• Title/Summary/Keyword: absorption site

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Evaluation of Concrete Material Properties for Pavement Using Job-site Processed Recycled Aggregates (현장재생골재를 사용한 포장용 콘크리트의 기본 물성실험)

  • Yang, Sungchul;Kim, Namho
    • International Journal of Highway Engineering
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    • v.15 no.2
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    • pp.57-63
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    • 2013
  • PURPOSES : This study was performed to investigate a feasibility of job-site use of recycled concrete aggregate exceeding 3% of absorption rate. Test variables are coarse aggregate types such as natural aggregate, job-site processed recycled aggregate, and recycled aggregate processed from the intermediate waste treatment company. METHODS : First, aggregate properties such as gradation, specific gravity and absorption rate were determined. Next a basic series of mechanical properties of concrete was tested. RESULTS : All strength test results such as compression, flexure and modulus were satisfied for the minimum requirements. Finally up to first 48 elapsed days the shrinkage strains of concretes made from both recycled aggregates (in case of volume-surface ratio of 300) appeared to be greater than 26% of the companion concretes made from natural aggregates. CONCLUSIONS : Drying shrinkage result is ascribed to greater absorption rate and specific gravity of those specimens made from recycled aggregate. This may be reduced with an addition of admixtures.

Aethalometer-based Estimate of Mass Absorption Cross Section of Black Carbon Particles at an Urban Site of Gwangju (광주 지역에서 aethalometer 측정 블랙 카본 입자의 질량흡수단면 평가)

  • Park, Seung-Shik;Yu, Geun-Hye;Lee, Sang-Il;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.5
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    • pp.727-734
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    • 2018
  • In this study, real-time absorption coefficients of carbonaceous species in $PM_{2.5}$ was observed using a dual-spot 7-wavelength Aethalometer between November 1, 2016 and December 31, 2017 at an urban site of Gwangju. In addition, 24-hr integrated $PM_{2.5}$ samples were simultaneously collected at the same site and analyzed for organic carbon and elemental carbon (OC and EC) using the thermal-optical transmittance protocol. A main objective of this study was to estimate mass absorption cross section (MAC) values of black carbon (BC) particles at the study site using the linear regression between aethalometer-based absorption coefficient and filter-based EC concentration. BC particles observed at 880 nm is mainly emitted from combustion of fossil fuels, and their concentration is typically reported as equivalent BC concentration (eBC). eBC concentration calculated using MAC value of $7.77m^2/g$ at wavelength of 880 nm, which was proposed by a manufacturer, ranged from 0.3 to $7.4{\mu}g/m^3$ with an average value of $1.9{\pm}1.2{\mu}g/m^3$, accounting for 7.3% (1.5~20.9%) of $PM_{2.5}$. The relationship between aerosol absorption coefficients at 880 nm and EC concentrations provided BC MAC value of $15.2m^2/g$, ranging from 11.4 to $16.2m^2/g$. The eBC concentrations calculated using the estimated MAC of $15.2m^2/g$ were significantly lower than those reported originally from aethalometer, and ranged from 0.2 to $3.8{\mu}g/m^3$, with an average of $1.0{\pm}0.6{\mu}g/m^3$, accounting for 3.7% of $PM_{2.5}$ (0.8~10.7%). Result from this study suggests that if the MAC value recommended by the manufacturer is applied to calculate the equivalent BC concentration and radiative forcing due to BC absorption, they would result in significant errors, implying investigation of an unique MAC value of BC particles at a study site.

Local Structure Refinement of the $BaFe_{1-x}Sn_xO_{3-y}$ System with Fe K-Edge X-Ray Absorption (XANES/EXAFS) Spectroscopy

  • 김민규;곽기섭;로권선;여철현
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.743-749
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    • 1997
  • Local structure refinement of the BaFe1-xSnxO3-y system (x=0.00-0.50) has been carried out with Fe K-edge x-ray absorpion spectroscopic studies. It is found out that the Fe ions are placed in two different symmetric sites such as tetrahedral and octahedral sites in the compounds by comparison with Fe K-edge x-ray absorption near edge structure (XANES) spectrum of the γ-Fe2O3 compound as a reference. Small absorption peaks of dipole-forbiden transitions appear at a pre-edge region of 7111 eV due to the existence of Fe ions in the tetrahedral and octahedral sites. The peak intensity decreases with the substitution amount of Sn ion. Three different absorption peaks of 1s→4p dipole-allowed transition appear on the energy region between 7123 and 7131 eV. The peaks correspond to 1s→4p main transition of Fe ions in tetrahedral and octahedral sites and 1s→4p transition followed by the shakedown process of ligand to metal charge transfer. The bond distances between Fe ions in the tetrahedral site and nearest neighboring oxygen atom (Fe-4O), and those in octahedral site (Fe-6O) are determined with the extended x-ray absorption fine structure (EXAFS) analysis. Two different interatomic distances increase with the substitution amount of Sn ion and also the bond lengths of Fe-4O are shorter than those of Fe-6O in all compounds.

Antidepressants and Related Drug Interactions (항우울제와 연관약물의 약물상호작용)

  • Lee, Min Soo
    • Korean Journal of Biological Psychiatry
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    • v.7 no.1
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    • pp.21-33
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    • 2000
  • As the clinical practice of using more than one drug at a time increase, the clinician is faced with ever-increasing number of potential drug interactions. Although many interactions have little clinical significances, some may interfere with treatment or even be life-threatening. This review provides a better understanding of drug-drug interactions often encountered in pharmacotherapy of depression. Drug interactions can be grouped into two principal subdivisions : pharmacokinetic and pharmacodynamic. These subgroups serve to focus attention on possible sites of interaction as a drug moves from the site of administration and absorption to its site of action. Pharmacokinetic processes are those that include transport to and from the receptor site and consist of absorption, distribution on body tissue, plasma protein binding, metabolism, and excretion. Pharmacodynamic interactions occur at biologically active sites. In this review, emphasis is placed on antidepressant medications, how they are metabolized by the P450 system, and how they alter the metabolism of other drugs. When prescribing antidepressant medications, the clinician must consider the drug-drug interactions that are potentially problematic.

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Estimation of Light Absorption by Brown Carbon Particles using Multi-wavelength Dual-spot Aethalometer (다파장 Dual-spot Aethalometer를 이용한 갈색탄소의 광흡수계수 평가)

  • Yu, Geun-Hye;Yu, Jae-Myeong;Park, Seung-Shik
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.2
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    • pp.207-222
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    • 2018
  • In this study, light absorption of carbonaceous species in $PM_{2.5}$ was investigated using a dual-spot 7-wavelength Aethalometer(model AE33) with 1-min time interval between January 01 and September 30, 2017 at an urban site of Gwangju. During the study period, two Asian dust (AD) events occurred in April (AD I) and May (AD II), respectively, during which light absorption in total suspended particles was observed. Black carbon (BC) was the dominant light absorbing aerosol component at all wavelengths over the study period. Light absorption coefficients by aerosol particles were found to have 2.7~3.3 times higher at 370 nm than at 880 nm. This would be attributed to light absorbing organic aerosols, which is called brown carbon (BrC), as well as BC as absorbing agents of aerosol particles. Monthly average absorption ${{\AA}}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950nm}$) calculated over wavelength range of 370~950 nm ranged from 1.10 to 1.35, which was lower than the $AAE_{370-520nm}$ values ranging from 1.19~1.68 that was enhanced due to the presence of BrC. The estimated $AAE_{370-660nm}$ of BrC ranged from 2.2 to 7.5 with an average of 4.22, which was fairly consistent to the values reported by previous studies. The BrC absorption at 370 nm contributed 10.4~28.4% to the total aerosol absorption, with higher contribution in winter and spring and lower in summer. Average $PM_{10}$ and $PM_{2.5}$ concentrations were $108{\pm}36$ and $24{\pm}14{\mu}g/m^3$ during AD I, respectively, and $164{\pm}66$ and $43{\pm}26{\mu}g/m^3$ during AD II, respectively, implying the greater contribution of local pollution and/or regional pollution to $PM_{2.5}$ during the AD II. BC concentration and aerosol light absorption at 370 nm were relatively high in AD II, compared to those in AD I. Strong spectral dependence of aerosol light absorption was clearly found during the two AD events. $AAE_{370-660nm}$ of both light absorbing organic aerosols and dust particles during the AD I and II was $4.8{\pm}0.5$ and $6.2{\pm}0.7$, respectively. Higher AAE value during the AD II could be attributed to mixed enhanced urban pollution and dust aerosols. Absorption contribution by the light absorbing organic and dust aerosols estimated at 370 nm to the total light absorption was approximately 19% before and after the AD events, but it increased to 32.9~35.0% during the AD events. In conclusion, results from this study support enhancement of the aerosol light absorption due to Asian dust particles observed at the site.

Evaluating Scapular Notching after Reverse Total Shoulder Arthroplasty

  • Kim, Young-Kyu;Won, Jun-Sung;Park, Chang-Kyu;Kim, Jong-Geun
    • Clinics in Shoulder and Elbow
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    • v.18 no.4
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    • pp.248-253
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    • 2015
  • Background: Scapular notching can happen at diverse location depending on implant design or operative technique, therefore, it is easily misdiagnosed. Thus, this study purposed to suggest a method helpful to assess scapular notching. Methods: The subjects were 73 cases of reverse shoulder arthroplasty (RSA) for cuff tear arthropathy during the period from May 2009 to April 2014 and followed-up for over a year. There was medialized RSA in 22 cases, bone increased offset RSA (BIO-RSA) in 36 cases, and metal increased offset RSA (metal-RSA) in 15 cases. Scapular notching was not determined by bone defect at the inferior of glenosphere as Sirveaux's classification, but scapular notching at the site where the rotational route of the polyethylene of humeral implant met the scapular neck were examined. The results were compared with conventional method. Results: By conventional method, scapular notching was observed in 10 cases (45.5%) in medialized RSA, 12 cases (33.3%) in BIO-RSA, and none in metal-RSA. By new method, it was observed in 9 cases (40.9%) in medialized RSA, 10 cases (27.8%) in BIO-RSA, and none of metal-RSA. The site of scapular notching was apart from glenoshpere in 18 cases, and at inferior of glenosphere in 1 case. Absorption of bone graft was observed in 4 (11.1%) out of 36 cases of BIO-RSA. Conclusions: It is hard to distinguish scapular notching from absorption of bone graft in BIO-RSA, and bone absorption at the lateral lower end of glenoid in medialized RSA. Thus, it is considered useful to assess scapular notching at the site where the rotational route of the polyethylene insert meets scapular neck.

Absorption properties and size distribution of aerosol particles during the fall season at an urban site of Gwangju, Korea

  • Park, Seungshik;Yu, Geun-Hye
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.159-172
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    • 2019
  • To investigate the influence of pollution events on the chemical composition and formation processes of aerosol particles, 24-h integrated size-segregated particulate matter (PM) was collected during the fall season at an urban site of Gwangju, Korea and was used to determine the concentrations of mass, water-soluble organic carbon (WSOC) and ionic species. Furthermore, black carbon (BC) concentrations were observed with an aethalometer. The entire sampling period was classified into four periods, i.e., typical, pollution event I, pollution event II, and an Asian dust event. Stable meteorological conditions (e.g., low wind speed, high surface pressure, and high relative humidity) observed during the two pollution events led to accumulation of aerosol particles and increased formation of secondary organic and inorganic aerosol species, thus causing $PM_{2.5}$ increase. Furthermore, these stable conditions resulted in the predominant condensation or droplet mode size distributions of PM, WSOC, $NO_3{^-}$, and $SO{_4}^{2-}$. However, difference in the accumulation mode size distributions of secondary water-soluble species between pollution events I and II could be attributed to the difference in transport pathways of air masses from high-pollution regions and the formation processes for the secondary chemical species. The average absorption ${\AA}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950}$) for 370-950 nm wavelengths > 1.0 indicates that the BC particles from traffic emissions were likely mixed with light absorbing brown carbon (BrC) from biomass burning (BB) emissions. It was found that light absorption by BrC in the near UV range was affected by both secondary organic aerosol and BB emissions. Overall, the pollution events observed during fall at the study site can be due to the synergy of unfavorable meteorological conditions, enhanced secondary formation, local emissions, and long-range transportation of air masses from upwind polluted areas.

Noise Map Analysis for the Design of Noise Barrier at School Site (학교부지의 방음벽 설계를 위한 소음지도 해석)

  • Yun, Junho;Kim, Wonjin
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.232-238
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    • 2012
  • In this study, the noise mapping simulation is executed to design an effective barrier reducing noise levels of a school site. The geographical features of the ambient site and the school buildings are modelled in detail in order to consider sound propagation, deflection, and absorption phenomena etc. The main sound source, sound power level of expressway, is estimated on the basis of measured noise levels at several points of the site. The noise mapping simulation is performed by using ENPro, environmental noise prediction program based on ISO 9613 to analysis the effectiveness of noise barrier. Consequently, the noise barrier is designed to meet an environmental noise standard and satisfy low cost and safety conditions.

A Study of Black Carbon Measurement in Metropolitan Area and Suburban Area of the Korean Peninsula Performed during Pre KORea-US Air Quality Study (KORUS-AQ) Campaign (한반도 수도권 및 준 수도권 지역의 블랙 카본 측정 연구: 한-미 협력 국내 대기질 공동 조사 연구 (KORea-US Air Quality Study, KORUS-AQ) 예비캠페인 기간을 중심으로)

  • Lee, Jeonghoon;Jeong, Byeongju;Park, Da-Jeong;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.5
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    • pp.472-481
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    • 2015
  • Black carbon (BC) aerosols were monitored at the KIST site ($37.603^{\circ}N$, $127.046^{\circ}E$) and Cheonan-KOREATECH site ($36.766^{\circ}N$, $127.281^{\circ}E$) during the pre KORea-US Air Quality Study (KORUS-AQ) campaign using a couple of Muliti Angle Absorption Photometers (MAAP). BC mass concentrations were presented as $2.14{\pm}1.06{\mu}g/m^3$ and $0.94{\pm}0.60{\mu}g/m^3$ at KIST site (Seoul) and KOREATECH site (Cheonan), respectively. BC mass concentrations measured at KIST and KOREATECH sites from 22:00 on May 22 to 12:00 on May 23, 2015 showed 80% and 72% higher than average BC mass concentrations measured during campaign period, respectively. It indicates both sites could be influenced by a remote source. Similar patterns of BC concentrations between two sites from 20:00 to 24:00 on June 6, 2015 implies that the BC could be transported into both sites and then be stagnant inside the Korean Peninsula. Diurnal variation of BC in weekdays and weekends were also presented for the KIST and KOREATECH sites. Morning rush hour peak was observed at KIST site located in metropolitan area though no distinct morning rush hour peak was not observed at KOREATECH site located in a suburban area. This study revealed transport pathways of BC near the Korean Peninsula using back-trajectory analysis of BC measured both in a metropolitan area and in a suburban area.

Metachromasy of Methylene Blue and Thionine on the Phospholipid Bilayer Membrane (Phospholipid 이중층막에서 Methylene Blue와 Thionine의 Metachromasy)

  • Kim, Ki-Jun;Lee, Hoo-Seol
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.43-49
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    • 1996
  • Metachromatic properties of admixture of thionine and methylene blue(MB) in aqueous solution and phospholipid bilayer membrane have been studied by absorption spectroscopy. When thionine and MB were mixed, new coaggregate has been formed because of MB was redistributed to thionine aggregate. In phosphlipid bilayer membrane system, the highly concentrated thionine was easily formed the coaggregation with MB moiety independent of MB concentration, and absorption band of admixture were more transferred to short wavelength than aqueous system. In monomeric thionine concentration, the coaggregation band was observed at the middle wavelength between the site of monomeric thionine and the site of dimeric MB in the presence of lipid bilayer membrane.