• Title/Summary/Keyword: acid environment

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Decolorization of Acid Orange II from Aqueous Solutions using Loess (황토를 이용한 Acid Orange II의 색도제거)

  • Park, Jae Hong
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.141-146
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    • 2011
  • Loess, a natural clay, was evaluated as an adsorbent for the decolorization of Acid Orange II, an azo and reactive dye, from aqueous solution. Adsorption studies were performed at $30^{\circ}C$ and the effect of reaction time, loess dosage, initial concentration, loess particle size, pH, agitation rate were investigated to determine the optimum operation conditions. The removal efficiencies of color were measured to evaluate the effectiveness of loess. From this study, it was found that optimal reaction time was 10 min. Color removal efficiencies of Acid Orange II were increased as higher loess dosage, initial concentration and agitation rate. However, color removal efficiencies decreased when pH is high and loess particle becomes large. Adsorption of Acid Orange II fitted to the pseudo-second-order rate kinetics more than first-order rate kinetics. Langmuir and Freundlich adsorption isotherm constants and correlation coefficients were calculated and compared. It was concluded that the adsorption data of Acid Orange II onto loess fitted to the Freundlich model more than Langmuir model.

A Comparative Study on Anthocyanin and Polyphenol Contents in Colored Agricultural Products (유색 농산물 중 안토시아닌과 폴리페놀 함량 비교 연구)

  • Jeong, Il-Hyung;Oh, Moon-Seog;Jeon, Jong-Sup;Kim, Han-Taek;Hong, Se-Ra;Park, Kwang-Hee;Yoon, Mi-Hye
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.371-380
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    • 2017
  • In this study, 17 kinds of polyphenols and 5 kinds of anthocyanins were analyzed to compare the contents of polyphenols and anthocyanins in 76 colored agricultural products. A total of 17 polyphenols were analyzed simultaneously by 9 phenolic acids (gallic acid, protocatechuic acid, chlorogenic acid, vanillic acid, caffeic acid, syringic acid, p-coumaric acid, t-ferulic acid, t-cinnamic acid) and 8 flavonoids ((+)catechin, syringic aldehyde, rutin, epicatechin gallate, naringin, luteolin, naringenin, kaempferol) and 5 anthocyanins (delphinidin-3-glucoside, delphinidin-3-rutinoside, cyanidin-3-galactoside, cyanidin-3-glucoside, cyanidin-3-arabinoside) were simultaneously analyzed. The total content of 17 polyphenols was determined as seoritae $255.1{\pm}7.5{\mu}g/g$, seomoktae $275.8{\pm}5.3{\mu}g/g$, black rice $78.5{\pm}4.6{\mu}g/g$, black sesame $75.8{\pm}3.2{\mu}g/g$, blueberry $143.3{\pm}5.5{\mu}g/g$, aronia $195.2{\pm}4.9{\mu}g/g$ and blackcurrent $131.6{\pm}3.2{\mu}g/g$, the highest content was found in the order of seomoktae > seoritae > aronia > blueberry > blackcurrant > black rice > black sesame. The total content of 5 anthocyanins was determined as seoritae $82.4{\pm}17.2{\mu}g/g$, seomoktae $95.2{\pm}6.1{\mu}g/g$, black rice $74.1{\pm}9.7{\mu}g/g$, black sesame were not detected, blueberry $110.8{\pm}1.9{\mu}g/g$, aronia $218.9{\pm}6.1{\mu}g/g$ and blackcurrent $209.7{\pm}4.0{\mu}g/g$, the highest content was found in the order of aronia > blackcurrant > blueberry > seomoktae > seoritae > black rice. These results indicated that seomoktae and aronia possessed the high level of functional components and further study will be needed to develop high value-added foods based on the colored agricultural products.

Selection of Herbal Medicines Requiring Quality Control for Loss on Drying, Total Ash, and Acid-insoluble Ash in Korea

  • Kim, Dong-Gyu;Kim, Bog-Soon;Kim, Yeon-Cheon;Hwang, Young-Ok;Chae, Young-Zoo;Park, Seung-Kook
    • Natural Product Sciences
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    • v.17 no.1
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    • pp.38-44
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    • 2011
  • The quality inspections items such as loss on drying, total ash, and acid-insoluble ash contents in herbal medicines, have a correlation with external sources of pollution, but are not themselves hazardous factors. Z-scores for standard normal distribution were used to investigate herbal medicines requiring quality control, which exceeds the regulatory limits of quality inspection. In total, 7,773 samples were analyzed based on plant parts. For the loss on drying, the numbers of items of herbal medicines requiring quality control are like these; 15 items for above-ground parts and 5 items for underground parts. For the total ash, 21 items for above-ground parts and 4 items for underground parts. For the acid-insoluble ash, 8 items for above-ground parts and 1 item for underground parts.

Manufacture Technology of Monoammonium phosphate from LCD Waste Acid (LCD 제조공정의 혼합폐산으로부터 일인산암모늄 제조 기술)

  • Lee, Ha-Young;Lee, Sang-Gil;Park, Sung-Kook;Kim, Ju-Han;Kim, Ju-Yup;Kim, Jun-Young
    • Clean Technology
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    • v.15 no.4
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    • pp.253-257
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    • 2009
  • The waste solution discharged form the LCD(Liquid Crystal Display) manufacturing process contains phosphoric acid, nitric acid, acetic acid and metal ions such Al and other impurities. In this study, vacuum evaporation and diffusion dialysis was developed to commercialize an efficient system for recovering the high-purity phosphoric acid and manufacturing monoammonium phosphate. By vacuum evaporation, almost 99% of nitric and acetic acid was removed. Also, by diffusion dialysis, about 97.5% of Al was removed. Monoammonium phosphate was manufactured from purified phosphoric acid and ammonium hydroxide. In order to get the optimum manufacturing condition, the molar ratio of ammonium hydroxide and phosphoric acid, pH and temperature was controlled. Using this optimum condition, we obtained the recovery rate of monoammonium phosphate of about 90%.

Chemical compositions and functional characteristics of Korean and imported pomegranate (Punica granatum L.) (국내산과 수입산 석류의 화학적 성분과 기능적 특성)

  • Kim, Mi Sook;Yun, Seol Hee;Na, Hwan Sik;Park, Hark Jae;Choi, Gyeong Cheol;Yang, Soo In;Lee, Ji Heon
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.342-347
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    • 2013
  • In recent years, polyphenol-rich herbs, fruits and processed foods, which are made of plant origin, have attracted much attention due to their potential health benefits. Pomegranate (Punica granatum L.) is an important source of bioactive compounds and has been used to treat diseases because of its medicinal properties. This research was focused on characterizing Korea's national cultivar and a similar product from California, USA. To evaluate their bioactive compounds and pharmacological activities, their anti-oxidation and cancer inhibition properties, as well as their organic acid and free sugar contents, were investigated. The national cultivar had low total sugar and high organic acid contents, contrary to the imported product. The results showed that the peel of national cultivar had high polyphenol and ellagic acid contents compared to imported product. The free radical scavenging capacity was evaluated via 2,2-diphenyl-1-picrylhydrazyl (DPPH) and its positive correlation with the total polyphenol contents was found. The anti-cancer activity of methanol extracts revealed growth inhibition against the prostate cancer cell. These results signify that while pomegranate, national cultivar, is more sour than the imported product, its health benefits could be excellent. Also, the polyphenol compound content of the non-edible part (such as the peel and the seed) was higher than that of the juice. Thus, it is suggested that the byproduct of the juice extraction could be potentially used in other fields such as medicine or dietary agents.

Physicochemical Properties and Physiological Activities of Ulsan Sweet Persimmon Peel.Flesh According to Cultivars (울산지역 생산 단감 과피.과육의 품종별 이화학적 특성 및 생리활성)

  • Choi, Jeong-Hwan;Lee, Eun-Young;Kim, Gyung-Jin;Park, In-Hae;Kim, Jong-Su;Choi, Gil-Bae;Jung, Su-Geun;Ham, Yu-Sik
    • Applied Biological Chemistry
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    • v.49 no.4
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    • pp.309-314
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    • 2006
  • This study was performed to confirm the physicochemical properties and physiological activities according to cultivar and parts of Ulsan sweet persimmons. The proximate composition of the sweet persimmons was moisture $77.68{\sim}84.65%$, crude ash $0.3{\sim}0.6$, crude fat $0.29{\sim}0.39$ and crude protein $0.52{\sim}0.61%$. Confirmed organic acids and free sugars in sweet persimmons were malic, citric, succinic, and fumaric acids, along with fructose, glucose and sucrose. The major fatty acids were linolenic, vaccenic and palmitic acids. Also, K is the highest mineral in sweet persimmons that accounts for the majority of mineral, more than 60% as $84.9{\sim}103.7mg%$. Contents of vitamin C, total phenolic compounds and flavonoids were the highest in Fuyu peel as 139.91, 169.36 and 60.79mg%, respectively, Electron donating ability and xanthine oxidase inhibition were the highest in Fuyu peel as $30.6{\sim}91.2$ and $26.3{\sim}91.9mg%$, respectively. Nitrite scavenging activity was higher in peel than flesh as $51.0{\sim}76.4mg%$ with slight difference depending on cultivar.

Metal-Urea-Montmorillonite Hybrid Incorporated with Citric Acid

  • Kim, Kwang Seop;Kim, Min-Tae;Ryu, Jin-Hee;Choi, Jong-Seo;Park, Ki Do;Kang, Hang-Won;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.610-614
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    • 2013
  • Massive intercalation of urea into montmorillonite (MUCH) was recently proposed to enhance urea use efficiency through smart suppression of emission of $NH_3$ and NOx. This study was to synthesize citrate-incorporated MUCH (Cit-MUCH) which can enhance suppression of $NH_3$ volatilization. The XRD pattern of Cit-MUCH was very similar to that of MUCH to indicate successful incorporation of citric acid into MUCH. Incorporation of citric acid was confirmed by the existence of $COO^-$ symmetric stretching vibration. During the initial 4 days after application, $NH_3$ volatilization from both bare and perilla-planted soils was much more suppressed by application of Cit-MUCH than MUCH. A peak volatilization rate decreased from 28.3 N mg $m^{-2}\;h^{-1}$ of MUCH-broadcasted soil to 22.2 N mg $m^{-2}\;h^{-1}$ of Cit-MUCH-broadcast soil. $NH_3$ volatilization was less in planted soil than bare soil for 72 hrs after application. These results showed that incorporation of citric acid led to increase in suppression of ammonia volatilization from urea-applied soils.

Inactivation of Escherichia coli O157:H7, Salmonella Enteritidis and Listeria monocytogenes by Hydrogen Peroxide and Lactic acid (과산화수소와 유산ol Escherichia coli O157:H7, Salmonella Enteritidis 및 Listeria monocytogenes의 증식 억제에 미치는 영향)

  • Jang Jae-Seon;Lee Mi-Yeon;Lee Jea-Mann;Kim Yong-Hee
    • Journal of environmental and Sanitary engineering
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    • v.19 no.4 s.54
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    • pp.69-75
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    • 2004
  • The inhibitory effect of the food processing agent on growth of Escherichia coli O157:H7, Salmonella Enteritidis, and Listeria monocytogenes was performed with hydrogen peroxide and lactic acid, and combination of hydrogen peroxide and lactic acid. The minimun inhibitory concentration (MIC) of hydrogen peroxide in E coli O157:H7 was 100 ppm at pH 5.0, 6.0, 6.5 and 7.0, while in Listeria monocytogenes 25 ppm at PH 5.5, 6.0 and 50 ppm at PH 6.5, 75ppm at pH 7.0. MIC of lactic acid in E coli O157:H7 was 2500 ppm at pH 5.0, 6.0, 6.5 and 7.0. MIC of lactic acid in S. Enteritidis was 1250 ppm at pH 5.0, 2500 ppm at pH 5.5, 6.0, 5.5 and 7.0, while in L monocytogenes 625 ppm at pH 5.5 and 125 ppm at pH 6.0, 6.5 and 7.0. MIC of combined hydrogen Peroxide and lactic acid in E. coli O157:H7, S. Enteritidis, and L. monocytogenes was 75 ppm of hydrogen peroxide with 2500 ppm of lactic acid at pH 6.5. The correlations between MICs of hydrogen peroxide and lactic acid in E. coli O157:H7, S. Enteritidis and L. monocytogene were obtained through the coefficient of $determination(R^2)$. $R^2$ value were 0.9994, 0.9935 and 0.9283, respectively. The inhibitory effect of hydrogen peroxide and lactic acid in E. coli O157:H7, S. Enteritidis and L. monocytogenes could be confirmed from the result of this experiment. Therefore, it was expected that the food process would increase or maintain by using lactic acid together with hydrogen peroxide.

Removal of Silica and Humic Acid from Brackish Water with Calcite (Calcite를 이용한 brackish water 내의 실리카와 휴믹산의 제거에 관한 연구)

  • 박소희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.243-245
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    • 2002
  • Brackish water desalination using reverse osmosis(RO) membrane is more useful and economic than sea water to solve the shortage of fresh water supply because of its low total dissolved solid(TDS) contents. Silica and humic acid in brackish water make serious fouling problems and cause the decline of permeate flux and increase of operating pressure. In this study, the experiments for removal of silica and humic acid were conducted with calcite particles to prevent membrane fouling and investigated the effect of pH of feed water Adsorption of silica to calcite was higher at pH=7.5 than 9.5 and removal rate was increased according to increase of initial concentration of silica. The effect of pH on adsorption of humic acid was not significant but at low initial concentration the adsorption of humic acid was enhanced at pH 7.5. The result of this study expect to apply to brackish water desalination experiment of flat-sheet reverse osmosis membrane.

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Physical properties of chitosan added on acrylic acid grafted cotton fabrics (아크릴산 그라프트 중합시 첨가된 Chitosan이 면직물에 미치는 물성)

  • 김수미;송화순
    • Textile Coloration and Finishing
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    • v.14 no.6
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    • pp.313-318
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    • 2002
  • Chitosan is known to be an excellent biocompatible natural polymer. Recently, with a growing interest of health and environment, chitosan which is good in no harmful effect on human body and environment, has been watched as the finish treatment of hygiene and pleasantness. The purpose of this study is to develop multi functional fabrics by chitosan added on acrylic acid grafted cotton fabrics. Therefore physical properties such as moisture regain, air permeability, whiteness, static voltage and tensile strength of chitosan added on acrylic acid grafted cotton fabrics were investigated. The results are as follows ; According to increased chitosan's concentration, grafting yield was decreased. Therefore thickness of film by treated chitosan added on acrylic acid grafted cotton fabric became thin. FT R spectra of chitosan add on acrylic acid grafted cotton fabric clearly showed peaks of COOH and $NH_2$, Moisture regain, static voltage of chitosan add on acrylic acid grafted cotton fabrics were increased than control. Air permeability, whiteness and tensile strength were decreased than control.