• 제목/요약/키워드: acid attack study

검색결과 68건 처리시간 0.024초

알루미네이트계 급결제를 사용한 숏크리트의 화학적침식에 대한 강도 특성 (The Strength Properties of Chemical Attack of Shotcrete using the Aluminate Accelerator)

  • 김성수;이정배;윤하영;한승우
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.245-248
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    • 2006
  • This study investigated the strength of shotcrete with aluminate accelerator to connect with the proper repair methods or monitoring skills in subway, cable tunnel and underground storage. In order to approach these goals, the shotcrete specimens were exposed to acid, sulfate and seawater environments, and strength properties of the shotcrete suffering from the attacking sources were examined.

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Assessment of strength and durability of bagasse ash and Silica fume concrete

  • Singaram, Jayanthi;Kowsik, Radhika
    • Computers and Concrete
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    • 제17권6호
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    • pp.801-814
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    • 2016
  • An alternative type of building system with masonry units is extensively used nowadays to reduce the emission of CO2 and embodied energy. Long-term performance of such structures has become essential for sustaining the building technology. This study aims to assess the strength and durability properties of concrete prepared with unprocessed bagasse ash (BA) and silica fume (SF). A mix proportion of 1:3:3 was used to cast concrete cubes of size $100mm{\times}100mm{\times}100mm$ with various replacement levels of cement and tested. The cubes were cast with zero slump normally adopted in the manufacturing of hollow blocks. The cubes were exposed to acid attack, alkaline attack and sulphate attack to evaluate their durability. The mass loss and damages to concrete for all cases of exposures were determined at 30, 60, and 90 days, respectively. Then, the residual compressive strength for all cases was determined at the end of 90 days of durability test. The results showed that there was slight difference in mass loss before and after exposure to chemical attack in all the cases. Though the appearance was slightly different than the normal concrete the residual weight was not affected. The compressive strength of 10% bagasse ash (BA) as a replacement for cement, with 10% SF as admixture resulted in better strength than the normal concrete. Hence concrete with 10% replacement with BA along with 10% SF as admixture was considered to be durable. Besides solid concrete cubes, hollow blocks using the same concrete were casted and tested simultaneously to explore the possibility of production of masonry units.

Tissue-specific systemic responses of the wild tobacco Nicotiana attenuata against stem-boring herbivore attack

  • Lee, Gisuk;Joo, Youngsung;Baldwin, Ian T.;Kim, Sang-Gyu
    • Journal of Ecology and Environment
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    • 제45권3호
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    • pp.143-151
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    • 2021
  • Background: Plants are able to optimize defense responses induced by various herbivores, which have different feeding strategies. Local and systemic responses within a plant after herbivory are essential to modulate herbivore-specific plant responses. For instance, leaf-chewing herbivores elicit jasmonic acid signaling, which result in the inductions of toxic chemicals in the attacked leaf (tissue-specific responses) and also in the other unattacked parts of the plant (systemic responses). Root herbivory induces toxic metabolites in the attacked root and alters the levels of transcripts and metabolites in the unattacked shoot. However, we have little knowledge of the local and systemic responses against stem-boring herbivores. In this study, we examined the systemic changes in metabolites in the wild tobacco Nicotiana attenuata, when the stem-boring herbivore Trichobaris mucorea attacks. Results: To investigate the systemic responses of T. mucorea attacks, we measured the levels of jasmonic acid (JA), JA-dependent secondary metabolites, soluble sugars, and free amino acids in 7 distinct tissues of N. attenuata: leaf lamina with epidermis (LLE), leaf midrib (LM), stem epidermis (SE), stem pith (SP), stem vascular bundle (SV), root cortex with epidermis (RCE), and root vascular bundle (RV). The levels of JA were increased in all root tissues and in LM by T. mucorea attacks. The levels of chlorogenic acids (CGAs) and nicotine were increased in all stem tissues by T. mucorea. However, CGA was systematically induced in LM, and nicotine was systematically induced in LM and RCE. We further tested the resource allocation by measuring soluble sugars and free amino acids in plant tissues. T. mucorea attacks increased the level of free amino acids in all tissues except in LLE. The levels of soluble sugars were significantly decreased in SE and SP, but increased in RV. Conclusions: The results reveal that plants have local- and systemic-specific responses in response to attack from a stem-boring herbivore. Interestingly, the level of induced secondary metabolites was not consistent with the systemic inductions of JA. Spatiotemporal resolution of plant defense responses against stem herbivory will be required to understand how a plant copes with attack from herbivores from different feeding guilds.

광물질 혼화재를 혼합한 수중불분리성 콘크리트의 물성 향상을 위한 연구 (A Study for Improving Properties of Antiwashout Underwater Concrete Mixed with Mineral Admixtures)

  • 문한영;신국재;이창수
    • 콘크리트학회논문집
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    • 제14권3호
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    • pp.409-419
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    • 2002
  • Nowadays, antiwashout underwater concrete is widely used for constructing underwater concrete structures but they, especially placed in marine environment, can be easily attacked by chemical ions such as SO$\^$2-/$\_$4/ Cl$\^$-/ and Mg$\^$2+/, so the quality and capability of concrete structures go down. In this paper, to solve and improve those matters, flyash and GGBFS(ground granulated blast furnace slag) were used as partial replacements for ordinary portland cement. As results of experiments for fundamental properties of antiwashout underwater concrete containing 10, 20, 30% of flyash and 40, 50, 60 % of GGBFS respectively, setting time, air contents, suspended solids and pH value were satisfied with the "Standard Specification of Antiwashout Admixtures for Concrete" prescribed by KSCE, and also slump flow, efflux time and elevation of head were more improved than that of control concrete. From the compressive strength test, it was revealed that the antiwashout underwater concrete containing mineral admixtures(flyash and GGBFS) is more effective for long term compressive strength than control concrete. An attempt to know how durable when they are under chemical attack has also been done by immersing in chemical solutions that were x2 artificial seawater, 5 % sulphuric acid solution, 10%, sodium sulfate solution and 10% calcium chloride solution. After immersion test for 91days, XRD analysis was carried out to investigate the reactants between cement hydrates and chemical ions and some crystalline such as gypsum ettringite and Fridel′s salt were confirmed.

pH Swing법을 활용한 이산화탄소 반응경화형 시멘트 경화체의 CO2 고정화 성능 및 기계적 물성 개선 (Improving the CO2 Sequestration Capability and Mechanical Properties of CO2 Reactive Cement Paste Using pH Swing Method)

  • 조성민;김경률;배성철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.115-116
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    • 2023
  • This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO2 reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO3) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO3)2 in water. The results presented that the higher the concentration of HNO3, the higher the compressive strength and CO2 sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO3 crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO3 presented deterioration due to the too harsh pH environment and abundant NO3- ions which are known to retard the reaction of cement.

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Effects of sulphuric acid on mechanical and durability properties of ECC confined by FRP fabrics

  • Gulsan, Mehmet Eren;Mohammedameen, Alaa;Sahmaran, Mustafa;Nis, Anil;Alzeebaree, Radhwan;Cevik, Abdulkadir
    • Advances in concrete construction
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    • 제6권2호
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    • pp.199-220
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    • 2018
  • In this study, the effects of sulphuric acid on the mechanical performance and the durability of Engineered Cementitious Composites (ECC) specimens were investigated. The carbon fiber reinforced polymer (CFRP) and basalt fiber reinforced polymer (BFRP) fabrics were used to evaluate the performances of the confined and unconfined ECC specimens under static and cyclic loading in the acidic environment. In addition, the use of CFRP and BFRP fabrics as a rehabilitation technique was also studied for the specimens exposed to the sulphuric acid environment. The polyvinyl alcohol (PVA) fiber with a fraction of 2% was used in the research. Two different PVA-ECC concretes were produced using low lime fly ash (LCFA) and high lime fly ash (HCFA) with the fly ash-to-OPC ratio of 1.2. Unwrapped PVA-ECC specimens were also produced as a reference concrete and all concrete specimens were continuously immersed in 5% sulphuric acid solution ($H_2SO_4$). The mechanical performance and the durability of specimens were evaluated by means of the visual inspection, weight change, static and cyclic loading, and failure mode. In addition, microscopic changes of the PVA-ECC specimens due to sulphuric acid attack were also assessed using scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that PVA-ECC specimens produced with low lime fly ash (LCFA) showed superior performance than the specimens produced with high lime fly ash (HCFA) in the acidic environment. In addition, confinement of ECC specimens with BFRP and CFRP fabrics significantly improved compressive strength, ductility, and durability of the specimens. PVA-ECC specimens wrapped with carbon FRP fabric showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabric. Both FRP materials can be used as a rehabilitation material in the acidic environment.

식물 세포막의 지방산 조성에 미치는 고강도 청색광선의 효과 (Blue Light Effect on the Fatty Acid Composition of Membrane Lipid of Plant Leaves)

  • 정보경;김창숙;정진
    • 한국환경농학회지
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    • 제11권3호
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    • pp.261-268
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    • 1992
  • 식물 세포의 미토콘드리아와 엽록체는 광 증감제로 작용할 가능성이 있는 여러 가지 색소들을 함유하고 있다. 이들 색소들은 대부분이 막에 결합되어있으며 청색광 영역에서 강한 흡수대를 가지므로 청색광하에서 노출된 이들 소기관에서는 활성산소가 발생되어 막의 구조적, 기능적 피해를 유발하는 요인이 된다. 활성산소의 광발생에 따른 막구조의 변화는 일차적으로 막지질 지방산성분의 산화적 파괴에 기인할 것이다. 본 연구에서는 식물이 고광도의 가시광선(특히 청색광선)하에서 일어나는 막지질 지방산의 산화적 파괴에 지방산 대신 상대적으로 둔감한 포화 지방산의 조성비를 높일 것이라고 가정하고, 이를 뒷받침할만한 실험결과를 얻었다. 즉, 광질이 서로 다른 가시광선 처리조건하에서 생장중인 식물 및 그 소기관들을 대상으로 막지질의 과산화, 지방산조성 및 불포화도, 막결합 단백질의 활성 등을 측정하고 이를 제시하였다.

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재생골재 콘크리트의 화학안정성에 관한 실험적 연구 (An Experimental Study on the Chemical Soundness of Recycled Aggregate Concrete)

  • 김무한;김규용;박선규;이정율
    • 콘크리트학회논문집
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    • 제11권4호
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    • pp.13-20
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    • 1999
  • Recently, the study for practical construction application no recycled aggregate concrete is actively being proceeded, on the purpose of technical development for recycling on the construction waste concrete occurred at the time of destruction of building construction by the rapid increase of building wastes and exhaustion of natural aggregates. But, the durability of investigation with all sorts of fluidity and engineering property for application recycled aggregate concrete to practical construction must be done at the same time. Especially, because of the real condition for chemical attack of concrete construction by the acid rain, acidification of soil, deepening of air pollution and dirty water etc. being come to the fore a serious problem, the study on the chemical soundness of concrete durability must be accompanied. This study is composed as: I series: Analysis for chemical soundness of aggregates. II series: Analysis for chemical soundness of natural and recycled aggregate concrete against $Na_2$$SO_4$ solution in drying and wet curing condition ($at20~80^{\circ}C$).

시호 약침제제의 자유기 소거능 및 지질과산화 억제효능에 관한 연구 (Scavenging Effects of Free Radicals and Inhibitory Effects of Lipid Peroxidation of Bupleury Radix Aqua-Acupuncture Solution in Vitro)

  • 문진영;임종국
    • Journal of Acupuncture Research
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    • 제15권2호
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    • pp.135-145
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    • 1998
  • Bupleury radix has been used for the treatment of fever, liver disease, inflammation in traditional medicine. The present study was carried out to evaluate the antioxidant effects of Bupleury radix aqua-acupuncture solution (BRAS) in vitro. Oxygen derived free radicals produced in the course of normal aerobic life, such as superoxide anion radical($O_2^-$ ), hydroxyl radicaI( OH), hydrogen peroxide($H_2O_2$) and singlet oxygen($^1O_2$) can attack polyunsaturated fatty acid in cell membranes, enzymes, other cell compounds, and give rise to lipid peroxidation, DNA damage, lipofuscin accumulation, structure alteration of cell membrane and cell death. In this study, antioxidant effects of BRAS on lipid peroxidation were determined according to the method of TBA. BRAS inhibited markedly peroxidation of linoleic acid during the autoxidation, and also inhibited lipid peroxidation induced by hydroxyl radical derived from $H_2O_2-Fe^{2+}$ in rat liver homogenate. And BRAS showed 30% scavenging effect on DPPH radical, also exhibited a 30% inhibitory effect on superoxide generation from xanthine-xanthine oxidase system. In addition, BRAS protected the cell death induced by tert-butyl hydroperoxide(t-BHP) and significantly increased cell viability in the normal rat liver cell(Ac2F).

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내황산성 자기치유 콘크리트 및 단면복구재 개발에 관한 연구 (A study on the development of self-healing concrete and repair materials with the resistance to sulfuric acid attack)

  • 방신영;김정미;안태호
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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    • pp.84-85
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    • 2015
  • The aim of this study is to develop crack self-healing concrete and repair materials with the sulfate resistance using geo-materials and by-products for practical industrial application. Research has been done on the healing of cracks in aged concrete, but it seems that very little is known about the actual healing mechanism and its conditions. In this research, the essential properties of geo-materials with pozzolanic reaction for self-healing were analyzed and discussed.

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