• Journal of environmental and Sanitary engineering
• /
• v.18 no.1
• /
• pp.41-50
• /
• 2003

Traditionally the supernatant after chemical treatment of metal acid wastewater is discharged in environment. The supernatant can be used as a coagulant as it contains effective metals. The aim of this study is to investigate the feasibility of treatment of dyeing wastewater using the supernatant after treatment by magnesium hydroxide and dolomite($Ca{\cdot}Mg(CO_3)_2$), of acidic metal wastewater. In dyeing wastewater treatment with the supernatant, optimum pH and dosage were determined. COD, turbidity and color were analyzed to evaluate the performance of treatment. In the case of magnesium hydroxide, the optimum dosage was 10%(v/v) for supernatant A and 3%(v/v) for supernatant B. Color, turbidity and COD removal was 99~100%, 85~97% and 43~53%, respectively. In the case of dolomite, the optimum dosage was 10%(v/v) for supernatant A and 3% for supernatant B. Color, turbidity and COD removal was 96~99%, 62~9l% and 52~53%, respectively.

• Applied Chemistry for Engineering
• /
• v.20 no.3
• /
• pp.301-306
• /
• 2009

This research was carried out to establish the effective treatment condition and characteristic of wastewater from the electroplating plant of cold rolling mill by using microorganism. Alkaline wastewater and acidic heavy metal wastewater accounted for 64%, 30%, respectively, of the total wastewater. Highly concentrated thiocyanate was 53890 mg/L as COD and it was 53% of total COD, even though it was 0.03% of wastewater from the electroplating plant. When treating mixed wastewater with microorganism, it was easy to remove when SCN concentrations of mixed wastewater was 200 mg/L or less. While the treatment effect of COD-causing materials was low at the concentration of 400 mg/L or less, it implies that highly concentrated thiocyanate contains a large amount of slowly biodegradable organics. When treating with mixed wastewater, pH was 7.33 at the beginning, but after 8 hours it increased to 7.99. This is caused by ammonia which is generated when SCN of highly concentrated thiocyanate was degraded by microorganism.

• Journal of Korean Society of Water and Wastewater
• /
• v.12 no.3
• /
• pp.30-40
• /
• 1998

Increasing water consumption produced sludge problems of the water treatment plants. The objective of this study is to investigate aluminium coagulants recovery n acidic and alkaline conditions. Water treatment plant sludge produced in Pusan Metropolitan City were tested for the aluminium extraction process. Experiment samples were obtained in summer from water treatment plants of Deoksan and Myongjang. Aluminium coagulants used in these plants during the test period were polyaluminium chloride(PAC), polyaluminium sulfate organic(PSO), polyaluminium sulfate silicate(PASS). Aluminium contents of water treatment sludge were in the range of 7.2~10.9% of the total solids. The recovery percentages for aluminium and iron by acidic extraction method was evaluated to 88% and 42% respectively. Extracted mass variation for other materials such as iron, manganese, total organic carbon was observed during the extraction operation. Alkaline extraction produced more than two times amount of total organic carbon than that in the acidic extraction process.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.12
• /
• pp.2175-2185
• /
• 2000

Respiration rate should be a reasonable state variable for the activated sludge and could be used to simulate the performance of the activated sludge process. Toxic materials are classified into three groups, competitive, noncompetitive and uncompetitive. They increase/decrease the half saturation coefficient or specific growth rate. that means decreasing of the substrate removal capacity. In this research, a pilot-scale activated sludge process was operated under extended aeration method, and a representative noncompetitive inhibitor, acidic wastewater was applied to establish a respirometry-based toxicity model. Using this model. the correlation coefficient between measured and calculated respiration rate was 0.96 when acidic wastewater(pH 3.9~5.5) was introduced continuously to the aeration tank. Even though respiration rate was decreased by toxic effect of acidic wastewater, effluent substrate concentration represented to COD was deteriorated just a little bit. It might be caused by the low ratio of readily biodegradable substrate in the input substrate. Reduction of respiration rate by decreasing of input substrate concentration was much lower than that by acidic wastewater, and hence it was estimated that the possibility of false toxic alarm caused by decreasing of substrate concentration should be low.

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.1
• /
• pp.10-16
• /
• 2013

Characteristics of biological hydrogen production rate and organic acid under anaerobic fermentation process were investigated with sugar wastewater. Hydrogen production rate was higher with alkaline pre-treatment than acidic pre-treatment, resulting in 70% increment. An adequate supply of the nutrients (N or P) into raw sugar wastewater could increase hydrogen production rate. Carbohydrate degradation of the anaerobic fermentation process was not directly related with hydrogen production. Sugar wastewater with the addition of the nutrients shows 3 times higher B/A ratio than the raw sugar wastewater. B/A ratio of the wastewater with alkaline pre-treatment and nutrients addition was most higher than other samples, showing 4.02 of B/A ratio. Higher B/A ratio shows higher hydrogen production rate at each sample.

• Analytical Science and Technology
• /
• v.14 no.3
• /
• pp.266-273
• /
• 2001

One pulp manufacture facility was selected as surveying facilities to examine the discharged rate and generation mechanism of dioxin in bleaching stag wastewater. The analytical method was established in the wastewater and the sample was collected and analyzed. The outlet concentration of bleaching stage was increased 5 times for 2,3,7,8-TCDF and 7 times for OCDD, and the discharged ratio between PCDFs and PCDDs was surveyed about 2:3. The 2,3,7,8-TCDF and 2,3,7,8-TCDD were mainly detected in acid wastewater of bleaching stage that is known as the typical discharged patterns of chlorine bleaching stage.

• Journal of environmental and Sanitary engineering
• /
• v.15 no.3
• /
• pp.62-69
• /
• 2000

In point of recycling wastes, batch test was conducted to examine the neutralization and Fe removal from laboratory wastewater using wastes. Oyster shell and slag had a buffer capacity to neutralize an acidic wastewater but tire rubber didn't. With increasing reaction time, dosage and agitation speed, Fe was well removed by wastes. As a result on the experiments of Freundlich isotherm, the adsorption intensities(1/n) were 0.32∼0.46 and the adsorption capacities(k) were 4.3∼4.6 for removing Fe from laboratory wastewater by wastes. In view of these results, it was estimated that wastes containing the similar compositions as these could utilize the neutralization and adsorption of heavy metals in laboratory wastewater.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.1
• /
• pp.123-130
• /
• 2007

The effects of hydrogen peroxide treatment on the reduction of waterworks sludge were investigated in this study. Sludge treated by peroxidation $H_2O_2$ oxidation) was dewatered using a pressure filter at 3atm. It was observed that $H_2O_2$ treatment at the acidic condition significantly reduce both cake water content and specific resistance to filtration (SRF), indicating the enhancement of dewaterability and filterability. The filterability by hydrogen peroxide treatment at pH 3.5 was better than acidic treatment and became comparable with polymer conditioning. The sludge filterability evaluated by SRF was optimal at a dose 2ml $H_2O_2$/sludge($0.02g\;H_2O_2/gTS$) after adjusting of pH to 3.5. The $H_2O_2$ oxidation at pH 3.5 also produced even more dewatered cake when compared with polymer conditioning. The reduction rate of sludge mass at an optimal condition showed 34% compared with untreated sludge. The effects of peroxidation on sludge properties including zeta potential, bound water and particle size were also evaluated. Peroxidation at the acidic condition reduced both bound water and zeta potential. By $H_2O_2$ combined with sulfuric acid leached iron caused Fenton's reaction, which showed a potential to significantly reduce the amount of solids mass and to produce more compact cake with higher filterability.

• Journal of Korean Society of Water and Wastewater
• /
• v.34 no.6
• /
• pp.425-435
• /
• 2020

Numerous chemical modifications on activated carbon such as acidic conditioning, thermal treatment and metal impregnation have been investigated to enhance adsorption capacities of micropollutants in water treatment plants. In this study, chemical modification including acidic, alkaline treatment, and iron-impregnation was evaluated for adsorption of 2,4-dichlorophenol (2,4-DCP). For Fe-impregnation, three concentrations of ferric chloride solutions, i.e., 0.2 M, 0.4 M, and 0.8 M, were used and ion-exchange (MIX) of iron and subsequent thermal treatment (MTH) were also applied. Surface properties of the modified carbons were analyzed by active surface area, pore volume, three-dimensional images, and chemical characteristics. The acidic and alkaline treatment changed the pore structures but yielded little improvement of adsorption capacities. As Fe concentrations were increased during impregnation, the active adsorption areas were decreased and the compositional ratios of Fe were increased. Adsorption capacities of modified ACs were evaluated using Langmuir isotherm. The MIX modification was not efficient to enhance 2,4-DCP adsorption and the MES treatment showed increases in adsorption capacities of 2,4-DCP, compared to the original activated carbon. These results implied a possibility of chemical impregnation modification for improvement of adsorption of 2,4-DCP, if a proper modification procedure is sought.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.22 no.2
• /
• pp.159-171
• /
• 2024

This study aimed to develop an efficient recycling process for wastewater generated from soil-washing used to remediate uranium (U(VI))-contaminated soil. Under acidic conditions, U(VI) ions leached from the soil were precipitated and separated through neutralization using hydrazine (N₂H₄). N₂H₄, employed as a pH adjuster, was decomposed into nitrogen gas (N₂), water (H₂O), and hydrogen ions (H⁺) by hydrogen peroxide (H₂O₂). The residual N₂H₄ was precipitated when the pH was adjusted using sulfuric acid (H₂SO₄) to recycle the wastewater in the soil-washing process. This purified wastewater was reused in the soil-washing process for a total of ten cycles. The results confirmed that the soil-washing performance for U(VI)-contaminated soil was maintained when using recycled wastewater. All in all, this study proposes an efficient recycling process for wastewater generated during the remediation of U(VI)-contaminated soil.