• 한국재료학회지
• /
• 제29권8호
• /
• pp.511-518
• /
• 2019

In this study, the effect of carbon equivalent and cooling rate on microstructure and hardness of A516 steels for pressure vessel is investigated. Six kinds of specimens are fabricated by varying carbon equivalent and cooling rate, and their microstructures and hardness levels are analyzed. Specimens with low carbon equivalent consist of ferrite and pearlite. As the cooling rate increases, the size of pearlite decreases slightly. The specimens with high carbon equivalent and rapid cooling rates of 10 and $20^{\circ}C/s$ consist of not only ferrite and pearlite but also bainite structure, such as granular bainite, acicular ferrite, and bainite ferrite. As the cooling rate increases, the volume fractions of bainite structure increase and the effective grain size decreases. The effective grain sizes of granular bainite, acicular ferrite, and bainitic ferrite are ~20, ~5, and ${\sim}10{{\mu}m$, respectively. In the specimens with bainite structure, the volume fractions of acicular ferrite and bainitic ferrite, with small effective grains, increase as cooling rate increases, and so the hardness increases significantly.

• 한국자기학회지
• /
• 제8권1호
• /
• pp.1-5
• /
• 1998

침상형 Fe-Co 합금입자는 고밀도 기록용 자성분말로 응용이 기대되는 재료이다. Co 조성변화에 따른 자기적 성질 중 특히 최미세자기장에 미치는 효과를 Mossbauer 분광법과 투과 전자현미경 (TEM), 그리고 X-선 회절실험 등을 이용하여 조사하였다. 침상형 FenCo(n=5,4,3,2) 합금입자는 화학적 공침법으로 제조하였고, silica 코팅 후에 수소분위가에서 환원 처리하였다. 결정구조는 모든 조성 영역에 걸쳐 체심입방구조로서 Co 조성값의 증가와 함께 격자상수 값은 감소하였다. Mossbauer 분광 실험을 통하여 Co 조성 증가에 기인된 Co 원자들의 국부적 분포 변화는 초미세 자기장 값의 감소를 초래하였다.

• 대한치과기공학회지
• /
• 제23권2호
• /
• pp.203-210
• /
• 2002

This test is to conduct applied research the reaction area of the Ti-cast metal body which is made use of Dental Phosphate-silica alumina bonded investment material selling at a market, and the cooling method is how to effect on the acicular. The experimentation is as followings, 1. Experimental specimens After invest with Dental Phosphate-silica alumina bonded investment material, the $10{\times}10{\times}1.0mm^3$ wax pattern was casted by Dental high vacuum argon centrifugal casting machine. 2. Test We can analyze SEM/EDS, XRD utilize the fractography(an optical microscope). 3. Conclusion The pure cast metal body constituted of reaction products layer, stability layer and contamination layer. This pure cast have no connection with the cooling condition. The pure Titanium shows difference in a component distribution according to the cooling condition. Through this experimentation we can establish that acicular in the pure Ti-cast metal is consist of Hexagonal structure a=2.9505$\AA$, c=4.6826$\AA$.

• 한국세라믹학회지
• /
• 제41권12호
• /
• pp.889-892
• /
• 2004

Acicular type aragonite precipitated calcium carbonate was synthesized by carbonation reaction of $Ca(OH)_2$ slurry and $CO_2$ gas. As increasing the initial concentration of $Mg^{2+}$ ion, calcite crystal phase substantially decreased while that of aragonite crystal phase increased. According to XRD and EDS analysis, it was found that the addition of $MgCl_2$ induced the $Mg^{2+}$ ion to substitute in $Ca^{2+}$ ion site of calcite lattice then the unstabled calcite structure be resolved, consequently the growth of calcite structure is interrupted while the growth of aragonite structure is expedited.

• 한국가스학회지
• /
• 제17권1호
• /
• pp.19-25
• /
• 2013

용접에 의한 가스설비, 교량, 선박 등 강 구조물의 접합 방법은 대부분 십자형이나 T형의 필릿 용접으로 이루어지며 구조물의 형상과 용도에 따라 완전 용입 또는 불완전 용입 상태로 이루어진다. 본 연구에서는 십자형 필릿용접 구조물에 대하여 재료 두께별 용입 깊이에 따른 피로 균열 특성을 파악하였고, 그 결과로부터 무한수명 영역내에서의 안전 설계응력에 대하여 고찰하였다. 미 용입 길이가 길면 루트 부 파괴가 되어 무한 수명 영역은 작고 미 용입 길이가 짧으면 토우부 파괴가 되어 무한 수명 영역은 크게 나타났다. 3층 용접한 재료 두께 20mm의 경우가 2층 용접한 재료 두께 10mm, 15mm의 경우보다 미세한 페라이트 침상 조직을 더 많게 형성시켜 노치 인성을 증가시키므로 서 피로강도와 무한 수명을 더 향상시킨 것으로 나타났다.

• 한국가스학회지
• /
• 제16권4호
• /
• pp.16-22
• /
• 2012

용접기술의 발달과 더불어 기계, 교량, 선박 그리고 가스설비 등의 제작공정을 위하여 용접의 이용이 증가하고 있다. 따라서 그들의 용접 구조물 제작을 위하여 높은 생산성과 안전설계를 고려하는 용접 법을 개발하는 것이 요구되고 있다. 본 연구에서는 재료 두께, 용접층수, 하중 방향 그리고 토우부의 노치 반경과 관련하여 완전 용입 십자형 필릿 용접부의 피로강도 및 피로수명의 특성에 대하여 기초적으로 고찰하였다. 대부분의 피로파괴는 십자형 필릿 용접의 토우부에서 발생하였다. 피로강도 및 피로수명은 토우 부의 노치 반경과 플랭크 각에 의한 응력집중의 영향을 받고 있다. 토우부의 금속이 다층 용접에 의하여 어닐링 되고 확산 되었으며 그 결과 침상 페라이트 조직이 형성되어 피로강도와 피로수명을 향상시켰다.

• 한국세라믹학회지
• /
• 제33권1호
• /
• pp.92-100
• /
• 1996

Amorphous alumina(AA) the precursor of ${\gamma}$-alumina for catalyst support was made in the newly designed ball filled heating column. Some properties of AA as precursor were investigated. In observation of microstruc-ture and pore structure of AA and its derivatives scanning electronic microscope(SEM) and transmission electronic microscope(TEM) were used. It was found that the width of one particle in AA was 45~60$\AA$ and the average distance among the particles ranged 9~12 $\AA$ which suggested a micropore structure. When AA was reacted with water the shape of the surface was found to be altered and acicular bioehmite was formed inside AA which contributed inproved formability. Pore distribution was evaluated for the three samples of AA ground and granulated lump and La2O3 coated alumina. Acid sites were quantitatively determined by ammonia TPD method and the effect of impurity of Na on acid sites was discussed. Water adsorption capacity was evaluated in terms of a desiccant.

• 한국주조공학회지
• /
• 제25권3호
• /
• pp.128-133
• /
• 2005

The effects of Mn and Cr on the crystallization behaviors of Fe-bearing intennetallics in A356 alloy were studied. Coarse and acicular ${\beta}-Al_{5}$FeSi phase in A356-0.20wt.%Fe alloy was modified into small ${\alpha}$-Al(Fe,Mn)Si and ${\alpha}$-Al(Fe,Cr)Si phases in response to Mn and Cr addition, respectively. Increasing of Mn addition amount elevates the crystallizing temperature of ${\alpha}$-Al(Fe,Mn)Si and the Mn/Fe ratio in the ${\alpha}$-Al(Fe,Mn)Si. Cr is more effective to modify ${\beta}-Al_{5}$FeSi in comparison with Mn. ${\alpha}$-Al(Fe,Mn)Si phase had BCC/SC dual structure.

• 대한치과기공학회지
• /
• 제30권1호
• /
• pp.25-31
• /
• 2008

Cp-Ti and Ti-6Al-4V alloys commonly used dental implant materials, particularly for orthopaedic and osteosynthesis because of its suitable mechanical properties and excellent biocompatibility. This alloys have excellent corrosion behavior in the clinical environment. The first factor to decide the success of dental implantation is sufficient osseointegration and high corrosion resistance between on implant fixture and its surrounding bone tissue. In this study, in order to increase corrosion resistance and biocompatibility of Cp-Ti and Ti-6Al-4V alloy that surface of manufactured alloy was coated with TiN by RF-magnetron sputtering method. The electrochemical behavior of TiN coated Cp-Ti and Ti-6Al-4V alloy were investigated using potentiodynamic (EG&G Co, PARSTAT 2273. USA) and potentiostatic test (250mV) in 0.9% NaCl solution at 36.5 $\pm$ 1$^{\circ}C$. These results are as follows : 1. From the microstructure analysis, Cp-Ti showed the acicular structure of $\alpha$-phase and Ti-6Al-4V showed the micro-acicular structure of ${\alpha}+{\beta}$ phase. 2. From the potentiodynamic test, Ecorr value of Cp-Ti and Ti-6Al-4V alloys showed -702.48mV and -319.87mV, respectively. Ti-6Al-4V alloy value was higher than Cp-Ti alloy. 3. From the analysis of TiN and coated layer, TIN coated surface showed columnar structure with 800 nm thickness. 4. The corrosion resistance of TiN coated Cp-Ti and Ti-6Al-4V alloys were higher than those of the non-coated Ti alloys in 0.9% NaCl solution from potentiodynamic test, indicating better protective effect. 5. The passivation current density of TiN coated Cp-Ti and Ti-6Al-4V alloys were smaller than that of the noncoated implant fixture in 0.9% NaCl solution, indicating the good protective effect resulting from more compact and homogeneous layer formation.

• 한국세라믹학회지
• /
• 제31권2호
• /
• pp.117-128
• /
• 1994

Hematite particles were obtained by hydrothermal reaction of ferric hydroxide in the presence of small amount of citric acid which is acted as crystal growth controller. The effects of hydrothermal reaction condition son the morphology and crystal structure of powder were investigated using X-ray, TEM and FT-IR. Ellipsoidal or rectangular hematite particles were formed in the range of pH 10.75~11.75 as initial basicity of reactants and 3$\times$10-5 ~9$\times$10-5 mol as citric acid content. Crystallization of hematite was inhibited in the range of pH9. 0~10.5 and above citric acid content of $1.5\times$10-4 mol. Hematite particle length and aspect ratio were decreased gradually with increasing of citric acid content. Hematite particles formed at 14$0^{\circ}C$ exhibited particle properties with the length of 0.7 ${\mu}{\textrm}{m}$ and aspect ratio of 8. Hematite particles having a good acicular-type were not obtained above 22$0^{\circ}C$.