• Korea-Australia Rheology Journal
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• v.13 no.3
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• pp.125-130
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• 2001

Block copolymers of PC-b-PMMA (polycarbonate-b-polymethylmethacrylate) and PC -b-SAN (polycarbonate-b-(styrene-c-acrylonitrile)), were examined as compatibilizers for blonds of PC with SAN copolymer. The average diameter of the dispersed particles was measured with an image analyser, and the interfacial properties of the blonds were analysed with an imbedded fiber retraction (IFR) technique. The average diameter of dispersed particles and interfacial tension of the PC/SAN blends reached a minimum value when the SAN copolymer contained about 24 wt% AN. Interfacial tension and particle size were further reduced by adding compatibilizer to the PC/SAN blends. PC-b-PMMA was more effective than PC-b-SAN as a compatibilizer in reducing the average diameter of the dispersed particles and interfacial tension of PC/SAN blend. A direct proportionality between the particle diameter and interfacial tension was also observed. The interfacial properties of the PC/SAN blends were optimized by adding a block copolymer and using an SAN copolymer that had minimum interaction energy with PC.

• Journal of the Korean Society for Precision Engineering
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• v.16 no.10
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• pp.59-67
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• 1999

The lead time for new products is very limited in the current manufacturing processes, therefore the Rapid Prototyping process has been introduced and generally used in the industry. Fused Deposition Manufacturing (FDM) is one of the most common methods in this field. In the FDM process, the patterns are made of Wax of ABS and ABS shows better quality of the patterns. To date, the FDM/ABS patterns are used in investment casting for making silicon moulds to produce was patterns because it is very difficult to dewax FDM/ABS directly. The aim of this paper was to propose a feasibility of using FDM/ABS parts as wax-pattern substitutes in the investment casting process. The effects of casting conditions, such as pre-heat temperature and casting temperature, are provided. Comparisons with the conventional investment casting processes using the wax-patterns under the same prototype are made. Lead-time and saving cost are discussed in using FDM/ABS parts as was-pattern substitutes compared with the products from other rapid prototype systems.

• Journal of the Korean Wood Science and Technology
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• v.25 no.1
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• pp.56-64
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• 1997

Since there are three hydroxyl groups on each anhydroglucose ring of the cellulose, the renewable resources, we can get various functional papers by the chemical modification of cellulose. The reaction involving the introduction of the ${\beta}$-cyanoethyl ($-CH_2-CH_2$-CN) group into organic substances containing reactive hydrogen atoms is known as cyanoethylation. Cellulose reacts with acrylonitrile in the presence of strong alkalis in a typical manner of primary and secondary alcohols to form cyanoethyl ethers. In cyanoethylation, important factors of reaction are temperature, concentration of the NaOH, and addition rate of acrylronitrile. FT-IR spectra of cyanoethyl group was confirmed at $2250cm^{-1}$, which corresponds the introduction of aliphatic nitrile group. Effect of cyanoethyl DS(degree of substitution) on strength properties was resulted that cyanoethylated BKP of DS 0.04 appeared to be the best choice for overall strength properties. Also, excellent thermal stability in aging characteristics was obtained.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.6
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• pp.50-55
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• 2014

An oxidized starch was modified for surface sizing via etherification and esterification. Propylene oxide (PO), sodium monochloroacetate (SMCA), and acrylonitrile (AN) were used as etherification, and vinyl acetate monomer (VAM), maleic anhydride (MA), fumaric acid (FA), and itaconic acid (ITA) were used for esterification. Esterification and etherification of starch decreased both Brookfield viscosity and Brabender viscosity substantially even though the solids level was increased by 2% from 14 to 16%. Surface sizing performance of starches in tensile strength, stiffness and compressive strength was improved by esterification and etherification of the oxidized starch. Especially, SMCA etherification was found to be the most effective modification method.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.973-978
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• 1997

The toughness and morphology of epoxy resin based on diglycidyl ether of bisphenol A(DGEBA) cured with of tris (dimethylaminomethy]) phenol(DMP-30) and castor oil (CO) as a toughening modifier have been studied. Mixtures of CO and an epoxy resin showed a higher miscibility than the classical CTBN modified epoxy resin. The glass transition temperature($T_g$) was decreased with the CO content and the cure temperature. It is interpreted that the networks of epoxy matrix obtained at high temperature are apparently looser and more flexible due to the lower crosslinking density. The toughness was slightly increased with the CO content at $40^{\circ}C$ of curing temperature. The toughness increased with increasing the cure temperature and CO content.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.2
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• pp.103-107
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• 2004

This paper was studied the properties of materials for treatment of anionic chromate$(CrO4^{-2})$ in industrial wastewater. Ion exchange fiber, poly(acryloamidino diethylene diamine) with ion exchange and adsorption was prepared PAN fiber and diethylenetriamine under $AlC1_3$ catalyst at $120^\circ{C}$ and was analyzed $^{{13}/C-NMR$}$ and FT-IR spectroscopy. The maximum adsorption and the coordination of chromate on chelating fiber were analyzed FT-IR spectra. We proposed the coordination structure with inter/intramolecular bond.

• Applied Chemistry for Engineering
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• v.7 no.4
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• pp.757-767
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• 1996

Poly(alkyl acrylate-g-caprolactone) graft copolymers were prepared, and they were applied as compatibilizing agents for polycarbonate (PC) / poly(acrylonitrile-butadiene-styrene) (ABS) blends. The incompatible poly(alkyl acrylate) segment was incorporated into the graft copolymer in order to localize the copolymer at the PC/ABS interface. The blend containing 1 phr of the copolymer showed remarkable improvement in impact strength as well as in elongation at break. Impact improvement was more pronounced with a thinner test specimens of 1/8 inch thickness. Morphological study showed that the presence of the graft copolymer led to a smoother PC/ABS interface due to the interfacial enrichment of the graft copolymer.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.113-124
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• 1993

Thermogravimetric analysis of copolymer of acrylonitrile(95%) and methyl acrylate(5%) have been carried out to investigate the activation under $H_2O$(30%) -$N_2$atmosphere at various heating rates. The kinetic equation [$f=1-\exp(-a{\Delta}T)^b$] which was derived on the basis of the nonisothermal activation process of carbon fiber in the $H_2O$(30%)-$N_2$system showed good agreement with experimetal results. The pore volume upon conversion was in good agreement with the model of theoretical pore volume. The pore structures of the activated carbon fiber were influenced by the heating rate, activation temperature and internal-external conversions.

• Proceedings of the Korean Reliability Society Conference
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• 2004.07a
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• pp.303-311
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• 2004

This paper presents the reliability estimation of door hinge for home appliances, which consists of bushing and shaft. The predominant failure mechanism of bushing made of polyoxymethylene(POM) is brittle fracture due to decrease of strength caused by voids existing, and that of shaft made of acrylonitrile-butadiene-styrene(ABS) is creep due to plastic deformation caused by excessive temperature and lowering of glass transition temperature by absorbed moisture. Since the brittle fracture of bushing is overstress failure mechanism, the load-strength interference model is used to estimate the failure rate of it along with failure analysis. By the way, the creep of shaft is wearout failure mechanism, and an accelerated life test is then planned and implemented to estimate its lifetime. Through the technical review about failure mechanism, temperature and humidity are selected as accelerating variables. Assuming Weibull lifetime distribution and Eyring model, the life-stress relationship and acceleration factor, B$_{10}$ life and its lower bound with 90% confidence at worst case use condition are estimated by analyzing the accelerated life test data.a.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.04a
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• pp.89-92
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• 1998

1. Introduction : Among many azeotropic compounds, pyridine which forms an azeotropic mixture with three moles of water boiling at 92-93$\circ$C is very useful synthetic intermediate in laboratory and industry. With conventional separation method, the dehydration of pyridine aqueous solution is difficult and requires strong drying chemicals. To overcome these difficulties, several researchers have investigated on the separation of pyridine from aqueous solution through polymer membranes. Kujawski reported several ion-exchang membranes containing carboxylic and sulfonic fuctional group for dehydration of aqueous pyridine solution [1]. We have applied the idea of activation of water tranport through ion-dipole interactions between polymer membrane and aclueous feed. Our previous studies reported on the in-situ complex membrane to separate water from aqueous pyridine solution based on simple acid'-base theory [2, 3]. Water transport was enhanced through in-situ complex formation between the , acid moiety in the membrane and the incoming pyridine moiety in the feed.