• Title/Summary/Keyword: acid dissolution

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The Effect of Acid Condiment and Cooking Condition on Aluminum Dissolution from Aluminum Cookware (알루미늄 조리기구에서 산성조미료와 조리조건이 알루미늄 용출에 미치는 영향)

  • ;;南出隆久
    • Journal of the Korean Home Economics Association
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    • v.38 no.2
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    • pp.21-26
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    • 2000
  • Effect of aluminum dissolution from aluminum sauce pans with the kind and concentration of acidity, boiling times and temperature of acidity solution, in new and old sauce pans, and aluminum content in typical food was investigated. As acetic acid concentration increases, aluminum content has increased. But malic acid and citric acid have suddenly increased until acidity concentration would be 0.4%. After that rapidly increasing is not shown. As boiling time and temperature of acidity solution increases, concentration of aluminum dissolved from aluminum sauce pan has increased. Concentration of aluminum by repeated use has increased only a slightly. But aluminum content has dissolved in large quantities from new pan rather than old pan.

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Effect of Solution Temperature and Bath Concentration on the Kinetics with Dissolution Reaction of Zinc-Ferrite (Zinc-ferrite의 용해 속도론에 미치는 황산 용액의 온도와 농도의 영향)

  • Oh Iee-Sik;Kim Chun-Jo
    • Resources Recycling
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    • v.12 no.4
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    • pp.30-37
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    • 2003
  • A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.

Dissolution properties of Chitin or Chitosan Microsphere Containing p-Aminosalicylic Acid (p-Aminosalicylic acid를 포함하고 있는 Chitin, Chitosan-Microsphere의 용출특성)

  • 임정수;김공수
    • Journal of Biomedical Engineering Research
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    • v.10 no.1
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    • pp.59-66
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    • 1989
  • The Applicability of chitin or chitosan microsphere as means to achieve sustained release of p-aminosalicylic acid(PAS) has been examined. The microsphere of chitin or chitosan containing PAS were prepared by coacervation in acidic aqueous system in range of pH 2.0-4.0. The dissolution test of PAS from polymeric drug system was carried out in vitro test. The dissolution rate of PAS from the microsphere with chitin was significanthly lower than that from the microsphere with chitosan.The dissolution rate of PAS from the microsphere was decreased with increasing of concentration of chitin and chitosan. The sustained release of PAS from the microsphere was more effective at pH 1.2 than pH 6.8.

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Dissolution of Mo/Al Bilayers in Phosphoric Acid

  • Kim, In-Sung;Chon, Seung-Whan;Kim, Ky-Sub;Jeon, Il-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1613-1617
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    • 2003
  • In the phosphoric acid based etchant, the dissolution rates of Mo films were measured by microgravimetry and the corrosion potentials of Mo and Al were estimated by Tafel plot method with various concentrations of nitric acid. Dissolution rate of Mo increased with the nitric acid concentration and reached a limiting value at high concentration of nitric acid in ambient condition. Corrosion potentials of Mo and Al shifted to positive direction and the difference between potentials of both metals was about 1,100 mV and 1,200 mV with 1% and above 4% of $HNO_3$, respectively. For a Mo/Al bilayers, the dissolution rate inversion is the main reason for good taper angle in shower etching process. Taper angles are observed by scanning electron microscope (SEM) after wet etching process for Mo/Al layered films with different concentrations of $HNO_3$. In the etch side profile, it was found that Al corroded faster than Mo below 4% of $HNO_3$ in dip etching process, however, Mo corroded faster above 4%. Trend for variation of taper angle of etched side of Mo/Al layered film can be explained by considering the effect corrosion rates of both metals with various concentrations of $HNO_3$.

Influence of Compression and Granule Size on Dissolution Rate of Acetaminophen, Fenbufen, and Mefenamic Acid Tablets (정제(錠劑)의 과립도(顆粒度) 및 임계타정압(臨界打錠壓)이 용출속도(溶出速度)에 미치는 영향(影響))

  • Ryu, Jang-Ha;Kim, Johng-Kap
    • Journal of Pharmaceutical Investigation
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    • v.13 no.4
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    • pp.191-195
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    • 1983
  • Acetaminophen, fenbufen, and mefenamic acid tablets were formulated with the same additives, granulated to different sizes, ranging $30{\sim}200mesh$, and compressed by pressure of $0.5{\sim}2.0\;ton{\cdot}cm^{-2}$. The hardness and disintegration time of the three tablets were determined. The dissolution rates of the three tablets at critical point of pressure were investigated. The results showed that fenbufen, and mefenamic acid tablet had critical compression pressure of $1.0\;ton{\cdot}cm^{-2}$, but acetaminophen tablet had that of $1.5\;ton{\cdot}cm^{-2}$. Neverthless, three tablets were disintegrated within 5 min. Among the three tablets, mefenamic acid tablet followed zero order of dissolution and the rate constants were as fellows; $1.68 \;mg{\cdot}min^{-1}\;(30{\sim}50mesh),\;1.76mg{\cdot} min^{-1}\;(50{\sim}80\;mesh)\;and\;4.85\;mg{\cdot}min^{-1}\;(80{\sim}200mesh)$.

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Comparison of Quality of Natural Pollen and Processed Pollen (시판 천연화분 및 가공화분의 품질에 관한 비교 연구)

  • 김성준;이영근;빈재훈;배기철
    • Journal of Food Hygiene and Safety
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    • v.6 no.1
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    • pp.41-48
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    • 1991
  • Dissolution rate , periduium state, nutrient component and fatty acid composition of 5 species of natural pollen and 3 species of processed pollen were carried out for evaluation of quality. Natural pollens had average 11.5% of moistures, and had native peridium may be responsible for allergy. The average dissolution rate of natural pollens were low as 66.3%. One among 3 species of processed pollen was observed to have not peridium, resulted in higher dissolution rate. Major fatty acid of pollen was palmitic acid but content of oleic acid was lower than that of other plant seeds.

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Decontamination of spent ion exchange resins contaminated with iron-oxide deposits using mineral acid solutions

  • Tokar, E.A.;Matskevich, A.I.;Palamarchuk, M.S.;Parotkina, Yu.A.;Egorin, A.M.
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2918-2925
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    • 2021
  • The efficiency of decontamination of model spent ion exchange resins, contaminated with magnetite and hematite, with mineral acid solutions, and using electro-decontamination, was evaluated. It has been shown that effective hematite dissolution occurs in concentrated mineral acid solutions. However, the use of direct current increases the decontamination efficiency of spent ion exchange resins contaminated with hematite. It is determined that with increasing voltage and acid concentration, the dissolution efficiency of hematite deposits increases and can exceed 99%. It has been shown that hematite dissolution is accompanied by secondary adsorption of radionuclides due to ion exchange, which can be removed with sodium nitrate solutions.

Alkaline Dissolution and Dyeing Properties of Sea-island Type Ultrafine Nylon Fiber (해도형 초극세 나일론 섬유의 알칼리 용출 및 염색성)

  • Lee, Hae-Jung;Lee, Hyo-Young;Park, Eun-Ji;Choi, Yeon-Ji;Kim, Sund-Dong
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.325-331
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    • 2010
  • The alkaline dissolution behavior of sea-island type ultrafine nylon fiber were dependent on the concentration of NaOH and treatment time, and the most appropriate condition for alkaline dissolution was to treat with 20g/l NaOH for 30 min at $80^{\circ}C$. The dyeing properties of sea-island type ultrafine nylon fiber and regular nylon fiber were examined with 3 different types of acid dyes in this study. The dye uptakes of ultrafine nylon fiber were higher than regular nylon fiber because of large surface area per unit mass, which increased as the dye bath pH decreased. The dyeing rates on ultrafine nylon fiber were faster and dye exhaustions were higher than regular nylon fiber, however color strength and rating of wash fastness were lower. It was also found that levelling type acid dye showed fast dyeing rate on both nylon fibers than metal-complex and milling type acid dyes.

Oxalic Acid-based Remediation of Arsenic-contaminated Soil (옥살산 기반의 비소오염토양 정화 연구)

  • Lee, Myeong Eun;Jeon, Eun-Ki;Kim, Jong-Gook;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.85-91
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    • 2018
  • Arsenic (As) usually is bound to amorphous iron oxides in the soils, and it can be removed via dissolution of iron oxides. Inorganic acid and chelating agent are widely used to extract As in the soil washing. However, the overall performance is highly dependent on the state of As fractionation. In this study, oxalic acid and inorganic acids (HCl, $H_2SO_4$, and $H_3PO_4$) were applied to enhance the dissolution of iron oxides for remediation of As-contaminated soils. Oxalic acid was most effective to extract As from soils and removal of As was two times greater than other inorganic acids. Additionally, 75% of As bound to amorphous iron oxides was removed by 0.2 M oxalic acid. Arsenic removal by oxalic acid was directly proportional to the sum of labile fractions of As instead of the total concentration of As. Therefore, the oxalic acid could extract most As bound to amorphous iron oxides.

Immediate Drug Release Enhancement of Nateglinide Using Fumaric Acid (푸마르산을 이용한 나테글리니드 함유 속방출형 제형의 약물방출 개선에 관한 연구)

  • Lee, Sung-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.506-512
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    • 2017
  • The purpose of this study was to improve release rate and bioavailability of nateglinide formulation. Polymorphism selection and particle size control were performed to enhance formulation dissolution rate, and a pH modifier was included in the formulation to overcome pH-dependent solubility of nateglinide. The enhanced dissolution rate was characterized by using a dissolution test. The results showed that H-type raw material had a higher dissolution rate than that of B-type raw material. There was 6.2% difference in dissolution between the two materials at 60 min. With regard to particle size, raw material with a $1.13{\mu}m$ particle size showed a 20% faster release rate than that of raw material with a $2.28{\mu}m$ particle size. Furthermore, fumaric acid was included in formulation as a pH modifier. That addition produced a greater than 50% improvement in dissolution rate. In conclusion, dissolution rate of nateglinide can be enhanced by optimizing its polymorphism and particle size; moreover, a synergistic effect on the enhancement of dissolution rate is obtained by including fumaric acid, a pH modifier, in the formulation.