• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 추계학술발표회
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• pp.81-84
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• 1999

The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

• 한국식품영양학회지
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• 제9권4호
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• pp.529-535
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• 1996

This study was performed to investigate some quality characteristics of 새려 prepared from soybean milk and various seaweed(Undaria pinnatifida, Laminaria japonica, Porpyra tenera, Enteromorpha sp., Codium sp.) pulps in the ration of 9:1(v:v) with 20% MgCl2. The yields of tofu containing Undaria pinnatifida, Laminaria japonica, or Enteromorpha sp. increased but porphyra tenera, Codium sp. decreased in comparison with tofu prepared from whole soybean milk. The protein content of tofu containing Undaria pinnatifida, Laminaria japonica, Porphyra tenera, or Codium sp. increased but Enteromprpha sp. decreased in comparison with the tofu prepared from whole soybean milk. The content of Ca in Undaria pinnatifida, Porphyra tenera added tofu was higher than that of the tofu prepared from whole soybean milk or other seaweeds added tofu. In sensory evaluation the texture, color, taste of tofu were favored with the addition of sea mustard(Undaria pinnatifida) pulp than that of the tofu prepared from whole soybean milk or tofu prepared other seaweed. Tofu prepared was possible with adding 0.5~1.5% sea mustard to soybean milk but the feasible added amount level was 1% of sea mustard. The yields, protein Ca, and K content of tofu were increased by the more adding amount of sea mustard tan tat of the tofu prepared from whole soybean milk. The hardness values of 1% sea mustard added tofu were decreased than that of the tofu prepared from whole soybean milk ; on the other hand, elasticity, cohensiveness, gumminess and brittleness of tofu with sea mustard increased. The L and a values of tofu were lower and b values were higher with the addition of 1% sea mustard. The content of histidine, tyrosine, leusine, and phenylalanine were decreased but the other amino acid were increased in tofu prepared from 1% sea mustard pulp added to soybean milk. The saturated fatty acid and monoene fatty acid content of tofu were increased and C18:2, C18:3(${\gamma}$), C18:3, C20:5 of polyene fatty acid were slightly decreased in tofu prepared from 1% sea mustard pulp added to soybean milk.

• 한국약용작물학회지
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• 제15권2호
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• pp.82-88
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• 2007

From the EtOAc fraction of Eugenia caryophyllata, four compounds were isolated through activity-guided silica gel column chromatography, From the result of spectroscopic data including NMR, MS and IR, the chemical structures of the compounds were determined as 1-allyl-4-hydroxy-3-methoxybezene acetate (eugenol acetate, 1), 1-allyl-4-hydroxy-3-methoxybezene (eugenol, 2), $3{\beta}-hydroxyolean-12-en-28-oic$ acid (oleanolic acid, 3) and $2{\alpha}$, $3{\beta}-dihydroxyolean-12-en-28-oic$ acid (maslinic acid, 4). Compounds 3 and 4 were isolated for the first time from this plant. Also, compounds 1, 2 and 3 exhibited relatively high platelet aggregation inhibitory activity with the $IC_{50}$ values of 0.24, 0.09 and 0.07 mM, respectively. Compound 2 significantly prolonged activated partial thromboplastin time (aPTT) with the value of $124{\pm}11.2$ seconds as compared to the control with the value of $37.5{\pm}2.2$ seconds at the concentration of 50 ${\mu}g/ml$. Compounds 1 and 3 revealed inhibitory activity on farnesyl protein transferase (FPTase) with the $IC_{50}$ values of 0.49 and 0.24 mM and compounds 1 and 2 highly inhibited the growth of rat-H-ras cells with the $Gl_{50}$ values of 6.63 and 5.70 ${\mu}M$, respectively.

• Asian-Australasian Journal of Animal Sciences
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• 제14권8호
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• pp.1073-1077
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• 2001

Forty three 7-month old, Barbados Black $Belly{\times}Malin$ crossbred sheep were used for the trial. They were allotted into three treatment groups fed varying levels of oil palm (Elaeis guineensis) frond pellets and commercial sheep pellets. Treatment diets were 80% commercial pellet+20 % (% w/w) oil palm frond pellet (CON group, n=15), 50% commercial pellet+50% oil palm frond pellet (% w/w) (HAF group, n=14) and 80% oil palm frond pellet+20% (% w/w) commercial pellet (OPF group, n=14). The plasma fatty acid profiles from these animals were compared before and after 14 weeks of feeding. Results showed that total unsaturated fatty acid content in the CON group had increased by 10% (p<0.01) from the pre-treatment values. All three treatment groups had significantly different plasma n-6 and n-3 polyunsaturated fatty acid contents at the end of the trial. In fact, the CON group had significantly (p<0.01) more n-6 polyunsaturated fatty acid content compared to its own initial values, and also the values from the HAF and OPF groups. However there was a significant (p<0.01) decline in plasma n-3 polyunsaturated fatty acids in all groups. The final total unsaturated to saturated fatty acid content ratio was significantly (p<0.01) highest in the CON group, demonstrating the high plasma unsaturated fatty acid content in these animals. This study shows the plasma unsaturated fatty acids in sheep can be increased by dietary manipulation.

• 한국환경생태학회지
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• 제7권1호
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• pp.10-21
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• 1993

소나무, 곰솔, 젓나무 및 독일가문비를 대상으로 인위적으로 산도를 조절한 인공산성우(PH 3.0, 4.0 및 5.0)와 지하수(pH 6.5)를 1991년 4월부터 1993년 8월까지, 생육기간 중에는 주 2~3회, 겨울철은 주 1회 1회 5mm의 강도로 처리하였다. 인공산성우를 처리하면서 수종별 발아 및 득묘율, 토양산도, 유묘의 생장 및 접촉각(contact angle)을 조사.비교하여 얻은 결과는 다음과 같다. 묘목의 생장관련 형질(묘고, 지하부, 엽량 및 개체당 건중량)의 경우에는 산성우처리 초기에는 산성우 처리가 양료로서의 효과를 가지는 것으로 판단되며, 수종별로 상이한 반응을 보였다. 그러나 처리가 2년 이상 지속된 3차년도에서는 처리산성우의 산도수준이 높을수록 모든 수종에서 생장관련 형질들이 감소되는 경향을 보였으며, 이는 토양완충력의 한계 이상으로 투하되는 산집적에 의한 결과로 판단된다. 엽피해율이나 엽량(낙엽율)등의 자료는 처리산성우의 산도수준과 관련지어져 있는 것으로 나타나 산성우 피해의 조기판단 기준으로 사용가치가 높을 것으로 판단된다. 토양산도는 처리간 고도의 통계적 유의차가 인정되었다. 침엽의 표면과 물방울이 이루는 접촉각을 측정한 결과, 처리산성우의 산도수준이 높을수록 엽령이 높을수록 접촉각의 크기는 낮아졌다. 접촉각을 측정비교하는 방법은 야외에서 침엽수류에 대한 산성우 피해의 조기판단을 위한 알맞고 훌륭한 기준이라 판단된다.

• Preventive Nutrition and Food Science
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• 제21권2호
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• pp.132-137
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• 2016

Enhanced production of individual phenolic compounds by subcritical water hydrolysis (SWH) of pumpkin leaves was investigated at various temperatures ranging from 100 to $220^{\circ}C$ at 20 min and at various reaction times ranging from 10 to 50 min at $160^{\circ}C$. Caffeic acid, p-coumaric acid, ferulic acid, and gentisic acid were the major phenolic compounds in the hydrolysate of pumpkin leaves. All phenolic compounds except gentisic acid showed the highest yield at $160^{\circ}C$, but gentisic acid showed the highest yield at $180^{\circ}C$. The cumulative amount of individual phenolic compounds gradually increased by 48.1, 52.2, and $78.4{\mu}g/g$ dry matter at $100^{\circ}C$, $120^{\circ}C$, and $140^{\circ}C$, respectively, and then greatly increased by $1,477.1{\mu}g/g$ dry matter at $160^{\circ}C$. The yields of caffeic acid and ferulic acid showed peaks at 20 min, while those of cinnamic acid, p-coumaric acid, p-hydroxybenzoic acid, and procatechuic acid showed peaks at 30 min. Antioxidant activities such as 2,2-diphenyl-1-picrylhydrazyl and ferric reducing antioxidant power values gradually increased with hydrolysis temperature and ranged from 6.77 to 12.42 mg ascorbic acid equivalents/g dry matter and from 4.25 to 8.92 mmol $Fe^{2+}$/100 g dry matter, respectively. Color $L^*$ and $b^*$ values gradually decreased as hydrolysis temperature increased from $100^{\circ}C$ to $140^{\circ}C$. At high temperatures ($160^{\circ}C$ to $220^{\circ}C$), L* and b* values decreased suddenly. The $a^*$ value peaked at $160^{\circ}C$ and then decreased as temperature increased from $160^{\circ}C$ to $220^{\circ}C$. These results suggest that SWH of pumpkin leaves was strongly influenced by hydrolysis temperature and may enhanced the production of phenolic compounds and antioxidant activities.

• Asian-Australasian Journal of Animal Sciences
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• 제30권1호
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• pp.85-93
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• 2017

Objective: This study evaluated the effect of acid whey and freeze-dried cranberries on the physicochemical characteristics, lipid oxidation and fatty acid composition of nitrite-free fermented sausage made from deer meat and pork fat. Antioxidant interactions between acid whey and cranberry compounds were also explored. Methods: Four formulations of fermented venison sausage were prepared: F1 (control), F2 (with 5% liquid acid whey), F3 (with 0.06% of freeze-dried cranberries), and F4 (with 5% liquid acid whey and 0.06% of freeze-dried cranberries). Each sample was analyzed for pH, water activity ($a_w$), heme iron content, 2-thiobarbituric acid reactive substances (TBARS) value and conjugated dienes at the end of the manufacturing process and at 30 and 90 days of refrigerated storage. Fatty acid composition was measured once at the end of the manufacturing process. Results: At the end of ripening, all samples presented statistically different values for a pH range of 4.47 to pH 4.59. The sum of the unsaturated fatty acids was higher, while the conjugated diene and the TBARS values were lower in sausages with freeze-dried cranberries as compared to the control sausage. The highest content of heme iron (21.52 mg/kg) at day 90 was found in the sausage formulation with the addition of freeze-dried cranberries, which suggests that the addition of cranberries stabilized the porphyrin ring of the heme molecule during storage and thereby reduced the release of iron. The use of liquid acid whey in combination with cranberries appears to not be justified in view of the oxidative stability of the obtained products. Conclusion: The results suggest that the application of freeze-dried cranberries can lower the intensity of oxidative changes during the storage of nitrite-free fermented sausage made

• 한국식품영양과학회지
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• 제17권2호
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• pp.158-163
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• 1988

합성항산화제인 BHA와 천연항산화제인 ${\alpha}-tocopherol$ 과 sesamol을 첨가한 가열유지를 실온방치의 순으로 높았으며, 특히 저온밀폐로 저장한 ${\alpha}-tocopherol$ 처리구의 산가, 과산화물가, carbonyl가는 실온방치로 저장한 BHA 처리구와 거의 동일하였다. 실온차광밀폐, 저온밀폐 $(4^{\circ}C)$로 4주간 동안 두면서 항산력을 측정하였다. 산화억제효과는 저온밀폐, 실온차광밀폐 실온방치점도와 비중의 상승은 저온밀폐, 실온차광밀폐, 실온방치의 순으로 억제되었다. 대부분의 가열처리유지의 linoleic acid와 linolenic acid의 함량은 감소하였고 oleic acid와 palmitic acid의 상대적 함량은 증가하였으나 특히 저온밀폐 ${\alpha}-tocopherol$ 처리구의 linoleic acid의 상대함량은 $53.61{\sim}50.29%$, BHA 처리구는 $53.78{\sim}50.68%$로 대조구의 $52.09{\sim}43.96%$에 비하여 매우 높았다.

• 한국식품영양과학회지
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• 제21권1호
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• pp.17-22
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• 1992

탈지된 산쑥(Artemisia montana Pampan)으로부터 물 추출물 및 에테르 추출물인 유리형 페놀산, 에스터형 및 불용성 페놀산을 추출하였다. 각 추출물들은 시판용 식용 대두유를 기질로 하여 $45^{\circ}C{\pm}1^{\circ}C$, 빛이 없는 항온기에서 32일간 저장하였으며, 매 4일 간격으로 과산화물가와 TBA치를 측정하였다. 물 추출물을 첨가한 시험구에서 항산화 효력이 모두 대조구보다 높게 나타나 BHA와 유사한 효력을 보였으나 BHT보다는 모두 항산화 효과가 낮게 나타났다. 에테르 추출물인 유리형, 에스터형 및 불용성 페놀산을 첨가한 시험구에서는 대조구보다 항산화 효력이 높았으며 유리형은 항산화 효력이 BHA와 유사했고 에스터형은 BHA보다 높고 BHT보다 낮게 나타난 반면 불용성 페놀산은 BHT보다 항산화 효력이 높게 나타남을 보여 주었다. 그리고 세가지 페놀산 추출물 중에서는 불용성 페놀산이 가장 강한 항산화 효과를 나타내었고 에스터형, 유리형 순이었다. Gas chromatography 로 부터 분리 동정된 페놀산은 catechol, vanillin, umbellinferone, protocatechuic acid, ferulic acid, caffeic acid였다. 이상의 결과들을 종합해 볼때 약용으로 사용하고 있는 산쑥은 caffeic acid, catechol, protocatechuic acid등의 항산화 효력이 강한 성분이 많이 함유되어 있으므로 식용대두유 기질에서 좋은 항산화 효력를 나타낸다고 생각된다.

• 대한화학회지
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• 제39권3호
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• pp.213-217
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• 1995

수용액상에서 BUDDA(Butyldithiodiacetic acid), BMDDA(Benzmethyldithiodiac-etic acid), CHDDA(Cyclohexyldithiodiacetic acid)의 IR 스펙트라는 다양한 pH값에서 보고되어진다. 이온화된 carboxyl group과 비이온화된 carboxyl group의 비대칭 신축진동 흡수띠 차이를 이용하여 free-ligand의 구조를 추정한다. 또한 이들 연구의 접근은 리간드의 IR 스펙트라와 전위차 적정법을 이용하여 얻어진 $pk_a$값을 비교함으로서 설명된다.