• Title/Summary/Keyword: acid stability

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Effect of Cholesterol in Liposome on the Stabilization of Encapsulated Ascorbic Acid (리포솜 내의 콜레스테롤 함량이 Ascorbic Acid의 안정성에 미치는 영향)

  • Rhim, Chae-Hwan;Lee, Yu-Weon;Lee, Sang-Chun;Lee, Seung-Cheol
    • Applied Biological Chemistry
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    • v.42 no.3
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    • pp.205-209
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    • 1999
  • Cholesterol plays an important role in various physiological responses and membrane stability. To investigate the effect of cholesterol in liposome on the stability of encapsulated ascorbic acid, the physico-chemical experiments using various amounts of cholesterol-containing liposomes were performed. The encapsulation efficiency of ascorbic acid was decreased with increasing cholesterol content in liposome, whereas size of liposome was increased. Furthermore, the stability of encapsulated ascorbic acid was increased with increasing the content of cholesterol. The stability was not affected by pH. Encapsulated ascorbic acid in liposome stored at $37^{\circ}C$ was rapidly oxidized compared to those stored at $4^{\circ}C$. These results suggest that cholesterol in liposome affects largely to the stability of encapsulated ascorbic acid.

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Storage Stability of Anthocyanin Extracted from Black Bean (Glycine max Merrill.) with Copigments Treatment (Copigments 처리에 의한 검정콩 안토시아닌 추출물의 저장 안정성)

  • Ji, Yeong Mi;Kim, Min Young;Lee, Sang Hoon;Jang, Gwi Yeong;Yoon, Nara;Kim, Eun Hee;Kim, Kyung Mi;Lee, Junsoo;Jeong, Heon Sang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.7
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    • pp.996-1000
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    • 2016
  • Effects of copigments (succinic acid, $Cu^{2+}$, ascorbic acid, sucrose, and pH) on stability of anthocyanin extracted from black beans (Glycine max Merrill.) were investigated during storage for 8 days at 4 and $40^{\circ}C$. Succinic acid improved stability of anthocyanin by 7~15% compared to the non-treatment group at $40^{\circ}C$. $Cu^{2+}$ maintained stability of anthocyanin by about 100% for 8 days at $4^{\circ}C$. Ascorbic acid reduced stability of anthocyanin by 64~72% of non-treatment at $40^{\circ}C$. Sucrose treatment did not significantly affect stability compared to the control. The lower pH improved stability of anthocyanin. Stability at pH 1 was improved by 81~87% compared to that at pH 7. These results show that temperature, organic acid, and pH were effective in improving storage stability of anthocyanin from black beans.

Influence of Oleic and Lauric Acid on the Stability of Magnetorheological Fluids

  • Huang, Yuehua;Jiang, Yuhuan;Yang, Xiongbo;Xu, Ruizhen
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.317-321
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    • 2015
  • In this paper, magnetorheological fluids (MRFs) based on micro-sized iron particles dispersed in silicone oil are presented. The iron particles are modified by adding different ratios of oleic acid and lauric acid as surfactants to the suspensions. Lauric acid was found to reduce the stability of the MRFs, and more lauric acid results in a higher rate of sedimentation. Further study showed that the formation and structure of lauric acid may result in the sedimentation of micrometer-sized particles. Meanwhile, the electro-resistance of MRF in this paper shows a decrease from beyond $6000M{\Omega}$ to $190{\Omega}$ with an increase in the external field from 0 mT to 400 mT.

Fatty Acid Composition and Stability of Extracted Mackerel Muscle Oil and Oil-Polyethylene Glycol Particles Formed by Gas Saturated Solution Process

  • Haque, A.S.M. Tanbirul;Asaduzzaman, A.K.M.;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.17 no.1
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    • pp.67-73
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    • 2014
  • The oil in mackerel muscle was extracted using an environment friendly solvent, supercritical carbon dioxide (SC-$CO_2$) at a semibatch flow extraction process and an n-hexane. The SC-$CO_2$ was maintained at a temperature of $45^{\circ}C$ under pressures ranging from 15 to 25 MPa. The flow rate of $CO_2$ (27 g/min) was constant during the entire 2 h extraction period. The fatty acid composition of the oil was analyzed using gas chromatography (GC). Significant concentrations of eicosapentaenoic acid (EPA) acid and docosahexaenoic acid (DHA) acid were present in the SC-$CO_2$ extracted oil. The oil extracted using SC-$CO_2$ exhibited increased stability compared with n-haxane extracted oil. Particles of mackerel oil together with the biodegradable polymer, polyethylene glycol (PEG) were formed using a gas saturated solution process (PGSS) with SC-$CO_2$ in a thermostatted stirred vessel. Different temperatures ($45-55^{\circ}C$), pressures (15-25 MPa) and a nozzle size $400{\mu}m$ were used for PGSS with a 1 h reaction time. The stability of mackerel oil in the particles did not changed significantly.

Characterictics and Stability of Anthocyanin Pigment Extracted from Purple-Fleshed Potato (자색감자 Anthocyanin 색소의 특성 및 안정성)

  • Rhim, Jong-Whan;Kim, Seon-Jae
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.348-355
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    • 1999
  • Effects of pH, sugars, organic acids, metal ions, ascorbic acid and light on the stability of anthocyanin pigment extracted from purple-fleshed potato (Solanum tuberosum L.) were studied. The pH had marked influences on the color of the potato anthocyanin pigment: i.e., the lower the pH of the anthocyanin solution was, the more stable and intenser of the pigment was. It showed characteristic bathochromic shift as the pH of the solution increased. Generally, the addition of sugars into the purple-fleshed potato anthocyanin solution caused decrease in color stability of the pigment. Among the sugars tested, maltose was the most deleterious followed by sucrose, galactose, fructose and glucose. The addition of organic acids greatly increased the stability of the pigment. Malic acid was found to be the most effective in stabilizing the pigment followed by tartaric, citric and succinic acids, while malonic acid was found to be deteriorative to the stability of the pigment. Most metal ions except $Cu^{2+}$ increased stability of the pigment-especially, $Cd^{2+}\;and\;Al^{3+}$ were more effective than the others. Ascorbic acid degraded the pigment considerably, but the adverse effect was diminished by adding thiourea. Light gave an adverse effect to the stability of the purple-fleshed potato anthocyanin pigment, which could be minimized by shielding the light from the pigment.

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Hydrolytic Stability of Cured Urea-Melamine-Formaldehyde Resins Depending on Hydrolysis Conditions and Hardener Types

  • Park, Byung-Dae;Lee, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.672-681
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    • 2015
  • As a part of abating the formaldehyde emission of amino resin-bonded wood-based composite panels, this study was conducted to investigate hydrolytic stability of urea-melamine-formaldehyde (UMF) resin depending on various hydrolysis conditions and hardener types. Commercial UMF resin was cured and ground into a powdered form, and then hydrolyzed with hydrochloric acid. After the acid hydrolysis, the concentration of liberated formaldehyde in the hydrolyzed solution and mass loss of the cured UMF resins were determined to compare their hydrolytic stability. The hydrolysis of cured UMF resin increased with an increase in the acid concentration, time, and temperature and with a decrease in the smaller particle size. An optimum hydrolysis condition for the cured UMF resins was determined as $50^{\circ}C$, 90 minutes, 1.0 M hydrochloric acid and $250{\mu}m$ particle size. Hydrolysis of the UMF resin cured with different hardener types showed different degrees of the hydrolytic stability of cured UMF resins with a descending order of aluminum sulfate, ammonium chloride, and ammonium sulfate. The hydrolytic stability also decreased as the addition level of ammonium chloride increased. These results indicated that hardener types and level also had an impact on the hydrolytic stability of cured UMF resins.

Effect of Aromatic Acid Amplifier, 2-hydroxy-2'-tosyloxy Biphenyl, on the kind of Resist Resins (방향족 산증식제 2-hydroxy-2'-tosyloxy Biphenyl의 레지스트 레진의 종류에 따른 효과에 관한 연구)

  • Kang, Ji-Eun;Jeong, Yong-Seok;Jeong, Yeon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.499-505
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    • 2005
  • We compared the effects of a representative aromatic acid amplifier, 2-hydroxy-2'-tosylory biphenyl, doped in poly(tort-butyl methacrylate) (PTBMA), poly (tetrahydropyranylmethacrylate) (pTHPMh) or poly[tert-butoxycarbonyloxystyrene) (pTBOCST) resin film as acid labile polymer in view of thermal stability and photosensitivity enhancement. The acid amplifier was stable up to 60 min in pTBMA and pTBOCST film and up to 10 min in pTHPMA film at $120^{\circ}C$. pTBMA and pTHPMA film doped with the acid amplifier showed 9 times and 3 times higher photosensitivity, respectively. But pTBOCST film showed a negligible photosensitivity enhancement. Photosensitivity enhancement and thermal stability of the acid amplifier were found to be affected by the resin.

Effects of Ascorbic Acid and Citric Acid on Pungency and Color of Commercial Horseradish Powder (아스코르빈산 및 구연산이 시판 고추냉이 분말 향신료의 신미와 색상에 미치는 영향)

  • 박완규;윤종훈;최춘언
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.2
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    • pp.171-174
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    • 1992
  • Effects of ascorbic acid and citric acid on pungency and color stabilities in the Horseradish powder during 16 weeks storage were investigated. When the ascorbic arid added 0.1 wt.%, the effect of allyl isothiocynate stability was very significant after 16 weeks storage at 37$^{\circ}C$. However, the effect of citric acid on the allyl isothiocyanate stability was not observed. The results also showed that ascorbic acid and citric arid did not affect the color stability of the Horseradish powder significantly. When the Horseradish powder was tempered with water, the effect of ascorbic acid on stability of allyl isothiocynate and color value was shown.

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Stability of Anthocyanin Pigment Extracted from Mulberry Fruit (오디 색소의 안정성)

  • 강창수;마상조;조원대;김진만
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.7
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    • pp.960-964
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    • 2003
  • Effects of pH, sugars, organic acids, and metal ions on the stability of anthocyanin pigments extracted from mulberry (Morus alba L) fruit were studied. The pH had marked influences on the color of the anthocyanine pigment: i.e. the lower pH of the anthocyanin solution was, the more stable and intense of the pigment was. Among the sugars, sucrose was the most deleterious followed by fructose, glucose and maltose. Among the organic acids, maleic acid was found to be the most effective in stabilizing the pigment followed by acetic acid, citric acid and tartaric acid. Most metal ions except C $u^{+2}$ and F $e^{+3}$ were found to be effective in stabilizing the pigment.

Effect of Copigmentation on the Stability of Anthocyanins from a Korean Pigmented Rice Variety (Copigmentation에 의한 유색미 안토시아닌의 안정화 효과)

  • Yoon, Joo-Mi;Hahn, Tae-Ryong;Yoon, Hye-Hyun
    • Korean Journal of Food Science and Technology
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    • v.30 no.4
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    • pp.733-738
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    • 1998
  • Tannic acid (TA), chlorogenic acid (GA) and caffeic acid (CA) as copigments were added in anthocyanin solutions (pH 3.0) to test their effects on the stability against temperatures, metal ions, and light. Absorbance of anthocyanins increased with the increase of copigment concentrations. Tannic acid showed the highest absorbance increase with bathochromic shift of 14 nm (from 514 nm to 528 nm). Copigmentation resulted in higher storage stability of anthocyanins for 21 days at room temperature $925^{\circ}C)$ but lower thermal stability at higher temperatures more than $70^{\circ}C. Addition of metal ions to TA caused the enhanced stability as well as increased absorbance of anthocyanins. Copigmentation also caused a significant increase of light stablilty of anthocyanins at room temperature, so that addition of TA showed 2.3 times showed photodegradation of anthocyanins under 20,000 lux-light dosage in pH 3.0 solution at $25^{\circ}C$.

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