• KCI Concrete Journal
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• 제13권1호
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• pp.3-9
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• 2001

This research concerns the effect of kaolin as material of cement admixture. which has the advantage of low price and high adaptability. Kaolin, a kind of soil, is well known as a raw material of pottery. which is widely scat-tered on the earth (especially in Korea). This research shows the method and process for activating kaolin to have the properties of a cement admixture through experiment. In the experiments, kaolin is baked in high temperature and then cooled suddenly to be activated. The temperature zone and time span, on which kaolin is activated are examined. The research looks over the effect of the activated kaolin based on several criteria regarding to chemical and physical characteristic of general admixtures. The results of this research are as follows; kaolin start activation at the temperature above 50$0^{\circ}C$ and make ends of activation at the temperature below 95$0^{\circ}C$ and there was little effect by the change of duration. It is concluded that compressive strength can be increased by putting activated kaolin in the concrete and the activated kaolin is good for water resistance and anti-chemical , and that it is effective for protecting the leakage of hazardous article like Cl- and for protecting damage by an organic salt like acid. The activated kaolin of proper temperature and time is effective in compressive strength, salt resistance and acid resistance. The adaptability of activated kaolin as a cement admixture was shown through this research.

• 설비공학논문집
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• 제15권10호
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• pp.821-827
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• 2003

Reduced-scale experimental study was carried out on the heat flow behavior which flows under the sloped ceiling in underground fire. Temperature and flow velocity were measured to characterize the ceiling jet along the sloped stairway ceiling. The methanol fuel was used as a model fire source giving 2.2 and 3.4 kW, with changing the slope angle of stairway adopting of 15, 25, 35, and 45 deg. Based on the experimental data, excess temperature and velocity along the sloped stairway ceiling were examined which are usefully applicable to estimate the activating conditions of heat detector and sprinkler head mounted on the sloped ceiling. Excess temperature in upper exit of the sloped stairway was also examined to analyze the soffit which delays the smoke diffusion. The result shows that the activating conditions of heat detector and sprinkler in the sloped stairway ceiling have to be considered differently in a point of about 30 deg.

• 자원리싸이클링
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• 제12권3호
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• pp.13-24
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• 2003

폐호도껍질을 원료로 활성탄을 제조하는 과정에서 활성화 온도, 활성화 시간, 활성화제의 양, 그리고 활성화제의 종류 등을 변수로 하여 활성화 특성을 조사하였다. 인산을 활성화제로 사용하여 제조된 활성탄은 그 흡착능이 온도가 증가함에 따라 증가하여 약 $550^{\circ}C$부근에서 최대 흡착능을 보였으며 그 수율은 온도 상승에 따라 지속적으로 감소하였다. 활성화 시간은 약 2시간 정도에서 최적의 조건을 보였으며 시간이 증가함에 따라 활성탄의 수율은 계속 감소하였다. 활성화제의 농도 증가에 따라 수율은 지속적으로 상승하였으며 흡착능 또한 증대되다가 약 1.5M $H_3PO_4$ 이상의 조건에서는 오히려 흡착능이 감소하였다. SEM으로 관찰한 조건에 따른 활성탄의 미세구조의 변화는 조건별 흡착능의 변화와 잘 일치되었으며 활성화제의 종류는 활성화 과정에서 중요한 영향을 미치는 것으로 조사되었다. 제조된 활성탄의 흡착특성을 파악하기 위해 $Cu^{2+}$ 이온을 흡착질로 하여 흡착반응을 조사한 결과, 흡착반응은 전체적으로 2차식을 따르는 것으로 관찰되었으며 흡착질의 초기 농도가 감소함에 따라 반응상수는 점차 증가하였다. 평형흡착량은 Freundlich Model 을 잘 따르는 것으로 나타났으며 온도별 흡착반응을 검토한 결과, 중금속 이온의 흡착은 흡열반응의 특성을 나타내었다. 흡착에 따른 Activation Energy는 약 13.07kcal/mol로 산출되었으며 van't Hoff Equation을 이용하여 흡착반응의 열역학적 인자들을 계산하였다.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.76-81
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• 2002

The dramatic increase in the depth of a weld bead penetration has been demonstrated by welding a stainless steel in GTA (Gas-Tungsten-Arc) process with activating flux which consists of oxides and halides. However, there is no commonly agreed mechanism fer the effect of flux on the process. In order to make clear the mechanism, each behavior of the arc md the weld pool in GTA process with activating flux is observed in comparison with a conventional GTA process. A constricted anode root is shown in GTA process with the activating flux, whereas a diffuse anode root is shown in the conventional process. These anode roots are related strongly to metal vapor from the weld pool and the metal vapor is also related to temperature distributions on the weld pool surface. Furthermore, it is suggested that a balance between the Marangoni force and the drag force of the cathode jet should dominate the direction of re-circulatory flow in the weld pool. The electromagnetic force encourages the inward re-circulatory flow due to the constricted anode root in the case with flux. The difference in flow direction in the weld pool changes the geometry or depth/width ratio of weld bead penetration.

• 자원리싸이클링
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• 제15권2호
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• pp.50-57
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• 2006

해양에서 발생하는 목질 폐기물의 재활용 방안의 일환으로 폐 어류 상자를 원료로 활성탄을 제조하는 방안을 검토하였다. 폐 황산을 활성화제로 하여 온도에 따른 활성탄의 흡착능의 변화를 검토한 결과 실험조건에서 $650^{\circ}C$부근에서 최대의 흡착능이 관찰되었으며 이보다 온도가 상승할 경우 열적 분해로 인해 흡착능이 감소하는 것으로 나타났다. 활성시간은 약 120분 정도가 적절한 것으로 파악되었으며 $550^{\circ}C$ 및 60분의 활성화 조건에서 원료 물질과 활성화제의 무게비가 1:3의 조건일 때 최대 흡착능이 관찰되었다. 활성화 조건은 황산의 농도가 1.2M일 때 최적인 것으로 조사되었으며 활성화제의 종류에 따른 활성능을 비교한 결과 황산은 질산에 비해 활성탄의 흡착능면에 있어서는 그 효과가 더욱 큰 것으로 파악되었으나 수율에 미치는 영향은 두 경우 뚜렷한 차이가 없는 것으로 나타났다. 제조된 활성탄은 중성 영역에서 분산도가 높은 것으로 관찰되었으며 전 pH 영역에 걸쳐 음의 전하를 띠는 것으로 파악되어 금속 이온 함유 폐수에 효과적인 흡착제로 사용될 수 있을 것으로 사료되었다.

• Journal of Forest and Environmental Science
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• 제23권1호
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• pp.51-55
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• 2007

본 연구는 염화아연을 이용한 화학약품 부활법으로 잣나무재 활성탄을 제조하기 위해 원료에 대한 화학약품부활제 비율의 영향을 검토하였다. 염화아연과 혼합한 목분은 질소분위기에서 상온에서 $600^{\circ}C$까지 1시간 열처리하여 중량변화를 측정하였다. 이 처리과정에 있어 활성탄 내부에 다양한 공극크기 분포와 표면특성이 확인되었다. 즉, 최대 BET 표면적과 총 공극체적은 목분에 대하여 염화아연의 비율이 5배인 경우였으며, 각각 그 값은 $1468m^2/g$와 1.74 cc/g이었다. 결론적으로 활성탄 제조시 화학약품부활제의 비율에 의해 활성탄의 특성이 뚜렷하게 차이가 나타나는 것이 확인되었다.

• 콘크리트학회지
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• 제9권2호
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• pp.121-132
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• 1997

콘크리트의 열해석은 콘크리트 초기온도, 환경조건 및 시멘트의 수화 등에 의해 특징지워진다. 이러한 상호관계를 모두 고려한 프로그램을 만들어서, 콘크리트재료의 열특성과 환경조건을 감안한 콘크리트 구조물의 온도해석을 하였다. 시멘트 수화의 특성으로는 활성화에너지, 단위열량, 수화열이 있으며 이러한 인자들에 의해 콘크리트의 내부열 발생이 영향을 받는다. 본 연구에서는 활성화에너지와 수화열을 상대강도-등가재령모델에 의해 구했으며, 단위열량은 등온열량측정법에 의해 실험적으로 구하였다. 또한 콘크리트 구조물의 온도분포를 실험적으로 구하여 수치해석모델과 비교하였다. 먼저 위에서 제시된 모든 조건들에 대한 parametric 해석을 실시하여 프로그램의 신뢰성을 확보하였다. 그리고 원주형시편을 만들어서 온도분포 및 변화를 측정하여 수치해석에 의해 예측된 온도분포와 비교하였다.

• 한국도로학회논문집
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• 제15권2호
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• pp.95-103
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• 2013

PURPOSES : To investigate the fundamental characteristics of blast-furnace slag mortar that was hardened with activating chemicals to capture and sequester carbon dioxide. METHODS : Various mix proportions were considered to find an appropriate stregnth development in regards with various dosages of activating chemicals, calcium hydroxides and sodium silicates, and curing conditions, air-dried, wet and underwater conditions. Flow characteristics was investigated and setting time of the mortar was measured. At different ages of 3, 7 and 28days, strength development was investigated for all the mix variables. At each age, samples were analyzed with XRD. RESULTS : The measured flow values showed the mortar lost its flowability as the activating chemicals amount increased in the scale of mole concentration. The setting time of the mortar was relatively shorter than OPC mortar but the initial curing condition was important, such as temperature. The amount of activating chemicals was found not to be critical in the sense of setting time. The strength increased with the increased amount of chemicals. The XRD analysis results showed that portlandite peaks reduced and clacite increased as the age increased. This may mean the $Ca(OH)_2$ keeps absorbing $CO_2$ in the air during curing period. CONCLUSIONS : The carbon capturing and sequestering activated blast-furnace slag mortar showed successful strength gain to be used for road system materials and its carbon absorbing property was verified though XRD analysis.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.143-150
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• 1997

The maturity concept was adopted to predict the strength of concrete, which was subjected to same temperature conditions and variable curing conditions. Penetration test and compressive test were conducted to measure the initial and final setting time and the compressible strength of concrete specimen, respectively. Also, the temperature and time were recorded at some intervals of time for calculating the maturity. The initial and final setting were delayed as the w/c ratio increased and curing temperature decreased. The activating energy decreased as the w/c ratio increased. The relationships at the relative strength and the maturity were proposed at different w/c ratio for the same temperature curing condition, and these were applied for the variable curing conditions. The results indicated that the difference between the strength of the proposed and the specimen was big at 1 days's age but quite similar after 3 day's age.

• Carbon letters
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• 제4권3호
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• pp.126-132
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• 2003

Granular Activated Carbon (GAC) has been proven to be an excellent material for many industrial applications. A systematic study has been carried out of the kinetics of physical as well as chemical activation of phenolic resin chars. Physical activation was carried out using $CO_2$ and chemical activation using KOH as activating agent. There are number of factors which influence the rate of activation. The activation temperature and residence time at HTT varied in the range $550{\sim}1000^{\circ}C$ and $\frac{1}{2}{\sim}8$ hrs respectively. Kinetic studies show that the rate of chemical activation is 10 times faster than physical activation even at much lower temperature. Above study show that the chemical activation process is suitable to prepare granular activated carbon with very high surface area i.e.$ 2895\;m^2/g$ in short duration of time i.e. 1 to 2 hrs at lower temperature i.e. $750^{\circ}C$ from phenolic resins.