthesized from the polystyrene (PS) with KOH as activating agent. And the influence of activation temperature on porosity of the ACs studied was investigated. The porous structures of ACs were characterized by nitrogen adsorption at 77K using BET and D-R equations, and MP and BJH methods. The weight loss behaviors of the samples impregnated with KOH were also monitored using thermogravimetric analyzer (TGA). As a result, it was found that the samples could be successfully converted into ACs with well-developed micropores. From the results of pore size analysis, it was confirmed that elevated activation temperature does lead to the formation and deepening of microstructures without significant change in mesostructures. A thermogravimetric study showed that KOH could suppress the thermal decomposition of the sample, resulting in the increase of carbon yields.

• Macromolecular Research
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• 제17권2호
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• pp.116-120
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• 2009

The cellulose smart material called electro-active paper (EAPap) is made by regenerating cellulose. However, the actuator performance is degraded at low humidity levels. To solve this drawback, EAPap bending actuators were made by activating wet cellulose films in three different room-temperature ionic liquids: l-butyl-3-methylimidazolium hexaflurophosphate ($BMIPF_6$), 1-butyl-3-methylimidazolium chloride (BMICL) and 1-butyl-3-methylimidazolium tetrafluroborate ($BMIBF_4$). In the results, the actuator performance was dependent on the type of anions in the ionic liquids, in the order of $BF_4$>Cl>$PF_6$. The BMIBF 4-activated actuator showed the maximum displacement of 3.8 mm with low electrical power consumption at relatively low humidity. However, the BMICL-activated actuator showed a slight degradation of actuator performance. Further performance and durability improvement will be possible once various ionic liquids are blended with cellulose.

• Molecules and Cells
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• 제21권2호
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• pp.251-260
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• 2006

During mitosis, genomic integrity is maintained by the proper coordination of anaphase entry and mitotic exit via mitotic checkpoints. In budding yeast, mitotic exit is controlled by a regulatory cascade called the mitotic exit network (MEN). The MEN is regulated by a small GTPase, Tem1p, which in turn is controlled by a two-component GAP, Bfa1p-Bub2p. Recent results suggested that phosphorylation of Bfa1p by the polorelated kinase Cdc5p is also required for triggering mitotic exit, since it decreases the GAP activity of Bfa1p-Bub2p. However, the dispensability of GEF Lte1p for mitotic exit has raised questions about regulation of the MEN by the GTPase activity of Tem1p. We isolated a Bfa1p mutant, $Bfa1p^{E438K}$, whose overexpression only partially induced anaphase arrest. The molecular and biochemical functions of $Bfa1p^{E438K}$ are similar to those of wild type Bfa1p, except for decreased GAP activity. Interestingly, in $BFA1^{E438K}$ cells, the MEN could be regulated with nearly wild type kinetics at physiological temperature, as well as in response to various checkpoint-activating signals, but the cells were more sensitive to spindle damage than wild type. These results suggest that the GAP activity of Bfa1p-Bub2p is responsible for the mitotic arrest caused by spindle damage and Bfa1p overproduction. In addition, the viability of cdc5-2 ${\Delta}bfa1 $ cells was not reduced by $BFA1^{E438K}$, suggesting that Cdc5p also regulates Bfa1p to activate mitotic exit by other mechanism(s), besides phosphorylation.

• 대한화학회지
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• 제46권3호
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• pp.233-240
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• 2002

본 연구에서는 잠재성 양이온 개시제 (N-benzyl pyrazinium hexafluoroantiminate, BPH)를 이용한 에폭시/폴리우레탄 블랜드계의 혼합조성에 따른 경화거동과 유변학적 특성 그리고 기계적 물성 변화에 대하여 연구하였다. 블랜드계의 반응성은 DSC를 이용하여 반응 온도에 따른 전환률을 구하여 측정하였으며, 유변학적 특성은 레오미터를 이용한 등온 실험을 통하여 측정하였고, 가교 활성화에너지(Ec)는 겔화 시간과 경화 온도를 이용하여 Arrhenius 방정식으로 구하였다. 한편, 경화된 시편의 기계적 물성은 충격강도 실험을 통하여 측정하였다. 실험결과, 블랜드계의 열잠재성 촉매로 사용된 BPH는 어떤 공개시제 없이도 우수한 촉매 특성을 나타내었다. 본 블랜드계의 가교 활성화에너지 및 충격강도는 PU가 30 wt% 첨가되었을 때 최대를 나타내었는데, 이는 EP와 PU간의 수소결합으로 인한 치밀한 가교밀도의 증가 때문이라고 사료된다.

• Carbon letters
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• 제8권1호
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• pp.30-36
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• 2007

Oxidized PAN (OXI-PAN) fibers were used for the precursors of activated carbon fiber in study. How drying temperature affected the properties of carbon fibers on activating process of carbon fibers was investigated. The specific surface areas of activated carbon fibers have been determined on a series of chemically activated carbons with KOH and NaOH. The experimental data showed variations in specific surface area, iodine and silver adsorptions by the activated carbon fibers. The amount of iodine adsorption increases with increasing specific surface areas in both activation methods. This was because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers. Silver adsorbed well in NaOH activated carbon fibers rather than KOH activated carbon fibers in this study.

• KIEAE Journal
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• 제15권4호
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• pp.29-35
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• 2015

Purpose: Double skin facade is a representative advantageous passive technology of building skin in the aspect of energy saving and environment improvement, reduces heat loss with buffer space in winter season and enhances indoor air and comfort of residents by activating natural ventilation in mid-season. However, in summer season, temperature increase in the intermediate space due to solar energy from exterior transparent skin could be a potential problem; also, relatively weak buoyancy of air caused by low density difference between double-skin facade could increase cooling load as air of intermediate space in high temperature hangs. However, proof data is insufficient to objectify such phenomenon. Method: In this study, researchers surveyed air temperature of intermediate space and airflow and diagnosed its cause targeting on applied multistory facade in the building which gives thermal uncomfort to residents. Also, the researchers produced Solar-air heat transfer coefficient meter, measured thermal boundary condition of double-skin facade, and presented the result of measurement as an objectified verification material regarding overheating phenomenon in the intermediate space of double-skin facade in summer season. Result: Inefficient condition was verified that total heat increases and overheating due to insufficient natural ventilation in multistory facade. In addition, logic behind preceding research was objectified and verified regarding high temperature phenomenon in the intermediate space which could increase cooling load in summer season.

• Nuclear Engineering and Technology
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• 제51권6호
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• pp.1532-1539
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• 2019

This paper analyzes a new method for reducing boiling water reactor fuel temperature during a Loss of Coolant Accident (LOCA). The method uses a device called Reverse Flow Restriction Device (RFRD) at the inlet of fuel bundles in the core to prevent coolant loss from the bundle inlet due to the reverse flow after a large break in the recirculation loop. The device allows for flow in the forward direction which occurs during normal operation, while after the break, the RFRD device changes its status to prevent reverse flow. In this paper, a detailed simulation of LOCA has been carried out using the U.S. NRC's TRACE code to investigate the effect of RFRD on the flow rate as well as peak clad temperature of BWR fuel bundles during three different LOCA scenarios: small break LOCA (25% LOCA), large break LOCA (100% LOCA), and double-ended guillotine break (200% LOCA). The results demonstrated that the device could substantially block flow reversal in fuel bundles during LOCA, allowing for coolant to remain in the core during the coolant blowdown phase. The device can retain additional cooling water after activating the emergency systems, which maintains the peak clad temperature at lower levels. Moreover, the RFRD achieved the reflood phase (when the saturation temperature of the clad is restored) earlier than without the RFRD.

• Carbon letters
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• 제9권3호
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• pp.203-209
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• 2008

The objective of this work is to study the feasibility of the preparation of the activated carbon (AC) from coconut tree flowers using high temperature fluidized bed reactor (HTFBR). The activating agent used in this work is steam. The reactor was operated at various activation temperature (650, 700, 750, 800 and $850^{\circ}C$) and activation time (30, 60, 120 and 240 min) for the production of AC from coconut tree flowers. Effect of activation time and activation temperature on the quality of the AC preparation was observed. Prepared AC was characterized in-terms of iodine number, methylene blue number, methyl violet number, ethylene glycol mono ethyl ether (EGME) surface area and SEM photographs. The best quality of AC from coconut tree flowers (CFC) was obtained at an activation temperature and time of $850^{\circ}C$ and 1 hr restectively. The effectiveness of carbon prepared from coconut tree flowers in adsorbing crystal violet from aqueous solution has been studied as a function of agitation time, carbon dosage, and pH. The adsorption of crystal violet onto AC followed second order kinetic model. Adsorption data were modeled using both Langmuir and Freundlich classical adsorption isotherms. The adsorption capacity $q_m$ was 277.78 mg/g., equilibrium time was found to be 180 min. This adsorbent from coconut tree flowers was found to be effective for the removal of CV dye.